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Anionic NbO-type copper organic framework decorated with carboxylate groups for light hydrocarbons separation under ambient conditions
Light hydrocarbons are important raw materials for industrial products and fine chemicals. The storage and separation of C 1 –C 3 hydrocarbons are vital to their practical use. Here, we report efficient C 1 –C 3 hydrocarbon adsorption and separation with a NbO-type anionic copper metal–organic frame...
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| Published in: | Journal of materials science 2018-06, Vol.53 (12), p.8866-8877 |
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| Main Authors: | , , , , , , , , |
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| cites | cdi_FETCH-LOGICAL-c426t-fe99c734eb88e48f66afbf3f65a7515c469027a7f39ee847079167c5835100eb3 |
| container_end_page | 8877 |
| container_issue | 12 |
| container_start_page | 8866 |
| container_title | Journal of materials science |
| container_volume | 53 |
| creator | Liu, Xiuping Li, Xue Li, Jing Li, Guixia Guo, Sheng Zhu, Houyu Zhao, Lianming Hao, Chunlian Guo, Wenyue |
| description | Light hydrocarbons are important raw materials for industrial products and fine chemicals. The storage and separation of C
1
–C
3
hydrocarbons are vital to their practical use. Here, we report efficient C
1
–C
3
hydrocarbon adsorption and separation with a NbO-type anionic copper metal–organic framework with uncoordinated –COO
−
groups ([Cu
2
(
L
)·(H
2
O)
2
]·2H
2
O·3DMA·(CH
3
)
2
NH
2
) (
1
). Complex
1
exhibited large C
2
H
2
(190 cm
3
g
−1
), C
2
H
4
(147 cm
3
g
−1
), C
2
H
6
(156 cm
3
g
−1
), C
3
H
6
(170 cm
3
g
−1
), and C
3
H
8
(173 cm
3
g
−1
) uptakes and high selectivities for C
2
H
2
/CH
4
(32.3), C
3
H
6
/CH
4
(152), and C
3
H
8
/CH
4
(127) under ambient conditions. The excellent cycling performance of the material was reflected by only 9.2 and 10.9% losses of the C
2
H
2
and C
3
H
6
storage capacities even after ten cycles of adsorption–desorption tests. First-principles calculations and Grand canonical Monte Carlo simulations further revealed that not only the open metal sites but also the –COO
−
groups played a key role in the high C
2
–C
3
hydrocarbon uptakes. The results obtained in this study suggest that anionic
1
is a promising candidate for light hydrocarbon adsorption and natural gas purification at room temperature. |
| doi_str_mv | 10.1007/s10853-018-2155-1 |
| format | article |
| fullrecord | <record><control><sourceid>gale_proqu</sourceid><recordid>TN_cdi_proquest_journals_2259612667</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><galeid>A533612644</galeid><sourcerecordid>A533612644</sourcerecordid><originalsourceid>FETCH-LOGICAL-c426t-fe99c734eb88e48f66afbf3f65a7515c469027a7f39ee847079167c5835100eb3</originalsourceid><addsrcrecordid>eNp1kcuKFDEUhoMo2I4-gLuAKxc15p6qZTN4GRgc8LIOqdRJdcbuSpmkmOkX8LlNWYLMQrII_HxfziE_Qq8puaSE6HeZklbyhtC2YVTKhj5BOyo1b0RL-FO0I4SxhglFn6MXOd8RQqRmdId-7acQp-Dw5_62KecZsIvzDAnHNNo198me4D6mH3gAF5MtMOD7UA7Y2dTHh_OxJnhMcZkz9jHhYxgPBR_OQ4p_iCnjDLOtYp2Dl2mob9tTH2AqddQ0hDXPL9Ezb48ZXv29L9D3D--_XX1qbm4_Xl_tbxonmCqNh65zmgvo2xZE65WyvvfcK2m1pNIJ1RGmrfa8A2iFJrqjSjvZcll_CXp-gd5s784p_lwgF3MXlzTVkYYx2SnKlNKVutyo0R7BhMnHkqyrZ4BTqEuDDzXfS85XQYgqvH0kVKbAQxntkrO5_vrlMUs31qWYcwJv5hRONp0NJWbt0mxdmtqlWbs0tDpsc3JlpxHSv7X_L_0GaVGi2Q</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2259612667</pqid></control><display><type>article</type><title>Anionic NbO-type copper organic framework decorated with carboxylate groups for light hydrocarbons separation under ambient conditions</title><source>Springer Nature</source><creator>Liu, Xiuping ; Li, Xue ; Li, Jing ; Li, Guixia ; Guo, Sheng ; Zhu, Houyu ; Zhao, Lianming ; Hao, Chunlian ; Guo, Wenyue</creator><creatorcontrib>Liu, Xiuping ; Li, Xue ; Li, Jing ; Li, Guixia ; Guo, Sheng ; Zhu, Houyu ; Zhao, Lianming ; Hao, Chunlian ; Guo, Wenyue</creatorcontrib><description>Light hydrocarbons are important raw materials for industrial products and fine chemicals. The storage and separation of C
1
–C
3
hydrocarbons are vital to their practical use. Here, we report efficient C
1
–C
3
hydrocarbon adsorption and separation with a NbO-type anionic copper metal–organic framework with uncoordinated –COO
−
groups ([Cu
2
(
L
)·(H
2
O)
2
]·2H
2
O·3DMA·(CH
3
)
2
NH
2
) (
1
). Complex
1
exhibited large C
2
H
2
(190 cm
3
g
−1
), C
2
H
4
(147 cm
3
g
−1
), C
2
H
6
(156 cm
3
g
−1
), C
3
H
6
(170 cm
3
g
−1
), and C
3
H
8
(173 cm
3
g
−1
) uptakes and high selectivities for C
2
H
2
/CH
4
(32.3), C
3
H
6
/CH
4
(152), and C
3
H
8
/CH
4
