Loading…
Diindenoperylene thin-film structure on MoS2 monolayer
Research on two-dimensional (2D) atomic crystals is one of the highly progressive topics in (opto)electronics, as the van der Waals (vdW) interactions enable integration of 2D crystals with a broad range of materials. Organic π-conjugated molecules offer new opportunities for creating the so-called...
Saved in:
Published in: | Applied physics letters 2019-06, Vol.114 (25) |
---|---|
Main Authors: | , , , , , , , , , , , , , , , , |
Format: | Article |
Language: | English |
Subjects: | |
Citations: | Items that this one cites Items that cite this one |
Online Access: | Get full text |
Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
cited_by | cdi_FETCH-LOGICAL-c327t-bbad30267403c9297d112d7fc1b95057bc3eb7927dfe52923e2ef73cc931a5d53 |
---|---|
cites | cdi_FETCH-LOGICAL-c327t-bbad30267403c9297d112d7fc1b95057bc3eb7927dfe52923e2ef73cc931a5d53 |
container_end_page | |
container_issue | 25 |
container_start_page | |
container_title | Applied physics letters |
container_volume | 114 |
creator | Mrkyvkova, N. Hodas, M. Hagara, J. Nadazdy, P. Halahovets, Y. Bodik, M. Tokar, K. Chai, J. W. Wang, S. J. Chi, D. Z. Chumakov, A. Konovalov, O. Hinderhofer, A. Jergel, M. Majkova, E. Siffalovic, P. Schreiber, F. |
description | Research on two-dimensional (2D) atomic crystals is one of the highly progressive topics in (opto)electronics, as the van der Waals (vdW) interactions enable integration of 2D crystals with a broad range of materials. Organic π-conjugated molecules offer new opportunities for creating the so-called “hybrid” vdW heterostructures, in which their anisotropy adds an extra degree of functional possibilities. Moreover, it was found that in the case of organic molecules, the 2D substrate changes the molecular orientation, which in turn can enhance the overall optoelectronic properties. However, the reorientation of the molecules has been until now studied solely on the graphene underlayer that restrained its applicability to a broader range of materials. Here, we study the molecular orientation of diindenoperylene (DIP), a representative of rodlike organic semiconductors, on the MoS2 monolayer. Our results show that DIP forms separate islands on the top of the MoS2 monolayer with lying-down orientation of the molecules. We combine the grazing-incidence X-ray diffraction technique with atomistic simulations to reveal the exact molecular arrangement on the atomically thin underlayer. We also investigate optical absorption spectra for different thicknesses of the DIP layer, as they are of fundamental importance for various applications in organic-based optoelectronics. |
doi_str_mv | 10.1063/1.5100282 |
format | article |
fullrecord | <record><control><sourceid>proquest_scita</sourceid><recordid>TN_cdi_proquest_journals_2248148599</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2248148599</sourcerecordid><originalsourceid>FETCH-LOGICAL-c327t-bbad30267403c9297d112d7fc1b95057bc3eb7927dfe52923e2ef73cc931a5d53</originalsourceid><addsrcrecordid>eNp90EtLAzEUBeAgCtbqwn8w4Epham7STCZLqfUBFRfqOszkgSnTZEwyQv-9Iy26EFxdLnycAwehc8AzwBW9hhkDjElNDtAEMOclBagP0QRjTMtKMDhGJymtx5cRSieounXOa-NDb-K2M94U-d350rpuU6QcB5WHaIrgi6fwQopN8KFrtiaeoiPbdMmc7e8Uvd0tXxcP5er5_nFxsyoVJTyXbdtoiknF55gqQQTXAERzq6AVDDPeKmpaLgjX1jAiCDXEWE6VEhQaphmdootdbh_Dx2BSluswRD9WSkLmNcxrJsSoLndKxZBSNFb20W2auJWA5fcsEuR-ltFe7WxSLjfZBf-DP0P8hbLX9j_8N_kLmdlvPw</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2248148599</pqid></control><display><type>article</type><title>Diindenoperylene thin-film structure on MoS2 monolayer</title><source>American Institute of Physics:Jisc Collections:Transitional Journals Agreement 2021-23 (Reading list)</source><source>AIP_美国物理联合会现刊(与NSTL共建)</source><creator>Mrkyvkova, N. ; Hodas, M. ; Hagara, J. ; Nadazdy, P. ; Halahovets, Y. ; Bodik, M. ; Tokar, K. ; Chai, J. W. ; Wang, S. J. ; Chi, D. Z. ; Chumakov, A. ; Konovalov, O. ; Hinderhofer, A. ; Jergel, M. ; Majkova, E. ; Siffalovic, P. ; Schreiber, F.