Design of Supramolecular Cluster Compounds of Copper Subgroup Metals Based on Polydentate Phosphine Ligands

Principles and examples of assembling heteroleptic supramolecular cluster compounds of copper subgroup metals based on polydentate phosphine ligands of various topologies are considered. The choice of an organic linker between phosphorus atoms allows one to control the formation of three-dimensional...

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Bibliographic Details
Published in:Russian journal of general chemistry 2019-06, Vol.89 (6), p.1102-1114
Main Author: Grachova, E. V.
Format: Article
Language:English
Subjects:
Chemistry
Chemistry and Materials Science
Chemistry/Food Science
Clusters
Copper
Copper compounds
Ligands
Optical properties
Subgroups
Topology
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Summary:Principles and examples of assembling heteroleptic supramolecular cluster compounds of copper subgroup metals based on polydentate phosphine ligands of various topologies are considered. The choice of an organic linker between phosphorus atoms allows one to control the formation of three-dimensional aggregates with a regular architecture, whereas the choice of alkynyl ligands determines their luminescent properties.
ISSN:1070-3632
1608-3350
DOI:10.1134/S1070363219060045