Investigation of rhodium complexes in micro- and mesoporous materials by computer modeling, FTIR, and 31P MAS NMR

Tetracarbonyldichlororhodium(I) [Rh(CO)2(μ -Cl)]2 entrapped in faujasite type zeolites reacted with phosphines PMe3- xPhx at 393-463 K to a different extent. Although according to computational studies phosphines with x

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Bibliographic Details
Published in:Catalysis letters 1997-10, Vol.48 (3-4), p.165-171
Main Authors: JANSSEN, A, NIEDERER, J. P. M, HÖLDERICH, W. F
Format: Article
Language:English
Subjects:
Acetylacetone
Aluminum
Carbonyls
Catalysis
Catalysts: preparations and properties
Chemical bonds
Chemistry
Exact sciences and technology
General and physical chemistry
Infrared spectroscopy
NMR spectroscopy
Organic chemistry
Phosphines
Rhodium
Spectrum analysis
Synthesis
Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry
Zeolites
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Summary:Tetracarbonyldichlororhodium(I) [Rh(CO)2(μ -Cl)]2 entrapped in faujasite type zeolites reacted with phosphines PMe3- xPhx at 393-463 K to a different extent. Although according to computational studies phosphines with x
ISSN:1011-372X
1572-879X
DOI:10.1023/A:1019043508034