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Coumarins Preparation by Pechmann Reaction Under Ultrasound Irradiation. Synthesis of Hymecromone as Insecticide Intermediate
Hymecromone, an important insecticide intermediate, were synthesized under solvent-free conditions by Pechmann reaction upon ultrasound irradiation in the presence of acid zeolites possessing different structural features. This methodology offers significant improvements for the synthesis of coumari...
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Published in: | Catalysis letters 2009-03, Vol.128 (3-4), p.318-322 |
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creator | Gutiérrez-Sánchez, C Calvino-Casilda, V Pérez-Mayoral, E Martín-Aranda, R. M López-Peinado, A. J Bejblová, M Čejka, J |
description | Hymecromone, an important insecticide intermediate, were synthesized under solvent-free conditions by Pechmann reaction upon ultrasound irradiation in the presence of acid zeolites possessing different structural features. This methodology offers significant improvements for the synthesis of coumarins with regards to yield of product, simplicity in operation, and avoiding toxic catalysts and solvents. |
doi_str_mv | 10.1007/s10562-008-9709-9 |
format | article |
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All Rights Reserved.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c370t-266fc39b4da02da7b9d221b8b335b2149107f750c1647a25ce972ce8edd98d453</citedby><cites>FETCH-LOGICAL-c370t-266fc39b4da02da7b9d221b8b335b2149107f750c1647a25ce972ce8edd98d453</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27901,27902</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=21217390$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Gutiérrez-Sánchez, C</creatorcontrib><creatorcontrib>Calvino-Casilda, V</creatorcontrib><creatorcontrib>Pérez-Mayoral, E</creatorcontrib><creatorcontrib>Martín-Aranda, R. M</creatorcontrib><creatorcontrib>López-Peinado, A. 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This methodology offers significant improvements for the synthesis of coumarins with regards to yield of product, simplicity in operation, and avoiding toxic catalysts and solvents.</description><subject>Catalysis</subject><subject>Chemical synthesis</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Exact sciences and technology</subject><subject>General and physical chemistry</subject><subject>Industrial Chemistry/Chemical Engineering</subject><subject>Insecticides</subject><subject>Ion-exchange</subject><subject>Irradiation</subject><subject>Organometallic Chemistry</subject><subject>Physical Chemistry</subject><subject>Solvents</subject><subject>Surface physical chemistry</subject><subject>Theory of reactions, general kinetics. Catalysis. 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Nomenclature, chemical documentation, computer chemistry</topic><topic>Ultrasonic imaging</topic><topic>Ultrasound</topic><topic>Zeolites</topic><topic>Zeolites: preparations and properties</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Gutiérrez-Sánchez, C</creatorcontrib><creatorcontrib>Calvino-Casilda, V</creatorcontrib><creatorcontrib>Pérez-Mayoral, E</creatorcontrib><creatorcontrib>Martín-Aranda, R. M</creatorcontrib><creatorcontrib>López-Peinado, A. 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subjects | Catalysis Chemical synthesis Chemistry Chemistry and Materials Science Exact sciences and technology General and physical chemistry Industrial Chemistry/Chemical Engineering Insecticides Ion-exchange Irradiation Organometallic Chemistry Physical Chemistry Solvents Surface physical chemistry Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry Ultrasonic imaging Ultrasound Zeolites Zeolites: preparations and properties |
title | Coumarins Preparation by Pechmann Reaction Under Ultrasound Irradiation. Synthesis of Hymecromone as Insecticide Intermediate |
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