Norbornene Copolymers with Acrylates Bearing Norbornane Moieties: Promising Materials for Optoelectronics

The radical copolymerization of norbornene with norbornenyl acrylate or bornyl acrylate has been studied. New copolymers containing norbornane moieties in the side chain were produced. The influence of the reaction conditions on the composition, molecular weight characteristics, and glass transition...

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Bibliographic Details
Published in:Russian journal of applied chemistry 2019-05, Vol.92 (5), p.667-671
Main Authors: Bykov, V. I., Butenko, T. A.
Format: Article
Language:English
Subjects:
Acrylates
Chemistry
Chemistry and Materials Science
Chemistry/Food Science
Copolymerization
Copolymers
Glass transition temperature
Industrial Chemistry/Chemical Engineering
Macromolecular Compounds and Polymeric Materials
Nanoparticles
Optoelectronics
Temperature
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Summary:The radical copolymerization of norbornene with norbornenyl acrylate or bornyl acrylate has been studied. New copolymers containing norbornane moieties in the side chain were produced. The influence of the reaction conditions on the composition, molecular weight characteristics, and glass transition temperature of the copolymers was studied. It was established that copolymers of norbornene with norbornenyl acrylate or bornyl acrylate have high transparency (95–97%) in the visible region (400–800 nm) and glass transition temperature. They effectively stabilize semiconductor nanoparticles, which allows these new copolymers to be considered as promising materials for optoelectronics.
ISSN:1070-4272
1608-3296
DOI:10.1134/S1070427219050136