Intermediate structural state in Bi1−x Pr x FeO3 ceramics at the rhombohedral–orthorhombic phase boundary

Crystal structure of the Bi1−xPrxFeO3 ceramics of the compositions corresponding to the threshold concentrations separating the polar rhombohedral (R3c) and anti-polar orthorhombic (Pbam) phases has been investigated with X-ray diffraction, transmission electron microscopy and differential scanning...

Full description

Saved in:
Bibliographic Details
Published in:Journal of materials science 2017-08, Vol.52 (16), p.9355-9362
Main Authors: Karpinsky, D. V., Troyanchuk, I. O., Willinger, M., Khomchenko, V. A., Salak, A. N., Sikolenko, V., Silibin, M. V.
Format: Article
Language:English
Subjects:
Ceramics
Crystal structure
Differential scanning calorimetry
Materials science
Orthorhombic phase
Phase transitions
Scanning electron microscopy
Structural analysis
Transmission electron microscopy
X-ray diffraction
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
cited_by cdi_FETCH-LOGICAL-c1610-fc3f53fc207e7c33bf48b6e320463bd83fe1c555ae3c334aa02fed24fc19aa4e3
cites cdi_FETCH-LOGICAL-c1610-fc3f53fc207e7c33bf48b6e320463bd83fe1c555ae3c334aa02fed24fc19aa4e3
container_end_page 9362
container_issue 16
container_start_page 9355
container_title Journal of materials science
container_volume 52
creator Karpinsky, D. V.
Troyanchuk, I. O.
Willinger, M.
Khomchenko, V. A.
Salak, A. N.
Sikolenko, V.
Silibin, M. V.
description Crystal structure of the Bi1−xPrxFeO3 ceramics of the compositions corresponding to the threshold concentrations separating the polar rhombohedral (R3c) and anti-polar orthorhombic (Pbam) phases has been investigated with X-ray diffraction, transmission electron microscopy and differential scanning calorimetry measurements performed in a broad temperature range. The structural study specifies the peculiarities of the temperature-driven transition into the non-polar orthorhombic (Pnma) phase depending on the structural state of the compounds at room temperature. The crystal structure analysis reveals the revival of the anti-polar orthorhombic phase upon the temperature-induced transition, thus assuming that it can be considered as the bridge phase between the polar rhombohedral and the non-polar orthorhombic phases.
doi_str_mv 10.1007/s10853-017-1152-0
format article
fullrecord <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_2259524927</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2259524927</sourcerecordid><originalsourceid>FETCH-LOGICAL-c1610-fc3f53fc207e7c33bf48b6e320463bd83fe1c555ae3c334aa02fed24fc19aa4e3</originalsourceid><addsrcrecordid>eNotkL9OwzAQxi0EEqXwAGyWmA3nf0k6QkWhUqUywGw5zllJ1TTFdqSyMTLDG_ZJSCnTnb777r7Tj5BrDrccIL-LHAotGfCcca4FgxMy4jqXTBUgT8kIQAgmVMbPyUWMKwDQueAj0s43CUOLVWMT0phC71If7HpoD0KzoQ8N33997-hLoDs6w6WkDoNtGxepTTTVSEPdtWVXYzXs7T9_upDq7k9rHN3WNiItu35T2fBxSc68XUe8-q9j8jZ7fJ0-s8XyaT69XzDHMw7MO-m19E5AjrmTsvSqKDOUAlQmy6qQHrnTWluUw1RZC8JjJZR3fGKtQjkmN8e729C99xiTWXV92AyRRgg90UJNRD64-NHlQhdjQG-2oWmHNw0Hc6BqjlTNQNUcqBqQv04abYc</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2259524927</pqid></control><display><type>article</type><title>Intermediate structural state in Bi1−x Pr x FeO3 ceramics at the rhombohedral–orthorhombic phase boundary</title><source>Springer Nature</source><creator>Karpinsky, D. V. ; Troyanchuk, I. O. ; Willinger, M. ; Khomchenko, V. A. ; Salak, A. N. ; Sikolenko, V. ; Silibin, M. V.</creator><creatorcontrib>Karpinsky, D. V. ; Troyanchuk, I. O. ; Willinger, M. ; Khomchenko, V. A. ; Salak, A. N. ; Sikolenko, V. ; Silibin, M. V.</creatorcontrib><description>Crystal structure of the Bi1−xPrxFeO3 ceramics of the compositions corresponding to the threshold concentrations separating the polar rhombohedral (R3c) and anti-polar orthorhombic (Pbam) phases has been investigated with X-ray diffraction, transmission electron microscopy and differential scanning calorimetry measurements performed in a broad temperature range. The structural study specifies the peculiarities of the temperature-driven transition into the non-polar orthorhombic (Pnma) phase depending on the structural state of the compounds at room temperature. The crystal structure analysis reveals the revival of the anti-polar orthorhombic phase upon the temperature-induced transition, thus assuming that it can be considered as the bridge phase between the polar rhombohedral and the non-polar orthorhombic phases.