Vanadium (V) and Tungsten (VI) Oxoperoxo-Complexes Anchored on Fe3O4 Magnetic Nanoparticles: Versatile and Efficient Catalysts for the Oxidation of Alcohols and Sulfides

Vanadium (V) and tungsten (VI) oxoperoxo complexes supported on Fe 3 O 4 magnetic nanoparticles were synthesized and characterized. These compounds are assigned as catalyst 1 ( C1 : Fe 3 O 4 @Gly@r-Py@VO 3 ) and catalyst 2 ( C2 : Fe 3 O 4 @Gly@r-Py@WO 3 ), respectively, and were found to be efficien...

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Bibliographic Details
Published in:Catalysis letters 2017-08, Vol.147 (8), p.2106-2115
Main Authors: Eftekhari-Sis, Bagher, Akbari, Masoud, Akbari, Ali, Amini, Mojtaba
Format: Article
Language:English
Subjects:
Alcohol
Alcohols
Catalysis
Catalysts
Chemistry
Chemistry and Materials Science
Hydrogen peroxide
Industrial Chemistry/Chemical Engineering
Iron oxides
Nanoparticles
Organometallic Chemistry
Oxidation
Physical Chemistry
Sulfides
Tungsten
Vanadium
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Summary:Vanadium (V) and tungsten (VI) oxoperoxo complexes supported on Fe 3 O 4 magnetic nanoparticles were synthesized and characterized. These compounds are assigned as catalyst 1 ( C1 : Fe 3 O 4 @Gly@r-Py@VO 3 ) and catalyst 2 ( C2 : Fe 3 O 4 @Gly@r-Py@WO 3 ), respectively, and were found to be efficient and reusable heterogeneous catalysts for the oxidation of alcohols and sulfides using H 2 O 2 . Graphical Abstract
ISSN:1011-372X
1572-879X
DOI:10.1007/s10562-017-2102-9