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Molybdenum Oxoanions as Dispersing Agents in the Preparation of Pd/C Catalysts for the Selective Oxidation of Glyoxal
Catalysts Pd/C were prepared in the presence of Mo oxoanions. The size of Mo precursor and the electrostatic interactions with the Pd precursor during the synthesis were found to be responsible for high Pd dispersions. These catalysts were very active for glyoxal oxidation into glyoxalic acid. Graph...
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Published in: | Catalysis letters 2012-05, Vol.142 (5), p.521-530 |
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creator | Hermans, S. Thiltges, F. Deffernez, A. Devillers, M. |
description | Catalysts Pd/C were prepared in the presence of Mo oxoanions. The size of Mo precursor and the electrostatic interactions with the Pd precursor during the synthesis were found to be responsible for high Pd dispersions. These catalysts were very active for glyoxal oxidation into glyoxalic acid.
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doi_str_mv | 10.1007/s10562-012-0804-6 |
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Graphical Abstract</description><identifier>ISSN: 1011-372X</identifier><identifier>EISSN: 1572-879X</identifier><identifier>DOI: 10.1007/s10562-012-0804-6</identifier><language>eng</language><publisher>Boston: Springer US</publisher><subject>Catalysis ; Catalysts ; Chemical properties ; Chemistry ; Chemistry and Materials Science ; Exact sciences and technology ; General and physical chemistry ; Glyoxylic acid ; Industrial Chemistry/Chemical Engineering ; Molybdenum ; Organometallic Chemistry ; Oxidation ; Oxidation-reduction reaction ; Palladium ; Palladium catalysts ; Physical Chemistry ; Precursors ; Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry</subject><ispartof>Catalysis letters, 2012-05, Vol.142 (5), p.521-530</ispartof><rights>Springer Science+Business Media, LLC 2012</rights><rights>2015 INIST-CNRS</rights><rights>COPYRIGHT 2012 Springer</rights><rights>Catalysis Letters is a copyright of Springer, (2012). All Rights Reserved.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c419t-161f25ac772e2280313db2bd89691adc256b365fc35081cff158ce72e47650453</citedby><cites>FETCH-LOGICAL-c419t-161f25ac772e2280313db2bd89691adc256b365fc35081cff158ce72e47650453</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=25912435$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Hermans, S.</creatorcontrib><creatorcontrib>Thiltges, F.</creatorcontrib><creatorcontrib>Deffernez, A.</creatorcontrib><creatorcontrib>Devillers, M.</creatorcontrib><title>Molybdenum Oxoanions as Dispersing Agents in the Preparation of Pd/C Catalysts for the Selective Oxidation of Glyoxal</title><title>Catalysis letters</title><addtitle>Catal Lett</addtitle><description>Catalysts Pd/C were prepared in the presence of Mo oxoanions. The size of Mo precursor and the electrostatic interactions with the Pd precursor during the synthesis were found to be responsible for high Pd dispersions. These catalysts were very active for glyoxal oxidation into glyoxalic acid.
Graphical Abstract</description><subject>Catalysis</subject><subject>Catalysts</subject><subject>Chemical properties</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Exact sciences and technology</subject><subject>General and physical chemistry</subject><subject>Glyoxylic acid</subject><subject>Industrial Chemistry/Chemical Engineering</subject><subject>Molybdenum</subject><subject>Organometallic Chemistry</subject><subject>Oxidation</subject><subject>Oxidation-reduction reaction</subject><subject>Palladium</subject><subject>Palladium catalysts</subject><subject>Physical Chemistry</subject><subject>Precursors</subject><subject>Theory of reactions, general kinetics. Catalysis. 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Nomenclature, chemical documentation, computer chemistry</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Hermans, S.</creatorcontrib><creatorcontrib>Thiltges, F.</creatorcontrib><creatorcontrib>Deffernez, A.</creatorcontrib><creatorcontrib>Devillers, M.</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Gale In Context: Science</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central</collection><collection>SciTech Premium Collection</collection><collection>Materials Science Database</collection><collection>Materials science collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><jtitle>Catalysis letters</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Hermans, S.</au><au>Thiltges, F.</au><au>Deffernez, A.</au><au>Devillers, M.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Molybdenum Oxoanions as Dispersing Agents in the Preparation of Pd/C Catalysts for the Selective Oxidation of Glyoxal</atitle><jtitle>Catalysis letters</jtitle><stitle>Catal Lett</stitle><date>2012-05-01</date><risdate>2012</risdate><volume>142</volume><issue>5</issue><spage>521</spage><epage>530</epage><pages>521-530</pages><issn>1011-372X</issn><eissn>1572-879X</eissn><abstract>Catalysts Pd/C were prepared in the presence of Mo oxoanions. The size of Mo precursor and the electrostatic interactions with the Pd precursor during the synthesis were found to be responsible for high Pd dispersions. These catalysts were very active for glyoxal oxidation into glyoxalic acid.
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subjects | Catalysis Catalysts Chemical properties Chemistry Chemistry and Materials Science Exact sciences and technology General and physical chemistry Glyoxylic acid Industrial Chemistry/Chemical Engineering Molybdenum Organometallic Chemistry Oxidation Oxidation-reduction reaction Palladium Palladium catalysts Physical Chemistry Precursors Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry |
title | Molybdenum Oxoanions as Dispersing Agents in the Preparation of Pd/C Catalysts for the Selective Oxidation of Glyoxal |
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