</creator><creatorcontrib>Mrkyvkova, N. ; Hodas, M. ; Hagara, J. ; Nadazdy, P. ; Halahovets, Y. ; Bodik, M. ; Tokar, K. ; Chai, J. W. ; Wang, S. J. ; Chi, D. Z. ; Chumakov, A. ; Konovalov, O. ; Hinderhofer, A. ; Jergel, M. ; Majkova, E. ; Siffalovic, P. ; Schreiber, F.</creatorcontrib><description>Research on two-dimensional (2D) atomic crystals is one of the highly progressive topics in (opto)electronics, as the van der Waals (vdW) interactions enable integration of 2D crystals with a broad range of materials. Organic π-conjugated molecules offer new opportunities for creating the so-called “hybrid” vdW heterostructures, in which their anisotropy adds an extra degree of functional possibilities. Moreover, it was found that in the case of organic molecules, the 2D substrate changes the molecular orientation, which in turn can enhance the overall optoelectronic properties. However, the reorientation of the molecules has been until now studied solely on the graphene underlayer that restrained its applicability to a broader range of materials. Here, we study the molecular orientation of diindenoperylene (DIP), a representative of rodlike organic semiconductors, on the MoS2 monolayer. Our results show that DIP forms separate islands on the top of the MoS2 monolayer with lying-down orientation of the molecules. We combine the grazing-incidence X-ray diffraction technique with atomistic simulations to reveal the exact molecular arrangement on the atomically thin underlayer. We also investigate optical absorption spectra for different thicknesses of the DIP layer, as they are of fundamental importance for various applications in organic-based optoelectronics.</description><identifier>ISSN: 0003-6951</identifier><identifier>EISSN: 1077-3118</identifier><identifier>DOI: 10.1063/1.5100282</identifier><identifier>CODEN: APPLAB</identifier><language>eng</language><publisher>Melville: American Institute of Physics</publisher><subject>Absorption spectra ; Anisotropy ; Applied physics ; Crystal structure ; Graphene ; Heterostructures ; Molybdenum disulfide ; Monolayers ; Optoelectronics ; Organic chemistry ; Organic semiconductors ; Orientation ; Substrates ; Thickness ; Thin films ; X-ray diffraction</subject><ispartof>Applied physics letters, 2019-06, Vol.114 (25)</ispartof><rights>Author(s)</rights><rights>2019 Author(s). Published under license by AIP Publishing.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c327t-bbad30267403c9297d112d7fc1b95057bc3eb7927dfe52923e2ef73cc931a5d53</citedby><cites>FETCH-LOGICAL-c327t-bbad30267403c9297d112d7fc1b95057bc3eb7927dfe52923e2ef73cc931a5d53</cites><orcidid>0000-0002-9269-5705 ; 0000-0002-9807-0810 ; 0000-0003-3257-3666 ; 0000-0002-0390-5900 ; 0000-0003-3659-6718 ; 0000-0002-6518-7617 ; 0000-0001-9597-9247 ; 0000-0002-2619-0872 ; 0000-0002-7033-1783 ; 0000-0001-7354-949X ; 0000-0001-6328-1717 ; 0000-0002-4482-7881</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://pubs.aip.org/apl/article-lookup/doi/10.1063/1.5100282$$EHTML$$P50$$Gscitation$$H</linktohtml><link.rule.ids>314,780,782,784,795,27924,27925,76383</link.rule.ids></links><search><creatorcontrib>Mrkyvkova, N.</creatorcontrib><creatorcontrib>Hodas, M.