</description><identifier>ISSN: 0022-2461</identifier><identifier>EISSN: 1573-4803</identifier><identifier>DOI: 10.1007/s10853-017-1152-0</identifier><language>eng</language><publisher>New York: Springer Nature B.V</publisher><subject>Ceramics ; Crystal structure ; Differential scanning calorimetry ; Materials science ; Orthorhombic phase ; Phase transitions ; Scanning electron microscopy ; Structural analysis ; Transmission electron microscopy ; X-ray diffraction</subject><ispartof>Journal of materials science, 2017-08, Vol.52 (16), p.9355-9362</ispartof><rights>Journal of Materials Science is a copyright of Springer, (2017). All Rights Reserved.</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c1610-fc3f53fc207e7c33bf48b6e320463bd83fe1c555ae3c334aa02fed24fc19aa4e3</citedby><cites>FETCH-LOGICAL-c1610-fc3f53fc207e7c33bf48b6e320463bd83fe1c555ae3c334aa02fed24fc19aa4e3</cites><orcidid>0000-0002-1046-543X</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27923,27924</link.rule.ids></links><search><creatorcontrib>Karpinsky, D. V.</creatorcontrib><creatorcontrib>Troyanchuk, I. O.</creatorcontrib><creatorcontrib>Willinger, M.</creatorcontrib><creatorcontrib>Khomchenko, V. A.</creatorcontrib><creatorcontrib>Salak, A. N.</creatorcontrib><creatorcontrib>Sikolenko, V.</creatorcontrib><creatorcontrib>Silibin, M. V.</creatorcontrib><title>Intermediate structural state in Bi1−x Pr x FeO3 ceramics at the rhombohedral–orthorhombic phase boundary</title><title>Journal of materials science</title><description>Crystal structure of the Bi1−xPrxFeO3 ceramics of the compositions corresponding to the threshold concentrations separating the polar rhombohedral (R3c) and anti-polar orthorhombic (Pbam) phases has been investigated with X-ray diffraction, transmission electron microscopy and differential scanning calorimetry measurements performed in a broad temperature range. The structural study specifies the peculiarities of the temperature-driven transition into the non-polar orthorhombic (Pnma) phase depending on the structural state of the compounds at room temperature. The crystal structure analysis reveals the revival of the anti-polar orthorhombic phase upon the temperature-induced transition, thus assuming that it can be considered as the bridge phase between the polar rhombohedral and the non-polar orthorhombic phases.</description><subject>Ceramics</subject><subject>Crystal structure</subject><subject>Differential scanning calorimetry</subject><subject>Materials science</subject><subject>Orthorhombic phase</subject><subject>Phase transitions</subject><subject>Scanning electron microscopy</subject><subject>Structural analysis</subject><subject>Transmission electron microscopy</subject><subject>X-ray diffraction</subject><issn>0022-2461</issn><issn>1573-4803</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2017</creationdate><recordtype>article</recordtype><recordid>eNotkL9OwzAQxi0EEqXwAGyWmA3nf0k6QkWhUqUywGw5zllJ1TTFdqSyMTLDG_ZJSCnTnb777r7Tj5BrDrccIL-LHAotGfCcca4FgxMy4jqXTBUgT8kIQAgmVMbPyUWMKwDQueAj0s43CUOLVWMT0phC71If7HpoD0KzoQ8N33997-hLoDs6w6WkDoNtGxepTTTVSEPdtWVXYzXs7T9_upDq7k9rHN3WNiItu35T2fBxSc68XUe8-q9j8jZ7fJ0-s8XyaT69XzDHMw7MO-m19E5AjrmTsvSqKDOUAlQmy6qQHrnTWluUw1RZC8JjJZR3fGKtQjkmN8e729C99xiTWXV92AyRRgg90UJNRD64-NHlQhdjQG-2oWmHNw0Hc6BqjlTNQNUcqBqQv04abYc</recordid><startdate>201708</startdate><enddate>201708</enddate><creator>Karpinsky, D. V.</creator><creator>Troyanchuk, I. O.</creator><creator>Willinger, M.</creator><creator>Khomchenko, V. A.</creator><creator>Salak, A. N.</creator><creator>Sikolenko, V.</creator><creator>Silibin, M. V.</creator><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>AFKRA</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>KB.</scope><scope>L6V</scope><scope>M7S</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope><scope>PTHSS</scope><orcidid>https://orcid.org/0000-0002-1046-543X</orcidid></search><sort><creationdate>201708</creationdate><title>Intermediate structural state in Bi1−x Pr x FeO3 ceramics at the rhombohedral–orthorhombic phase boundary</title><author>Karpinsky, D. V. ; Troyanchuk, I. O. ; Willinger, M. ; Khomchenko, V. A. ; Salak, A. N. ; Sikolenko, V. ; Silibin, M. V.