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Highly Dispersed Palladium Nanoparticle-Loaded Magnetic Catalyst (FeS@EP–AG–Pd) for Suzuki Reaction in Water
In this work, an efficient epichlorohydrin–aminoguanidine-modified Fe 3 O 4 @SiO 2 magnetic nanoparticles (FeS@EP–AG–Pd) with highly dispersed Palladium nanoparticles (Pd NPs) was reported for Suzuki reaction in water. After preparation of Fe 3 O 4 @SiO 2 (FeS), special epichlorohydrin–aminoguanidin...
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| Published in: | Catalysis letters 2017-05, Vol.147 (5), p.1162-1171 |
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| Language: | English |
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| cites | cdi_FETCH-LOGICAL-c425t-e9bc855ed7d15b87b835a50ad8e9c5718aef51083fa99e60f97ed323d9f4696c3 |
| container_end_page | 1171 |
| container_issue | 5 |
| container_start_page | 1162 |
| container_title | Catalysis letters |
| container_volume | 147 |
| creator | Sarvi, Iraj Gholizadeh, Mostafa Izadyar, Mohammad |
| description | In this work, an efficient epichlorohydrin–aminoguanidine-modified Fe
3
O
4
@SiO
2
magnetic nanoparticles (FeS@EP–AG–Pd) with highly dispersed Palladium nanoparticles (Pd NPs) was reported for Suzuki reaction in water. After preparation of Fe
3
O
4
@SiO
2
(FeS), special epichlorohydrin–aminoguanidine linker as a ligand with high content of heteroatoms was covalently bonded onto the FeS MNPs to increase their electron density. Pd
II
ions were then loaded on surface of FeS@EP–AG MNPs and reduced for achieving the uniformly dispersed Pd NPs. FeS@EP–AG–Pd MNPs were performed in Suzuki reaction as an efficient catalyst in water as a green non-toxic solvent. Magnetically separable and recyclable FeS@EP–AG–Pd MNPs were then fully characterized by FTIR, SEM, TEM, TGA, VSM, XRD, and ICP–OES. The heterogeneous catalyst could also easily be recovered and reused with no loss of activity over 6 cycles.
Graphical Abstract |
| doi_str_mv | 10.1007/s10562-017-2009-5 |
| format | article |
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3
O
4
@SiO
2
magnetic nanoparticles (FeS@EP–AG–Pd) with highly dispersed Palladium nanoparticles (Pd NPs) was reported for Suzuki reaction in water. After preparation of Fe
3
O
4
@SiO
2
(FeS), special epichlorohydrin–aminoguanidine linker as a ligand with high content of heteroatoms was covalently bonded onto the FeS MNPs to increase their electron density. Pd
II
ions were then loaded on surface of FeS@EP–AG MNPs and reduced for achieving the uniformly dispersed Pd NPs. FeS@EP–AG–Pd MNPs were performed in Suzuki reaction as an efficient catalyst in water as a green non-toxic solvent. Magnetically separable and recyclable FeS@EP–AG–Pd MNPs were then fully characterized by FTIR, SEM, TEM, TGA, VSM, XRD, and ICP–OES. The heterogeneous catalyst could also easily be recovered and reused with no loss of activity over 6 cycles.