</creatorcontrib><creatorcontrib>Hagara, J.</creatorcontrib><creatorcontrib>Nadazdy, P.</creatorcontrib><creatorcontrib>Halahovets, Y.</creatorcontrib><creatorcontrib>Bodik, M.</creatorcontrib><creatorcontrib>Tokar, K.</creatorcontrib><creatorcontrib>Chai, J. W.</creatorcontrib><creatorcontrib>Wang, S. J.</creatorcontrib><creatorcontrib>Chi, D. Z.</creatorcontrib><creatorcontrib>Chumakov, A.</creatorcontrib><creatorcontrib>Konovalov, O.</creatorcontrib><creatorcontrib>Hinderhofer, A.</creatorcontrib><creatorcontrib>Jergel, M.</creatorcontrib><creatorcontrib>Majkova, E.</creatorcontrib><creatorcontrib>Siffalovic, P.</creatorcontrib><creatorcontrib>Schreiber, F.</creatorcontrib><title>Diindenoperylene thin-film structure on MoS2 monolayer</title><title>Applied physics letters</title><description>Research on two-dimensional (2D) atomic crystals is one of the highly progressive topics in (opto)electronics, as the van der Waals (vdW) interactions enable integration of 2D crystals with a broad range of materials. Organic π-conjugated molecules offer new opportunities for creating the so-called “hybrid” vdW heterostructures, in which their anisotropy adds an extra degree of functional possibilities. Moreover, it was found that in the case of organic molecules, the 2D substrate changes the molecular orientation, which in turn can enhance the overall optoelectronic properties. However, the reorientation of the molecules has been until now studied solely on the graphene underlayer that restrained its applicability to a broader range of materials. Here, we study the molecular orientation of diindenoperylene (DIP), a representative of rodlike organic semiconductors, on the MoS2 monolayer. Our results show that DIP forms separate islands on the top of the MoS2 monolayer with lying-down orientation of the molecules. We combine the grazing-incidence X-ray diffraction technique with atomistic simulations to reveal the exact molecular arrangement on the atomically thin underlayer. We also investigate optical absorption spectra for different thicknesses of the DIP layer, as they are of fundamental importance for various applications in organic-based optoelectronics.</description><subject>Absorption spectra</subject><subject>Anisotropy</subject><subject>Applied physics</subject><subject>Crystal structure</subject><subject>Graphene</subject><subject>Heterostructures</subject><subject>Molybdenum disulfide</subject><subject>Monolayers</subject><subject>Optoelectronics</subject><subject>Organic chemistry</subject><subject>Organic semiconductors</subject><subject>Orientation</subject><subject>Substrates</subject><subject>Thickness</subject><subject>Thin films</subject><subject>X-ray diffraction</subject><issn>0003-6951</issn><issn>1077-3118</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><recordid>eNp90EtLAzEUBeAgCtbqwn8w4Epham7STCZLqfUBFRfqOszkgSnTZEwyQv-9Iy26EFxdLnycAwehc8AzwBW9hhkDjElNDtAEMOclBagP0QRjTMtKMDhGJymtx5cRSieounXOa-NDb-K2M94U-d350rpuU6QcB5WHaIrgi6fwQopN8KFrtiaeoiPbdMmc7e8Uvd0tXxcP5er5_nFxsyoVJTyXbdtoiknF55gqQQTXAERzq6AVDDPeKmpaLgjX1jAiCDXEWE6VEhQaphmdootdbh_Dx2BSluswRD9WSkLmNcxrJsSoLndKxZBSNFb20W2auJWA5fcsEuR-ltFe7WxSLjfZBf-DP0P8hbLX9j_8N_kLmdlvPw</recordid><startdate>20190624</startdate><enddate>20190624</enddate><creator>Mrkyvkova, N.</creator><creator>Hodas, M.</creator><creator>Hagara, J.</creator><creator>Nadazdy, P.</creator><creator>Halahovets, Y.</creator><creator>Bodik, M.</creator><creator>Tokar, K.</creator><creator>Chai, J. W.</creator><creator>Wang, S. J.</creator><creator>Chi, D. Z.</creator><creator>Chumakov, A.</creator><creator>Konovalov, O.