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c1610-fc3f53fc207e7c33bf48b6e320463bd83fe1c555ae3c334aa02fed24fc19aa4e3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2017</creationdate><topic>Ceramics</topic><topic>Crystal structure</topic><topic>Differential scanning calorimetry</topic><topic>Materials science</topic><topic>Orthorhombic phase</topic><topic>Phase transitions</topic><topic>Scanning electron microscopy</topic><topic>Structural analysis</topic><topic>Transmission electron microscopy</topic><topic>X-ray diffraction</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Karpinsky, D. V.</creatorcontrib><creatorcontrib>Troyanchuk, I. O.</creatorcontrib><creatorcontrib>Willinger, M.</creatorcontrib><creatorcontrib>Khomchenko, V. A.</creatorcontrib><creatorcontrib>Salak, A. N.</creatorcontrib><creatorcontrib>Sikolenko, V.</creatorcontrib><creatorcontrib>Silibin, M. V.</creatorcontrib><collection>CrossRef</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science &amp; Engineering Collection</collection><collection>ProQuest Central</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central</collection><collection>SciTech Premium Collection</collection><collection>Materials Science Database</collection><collection>ProQuest Engineering Collection</collection><collection>Engineering Database</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><collection>Engineering Collection</collection><jtitle>Journal of materials science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Karpinsky, D. V.</au><au>Troyanchuk, I. O.</au><au>Willinger, M.</au><au>Khomchenko, V. A.</au><au>Salak, A. N.</au><au>Sikolenko, V.</au><au>Silibin, M. V.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Intermediate structural state in Bi1−x Pr x FeO3 ceramics at the rhombohedral–orthorhombic phase boundary</atitle><jtitle>Journal of materials science</jtitle><date>2017-08</date><risdate>2017</risdate><volume>52</volume><issue>16</issue><spage>9355</spage><epage>9362</epage><pages>9355-9362</pages><issn>0022-2461</issn><eissn>1573-4803</eissn><abstract>Crystal structure of the Bi1−xPrxFeO3 ceramics of the compositions corresponding to the threshold concentrations separating the polar rhombohedral (R3c) and anti-polar orthorhombic (Pbam) phases has been investigated with X-ray diffraction, transmission electron microscopy and differential scanning calorimetry measurements performed in a broad temperature range. The structural study specifies the peculiarities of the temperature-driven transition into the non-polar orthorhombic (Pnma) phase depending on the structural state of the compounds at room temperature. The crystal structure analysis reveals the revival of the anti-polar orthorhombic phase upon the temperature-induced transition, thus assuming that it can be considered as the bridge phase between the polar rhombohedral and the non-polar orthorhombic phases.</abstract><cop>New York</cop><pub>Springer Nature B.V</pub><doi>10.1007/s10853-017-1152-0</doi><tpages>8</tpages><orcidid>https://orcid.org/0000-0002-1046-543X</orcidid><oa>free_for_read</oa></addata></record>
fulltext fulltext
identifier ISSN: 0022-2461
ispartof Journal of materials science, 2017-08, Vol.52 (16), p.9355-9362
issn 0022-2461
1573-4803
language eng
recordid cdi_proquest_journals_2259524927
source Springer Nature
subjects Ceramics
Crystal structure
Differential scanning calorimetry
Materials science
Orthorhombic phase
Phase transitions
Scanning electron microscopy
Structural analysis
Transmission electron microscopy
X-ray diffraction
title Intermediate structural state in Bi1−x Pr x FeO3 ceramics at the rhombohedral–orthorhombic phase boundary
url http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-12T23%3A07%3A12IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Intermediate%20structural%20state%20in%20Bi1%E2%88%92x%20Pr%20x%20FeO3%20ceramics%20at%20the%20rhombohedral%E2%80%93orthorhombic%20phase%20boundary&rft.jtitle=Journal%20of%20materials%20science&rft.au=Karpinsky,%20D.%20V.&rft.date=2017-08&rft.volume=52&rft.issue=16&rft.spage=9355&rft.epage=9362&rft.pages=9355-9362&rft.issn=0022-2461&rft.eissn=1573-4803&rft_id=info:doi/10.1007/s10853-017-1152-0&rft_dat=%3Cproquest_cross%3E2259524927%3C/proquest_cross%3E%3Cgrp_id%3Ecdi_FETCH-LOGICAL-c1610-fc3f53fc207e7c33bf48b6e320463bd83fe1c555ae3c334aa02fed24fc19aa4e3%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_pqid=2259524927&rft_id=info:pmid/&rfr_iscdi=true