Graphical Abstract</description><identifier>ISSN: 1011-372X</identifier><identifier>EISSN: 1572-879X</identifier><identifier>DOI: 10.1007/s10562-017-2009-5</identifier><language>eng</language><publisher>New York: Springer US</publisher><subject>Catalysis ; Catalysts ; Chemical reactions ; Chemistry ; Chemistry and Materials Science ; Dispersion ; Electron density ; Epichlorohydrin ; Epoxy resins ; Industrial Chemistry/Chemical Engineering ; Iron oxides ; Nanoparticles ; Organometallic Chemistry ; Palladium ; Palladium catalysts ; Physical Chemistry ; Silicon dioxide ; Substitution reactions</subject><ispartof>Catalysis letters, 2017-05, Vol.147 (5), p.1162-1171</ispartof><rights>Springer Science+Business Media New York 2017</rights><rights>COPYRIGHT 2017 Springer</rights><rights>Catalysis Letters is a copyright of Springer, (2017). All Rights Reserved.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c425t-e9bc855ed7d15b87b835a50ad8e9c5718aef51083fa99e60f97ed323d9f4696c3</citedby><cites>FETCH-LOGICAL-c425t-e9bc855ed7d15b87b835a50ad8e9c5718aef51083fa99e60f97ed323d9f4696c3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27903,27904</link.rule.ids></links><search><creatorcontrib>Sarvi, Iraj</creatorcontrib><creatorcontrib>Gholizadeh, Mostafa</creatorcontrib><creatorcontrib>Izadyar, Mohammad</creatorcontrib><title>Highly Dispersed Palladium Nanoparticle-Loaded Magnetic Catalyst (FeS@EP–AG–Pd) for Suzuki Reaction in Water</title><title>Catalysis letters</title><addtitle>Catal Lett</addtitle><description>In this work, an efficient epichlorohydrin–aminoguanidine-modified Fe
3
O
4
@SiO
2
magnetic nanoparticles (FeS@EP–AG–Pd) with highly dispersed Palladium nanoparticles (Pd NPs) was reported for Suzuki reaction in water. After preparation of Fe
3
O
4
@SiO
2
(FeS), special epichlorohydrin–aminoguanidine linker as a ligand with high content of heteroatoms was covalently bonded onto the FeS MNPs to increase their electron density. Pd
II
ions were then loaded on surface of FeS@EP–AG MNPs and reduced for achieving the uniformly dispersed Pd NPs. FeS@EP–AG–Pd MNPs were performed in Suzuki reaction as an efficient catalyst in water as a green non-toxic solvent. Magnetically separable and recyclable FeS@EP–AG–Pd MNPs were then fully characterized by FTIR, SEM, TEM, TGA, VSM, XRD, and ICP–OES. The heterogeneous catalyst could also easily be recovered and reused with no loss of activity over 6 cycles.
Graphical Abstract</description><subject>Catalysis</subject><subject>Catalysts</subject><subject>Chemical reactions</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Dispersion</subject><subject>Electron density</subject><subject>Epichlorohydrin</subject><subject>Epoxy resins</subject><subject>Industrial Chemistry/Chemical Engineering</subject><subject>Iron oxides</subject><subject>Nanoparticles</subject><subject>Organometallic Chemistry</subject><subject>Palladium</subject><subject>Palladium catalysts</subject><subject>Physical Chemistry</subject><subject>Silicon dioxide</subject><subject>Substitution reactions</subject><issn>1011-372X</issn><issn>1572-879X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2017</creationdate><recordtype>article</recordtype><recordid>eNp1kc9uFSEUhydGE2v1AdyRuNEFLTBlgJ03t3-TW72xNXZHzoUzV-rcYYSZxXXlO_QNfZLSjIkrQwLk8H0Hwq-q3nJ2xBlTx5kz2QjKuKKCMUPls-qASyWoVubuedkzzmmtxN3L6lXO96wwipuDargM2-_dnpyGPGDK6Mkaug58mHbkE_RxgDQG1yFdRfDl9Bq2PZYKWcII3T6P5P053nw8W__5_bC4KNPafyBtTORm-jX9COQLghtD7EnoyTcYMb2uXrTQZXzzdz2svp6f3S4v6erzxdVysaLuRMiRotk4LSV65bncaLXRtQTJwGs0TiquAVvJma5bMAYb1hqFvha1N-1JYxpXH1bv5r5Dij8nzKO9j1Pqy5VWCKm1NqZuCnU0U1vo0Ia-jWMCV4bHXXCxxzaU-kJKZiQrn1sEPgsuxZwTtnZIYQdpbzmzT0nYOQlbYPuUhJXFEbOTC9tvMf17yv-lR2XjjNs</recordid><startdate>20170501</startdate><enddate>20170501</enddate><creator>Sarvi, Iraj</creator><creator>Gholizadeh, Mostafa</creator><creator>Izadyar, Mohammad</creator><general>Springer US</general><general>Springer</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>AFKRA</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>KB.