</creator><creator>Hinderhofer, A.</creator><creator>Jergel, M.</creator><creator>Majkova, E.</creator><creator>Siffalovic, P.</creator><creator>Schreiber, F.</creator><general>American Institute of Physics</general><scope>AAYXX</scope><scope>CITATION</scope><scope>8FD</scope><scope>H8D</scope><scope>L7M</scope><orcidid>https://orcid.org/0000-0002-9269-5705</orcidid><orcidid>https://orcid.org/0000-0002-9807-0810</orcidid><orcidid>https://orcid.org/0000-0003-3257-3666</orcidid><orcidid>https://orcid.org/0000-0002-0390-5900</orcidid><orcidid>https://orcid.org/0000-0003-3659-6718</orcidid><orcidid>https://orcid.org/0000-0002-6518-7617</orcidid><orcidid>https://orcid.org/0000-0001-9597-9247</orcidid><orcidid>https://orcid.org/0000-0002-2619-0872</orcidid><orcidid>https://orcid.org/0000-0002-7033-1783</orcidid><orcidid>https://orcid.org/0000-0001-7354-949X</orcidid><orcidid>https://orcid.org/0000-0001-6328-1717</orcidid><orcidid>https://orcid.org/0000-0002-4482-7881</orcidid></search><sort><creationdate>20190624</creationdate><title>Diindenoperylene thin-film structure on MoS2 monolayer</title><author>Mrkyvkova, N. ; Hodas, M. ; Hagara, J. ; Nadazdy, P. ; Halahovets, Y. ; Bodik, M. ; Tokar, K. ; Chai, J. W. ; Wang, S. J. ; Chi, D. Z. ; Chumakov, A. ; Konovalov, O. ; Hinderhofer, A. ; Jergel, M. ; Majkova, E. ; Siffalovic, P. ; Schreiber, F.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c327t-bbad30267403c9297d112d7fc1b95057bc3eb7927dfe52923e2ef73cc931a5d53</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><topic>Absorption spectra</topic><topic>Anisotropy</topic><topic>Applied physics</topic><topic>Crystal structure</topic><topic>Graphene</topic><topic>Heterostructures</topic><topic>Molybdenum disulfide</topic><topic>Monolayers</topic><topic>Optoelectronics</topic><topic>Organic chemistry</topic><topic>Organic semiconductors</topic><topic>Orientation</topic><topic>Substrates</topic><topic>Thickness</topic><topic>Thin films</topic><topic>X-ray diffraction</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Mrkyvkova, N.</creatorcontrib><creatorcontrib>Hodas, M.</creatorcontrib><creatorcontrib>Hagara, J.</creatorcontrib><creatorcontrib>Nadazdy, P.</creatorcontrib><creatorcontrib>Halahovets, Y.</creatorcontrib><creatorcontrib>Bodik, M.</creatorcontrib><creatorcontrib>Tokar, K.</creatorcontrib><creatorcontrib>Chai, J. W.</creatorcontrib><creatorcontrib>Wang, S. J.</creatorcontrib><creatorcontrib>Chi, D. Z.</creatorcontrib><creatorcontrib>Chumakov, A.</creatorcontrib><creatorcontrib>Konovalov, O.</creatorcontrib><creatorcontrib>Hinderhofer, A.</creatorcontrib><creatorcontrib>Jergel, M.</creatorcontrib><creatorcontrib>Majkova, E.</creatorcontrib><creatorcontrib>Siffalovic, P.</creatorcontrib><creatorcontrib>Schreiber, F.</creatorcontrib><collection>CrossRef</collection><collection>Technology Research Database</collection><collection>Aerospace Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Applied physics letters</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Mrkyvkova, N.</au><au>Hodas, M.</au><au>Hagara, J.</au><au>Nadazdy, P.</au><au>Halahovets, Y.</au><au>Bodik, M.</au><au>Tokar, K.</au><au>Chai, J. W.</au><au>Wang, S. J.</au><au>Chi, D. Z.</au><au>Chumakov, A.</au><au>Konovalov, O.</au><au>Hinderhofer, A.</au><au>Jergel, M.</au><au>Majkova, E.</au><au>Siffalovic, P.</au><au>Schreiber, F.