Preparation and characterization of the system NiMn2O4/TiO2 by sol–gel: application to the photodegradation of benzamide under visible light

• Published in: Journal of sol-gel science and technology 2018-03, Vol.85 (3), p.677-683
• Main Authors: Rekhila, Gharib, Gabes, Yamina, Brahimi, Razika, Bessekhouad, Yassine, Mahroua, Ousama, Trari, Mohamed
• Format: Article
• Language: English
• Subjects: Aeration; Benzamide; Ceramics; Chemistry and Materials Science; Composites; Conversion; Crystallization; Diffraction patterns; Dosage; Electron transfer; Glass; High performance liquid chromatography; Inorganic Chemistry; Light; Materials Science; Nanotechnology; Natural Materials; Optical and Electronic Materials; Original Paper: Sol-gel and hybrid materials for catalytic; Oxidation; Photodegradation; photoelectrochemical and sensor applications; Reaction kinetics; Sol-gel processes; Spinel; Titanium dioxide; Titanium oxides; X-ray diffraction
• ISSN: 0928-0707; 1573-4846
• DOI: 10.1007/s10971-018-4598-x

Benzamide is successfully degraded on the novel heterosystem NiMn 2 O 4 /TiO 2 under visible light. The nanosized spinel is synthesized by the sol–gel method at ~850 °C. The X-ray diffraction pattern shows narrow peaks and the oxides are well crystallized. The Mott–Schottky plot ( C −2 − E ) of NiMn 2 O 4 is characteristic of p -type conductivity from which a flat-band potential of −0.20 V SCE is obtained. The energy-band diagram, built from the physicochemical characterizations, predicts the electron transfer from the conduction to dissolved oxygen via TiO 2 . The loading of TiO 2 with NiMn 2 O 4 enhances the photoactivity and NiMn 2 O 4 islands achieve a colloidal photochemical heterosystem, tested successfully for the light-induced benzamide degradation. The spinel dose and benzamide concentration are optimized. Under the ideal conditions, the rate of the benzamide disappearance is controlled by high-performance liquid chromatography. A conversion of 85% is reported in aerated benzamide solution (15 ppm) in less than 2 h under artificial light. This conversion rate increases up to 94% under solar light and the oxidation obeys to a first-order kinetics with a half-life of 53 min. Photodegradation of benzamide on the heterosystem NiMn 2 O 4 /TiO 2 under visible light.