</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope></search><sort><creationdate>20170501</creationdate><title>Highly Dispersed Palladium Nanoparticle-Loaded Magnetic Catalyst (FeS@EP–AG–Pd) for Suzuki Reaction in Water</title><author>Sarvi, Iraj ; Gholizadeh, Mostafa ; Izadyar, Mohammad</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c425t-e9bc855ed7d15b87b835a50ad8e9c5718aef51083fa99e60f97ed323d9f4696c3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2017</creationdate><topic>Catalysis</topic><topic>Catalysts</topic><topic>Chemical reactions</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Dispersion</topic><topic>Electron density</topic><topic>Epichlorohydrin</topic><topic>Epoxy resins</topic><topic>Industrial Chemistry/Chemical Engineering</topic><topic>Iron oxides</topic><topic>Nanoparticles</topic><topic>Organometallic Chemistry</topic><topic>Palladium</topic><topic>Palladium catalysts</topic><topic>Physical Chemistry</topic><topic>Silicon dioxide</topic><topic>Substitution reactions</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Sarvi, Iraj</creatorcontrib><creatorcontrib>Gholizadeh, Mostafa</creatorcontrib><creatorcontrib>Izadyar, Mohammad</creatorcontrib><collection>CrossRef</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>SciTech Premium Collection</collection><collection>Materials Science Database</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><jtitle>Catalysis letters</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Sarvi, Iraj</au><au>Gholizadeh, Mostafa</au><au>Izadyar, Mohammad</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Highly Dispersed Palladium Nanoparticle-Loaded Magnetic Catalyst (FeS@EP–AG–Pd) for Suzuki Reaction in Water</atitle><jtitle>Catalysis letters</jtitle><stitle>Catal Lett</stitle><date>2017-05-01</date><risdate>2017</risdate><volume>147</volume><issue>5</issue><spage>1162</spage><epage>1171</epage><pages>1162-1171</pages><issn>1011-372X</issn><eissn>1572-879X</eissn><abstract>In this work, an efficient epichlorohydrin–aminoguanidine-modified Fe
3
O
4
@SiO
2
magnetic nanoparticles (FeS@EP–AG–Pd) with highly dispersed Palladium nanoparticles (Pd NPs) was reported for Suzuki reaction in water. After preparation of Fe
3
O
4
@SiO
2
(FeS), special epichlorohydrin–aminoguanidine linker as a ligand with high content of heteroatoms was covalently bonded onto the FeS MNPs to increase their electron density. Pd
II
ions were then loaded on surface of FeS@EP–AG MNPs and reduced for achieving the uniformly dispersed Pd NPs. FeS@EP–AG–Pd MNPs were performed in Suzuki reaction as an efficient catalyst in water as a green non-toxic solvent. Magnetically separable and recyclable FeS@EP–AG–Pd MNPs were then fully characterized by FTIR, SEM, TEM, TGA, VSM, XRD, and ICP–OES. The heterogeneous catalyst could also easily be recovered and reused with no loss of activity over 6 cycles.
Graphical Abstract</abstract><cop>New York</cop><pub>Springer US</pub><doi>10.1007/s10562-017-2009-5</doi><tpages>10</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1011-372X |
| ispartof | Catalysis letters, 2017-05, Vol.147 (5), p.1162-1171 |
| issn | 1011-372X 1572-879X |
| language | eng |
| recordid | cdi_proquest_journals_2258889936 |
| source | Springer Nature |
| subjects | Catalysis Catalysts Chemical reactions Chemistry Chemistry and Materials Science Dispersion Electron density Epichlorohydrin Epoxy resins Industrial Chemistry/Chemical Engineering Iron oxides Nanoparticles Organometallic Chemistry Palladium Palladium catalysts Physical Chemistry Silicon dioxide Substitution reactions |
| title | Highly Dispersed Palladium Nanoparticle-Loaded Magnetic Catalyst (FeS@EP–AG–Pd) for Suzuki Reaction in Water |
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