Physical and luminescence properties of samarium doped oxide and oxyfluoride phosphate glasses

• Published in: Materials chemistry and physics 2019-05, Vol.229, p.514-522
• Main Authors: Shoaib, M., Rooh, G., Rajaramakrishna, R., Chanthima, N., Kim, H.J., Tuscharoen, S., Kaewkhao, J.
• Format: Article
• Language: English
• Subjects: Absorption spectra; CIE chromaticity; Density; Emission spectra; Energy transfer; Excitation; Fluorides; Gadolinium; Gadolinium oxide; Gadolinium oxides; Glass; Judd-Ofelt theory; Lithium; Luminescence; Mathematical analysis; Optical properties; Oxy-fluoride glasses; Oxyfluorides; Photoluminescence; Radioluminescence; Samarium
• ISSN: 0254-0584; 1879-3312
• DOI: 10.1016/j.matchemphys.2019.03.016

The research work emphasizes on physical and luminescence properties of oxide and oxyfluoride phosphate glasses and discusses the energy transfer between Gd3+ and Sm3+ ions. Lithium gadolinium oxide and oxy-fluoride phosphate glasses doped with Sm3+ ions were prepared by conventional melt quenching technique. Subsequently the physical and luminescence properties were investigated systematically to understand their behavior. The density of the prepared glass samples show high in oxide glasses as compared to oxy-fluoride glasses, and the density of both glass samples increase with increase in the Sm2O3 concentrations. In total, ten signature Sm3+ ion peaks were observed in the UV-Vis-NIR absorption spectra. In photoluminescence spectra the oxy-fluoride glass samples show higher excitation and emissions intensity than oxide glasses. The emission intensity increases up to 1mol% concentration of Sm3+ ions and then decreases due to non-radiative energy transfers. The same is observed in case of radioluminescence emission spectra. The calculated J-O intensity parameters show Ω2 > Ω4 > Ω6 trend. From Judd-Ofelt analysis, these glasses exhibit high potential for using as laser host medium. The life time recorded at the excitation and emission wavelength 401 nm and 598 nm respectively and it is observed that the life time decreases with increase in the Sm3+ ions concentration. The CIE coordinates positioned in the orange region of CIE diagram. The properties evaluated in the present work indicate that these glasses can be a good candidate of orange LEDs applications. Energy level diagram and Comparison of the Radioluminescence emission spectra at 1mol% Sm3+ concentration. [Display omitted] •17Li2O:17Gd2O3/GdF3(66-x) P2O5:xSm2O3 were synthesized.•J-O (Ωλ) parameters for these glasses showed Ω2> Ω4> Ω6 trend.•Oxy-fluoride glass has less phonon energy and less non-radiative energy transfer.•The ratiative transition probability show high values for 4G5/2. → 6H7/2 transition.•The energy transfer between Sm3+ ions is confirmed using IH Fit.