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Diindenoperylene thin-film structure on MoS2 monolayer</atitle><jtitle>Applied physics letters</jtitle><date>2019-06-24</date><risdate>2019</risdate><volume>114</volume><issue>25</issue><issn>0003-6951</issn><eissn>1077-3118</eissn><coden>APPLAB</coden><abstract>Research on two-dimensional (2D) atomic crystals is one of the highly progressive topics in (opto)electronics, as the van der Waals (vdW) interactions enable integration of 2D crystals with a broad range of materials. Organic π-conjugated molecules offer new opportunities for creating the so-called “hybrid” vdW heterostructures, in which their anisotropy adds an extra degree of functional possibilities. Moreover, it was found that in the case of organic molecules, the 2D substrate changes the molecular orientation, which in turn can enhance the overall optoelectronic properties. However, the reorientation of the molecules has been until now studied solely on the graphene underlayer that restrained its applicability to a broader range of materials. Here, we study the molecular orientation of diindenoperylene (DIP), a representative of rodlike organic semiconductors, on the MoS2 monolayer. Our results show that DIP forms separate islands on the top of the MoS2 monolayer with lying-down orientation of the molecules. We combine the grazing-incidence X-ray diffraction technique with atomistic simulations to reveal the exact molecular arrangement on the atomically thin underlayer. We also investigate optical absorption spectra for different thicknesses of the DIP layer, as they are of fundamental importance for various applications in organic-based optoelectronics.</abstract><cop>Melville</cop><pub>American Institute of Physics</pub><doi>10.1063/1.5100282</doi><tpages>5</tpages><orcidid>https://orcid.org/0000-0002-9269-5705</orcidid><orcidid>https://orcid.org/0000-0002-9807-0810</orcidid><orcidid>https://orcid.org/0000-0003-3257-3666</orcidid><orcidid>https://orcid.org/0000-0002-0390-5900</orcidid><orcidid>https://orcid.org/0000-0003-3659-6718</orcidid><orcidid>https://orcid.org/0000-0002-6518-7617</orcidid><orcidid>https://orcid.org/0000-0001-9597-9247</orcidid><orcidid>https://orcid.org/0000-0002-2619-0872</orcidid><orcidid>https://orcid.org/0000-0002-7033-1783</orcidid><orcidid>https://orcid.org/0000-0001-7354-949X</orcidid><orcidid>https://orcid.org/0000-0001-6328-1717</orcidid><orcidid>https://orcid.org/0000-0002-4482-7881</orcidid></addata></record> |
fulltext | fulltext |
identifier | ISSN: 0003-6951 |
ispartof | Applied physics letters, 2019-06, Vol.114 (25) |
issn | 0003-6951 1077-3118 |
language | eng |
recordid | cdi_proquest_journals_2248148599 |
source | American Institute of Physics:Jisc Collections:Transitional Journals Agreement 2021-23 (Reading list); AIP_美国物理联合会现刊(与NSTL共建) |
subjects | Absorption spectra Anisotropy Applied physics Crystal structure Graphene Heterostructures Molybdenum disulfide Monolayers Optoelectronics Organic chemistry Organic semiconductors Orientation Substrates Thickness Thin films X-ray diffraction |
title | Diindenoperylene thin-film structure on MoS2 monolayer |
url | http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-25T17%3A27%3A29IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_scita&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Diindenoperylene%20thin-film%20structure%20on%20MoS2%20monolayer&rft.jtitle=Applied%20physics%20letters&rft.au=Mrkyvkova,%20N.&rft.date=2019-06-24&rft.volume=114&rft.issue=25&rft.issn=0003-6951&rft.eissn=1077-3118&rft.coden=APPLAB&rft_id=info:doi/10.1063/1.5100282&rft_dat=%3Cproquest_scita%3E2248148599%3C/proquest_scita%3E%3Cgrp_id%3Ecdi_FETCH-LOGICAL-c327t-bbad30267403c9297d112d7fc1b95057bc3eb7927dfe52923e2ef73cc931a5d53%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_pqid=2248148599&rft_id=info:pmid/&rfr_iscdi=true |