(127) under ambient conditions. The excellent cycling performance of the material was reflected by only 9.2 and 10.9% losses of the C
2
H
2
and C
3
H
6
storage capacities even after ten cycles of adsorption–desorption tests. First-principles calculations and Grand canonical Monte Carlo simulations further revealed that not only the open metal sites but also the –COO
−
groups played a key role in the high C
2
–C
3
hydrocarbon uptakes. The results obtained in this study suggest that anionic
1
is a promising candidate for light hydrocarbon adsorption and natural gas purification at room temperature.</description><identifier>ISSN: 0022-2461</identifier><identifier>EISSN: 1573-4803</identifier><identifier>DOI: 10.1007/s10853-018-2155-1</identifier><language>eng</language><publisher>New York: Springer US</publisher><subject>Adsorption ; Characterization and Evaluation of Materials ; Chemical Routes to Materials ; Chemistry and Materials Science ; Classical Mechanics ; Computer simulation ; Copper ; Crystallography and Scattering Methods ; Fine chemicals ; First principles ; Hydrocarbons ; Materials Science ; Metal-organic frameworks ; Methane ; Monte Carlo methods ; Natural gas ; Niobium oxides ; Organic chemistry ; Polymer Sciences ; Raw materials ; Separation ; Solid Mechanics ; Surface active agents</subject><ispartof>Journal of materials science, 2018-06, Vol.53 (12), p.8866-8877</ispartof><rights>Springer Science+Business Media, LLC, part of Springer Nature 2018</rights><rights>COPYRIGHT 2018 Springer</rights><rights>Journal of Materials Science is a copyright of Springer, (2018). All Rights Reserved.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c426t-fe99c734eb88e48f66afbf3f65a7515c469027a7f39ee847079167c5835100eb3</citedby><cites>FETCH-LOGICAL-c426t-fe99c734eb88e48f66afbf3f65a7515c469027a7f39ee847079167c5835100eb3</cites><orcidid>0000-0002-9304-260X ; 0000-0002-4935-3750 ; 0000-0003-4651-8131 ; 0000-0002-2512-9834 ; 0000-0002-7537-984X ; 0000-0001-9869-3615 ; 0000-0002-5084-2711 ; 0000-0002-1102-2163 ; 0000-0002-7706-1843</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Liu, Xiuping</creatorcontrib><creatorcontrib>Li, Xue</creatorcontrib><creatorcontrib>Li, Jing</creatorcontrib><creatorcontrib>Li, Guixia</creatorcontrib><creatorcontrib>Guo, Sheng</creatorcontrib><creatorcontrib>Zhu, Houyu</creatorcontrib><creatorcontrib>Zhao, Lianming</creatorcontrib><creatorcontrib>Hao, Chunlian</creatorcontrib><creatorcontrib>Guo, Wenyue</creatorcontrib><title>Anionic NbO-type copper organic framework decorated with carboxylate groups for light hydrocarbons separation under ambient conditions</title><title>Journal of materials science</title><addtitle>J Mater Sci</addtitle><description>Light hydrocarbons are important raw materials for industrial products and fine chemicals. The storage and separation of C
1
–C
3
hydrocarbons are vital to their practical use. Here, we report efficient C
1
–C
3
hydrocarbon adsorption and separation with a NbO-type anionic copper metal–organic framework with uncoordinated –COO
−
groups ([Cu
2
(
L
)·(H
2
O)
2
]·2H
2
O·3DMA·(CH
3
)
2
NH
2
) (
1
). Complex
1
exhibited large C
2
H
2
(190 cm
3
g
−1
), C
2
H
4
(147 cm
3
g
−1
), C
2
H
6
(156 cm
3
g
−1
), C
3
H
6
(170 cm
3
g
−1
), and C
3
H
8
(173 cm
3
g
−1
) uptakes and high selectivities for C
2
H
2
/CH
4
(32.3), C
3
H
6
/CH
4
(152), and C
3
H
8
/CH
4
(127) under ambient conditions. The excellent cycling performance of the material was reflected by only 9.2 and 10.9% losses of the C
2
H
2
and C
3
H
6
storage capacities even after ten cycles of adsorption–desorption tests. First-principles calculations and Grand canonical Monte Carlo simulations further revealed that not only the open metal sites but also the –COO
−
groups played a key role in the high C
2
–C
3
hydrocarbon uptakes. The results obtained in this study suggest that anionic
1
is a promising candidate for light hydrocarbon adsorption and natural gas purification at room temperature.</description><subject>Adsorption</subject><subject>Characterization and Evaluation of Materials</subject><subject>Chemical Routes to Materials</subject><subject>Chemistry and Materials Science</subject><subject>Classical Mechanics</subject><subject>Computer simulation</subject><subject>Copper</subject><subject>Crystallography and Scattering Methods</subject><subject>Fine chemicals</subject><subject>First principles</subject><subject>Hydrocarbons</subject><subject>Materials Science</subject><subject>Metal-organic frameworks</subject><subject>Methane</subject><subject>Monte Carlo methods</subject><subject>Natural gas</subject><subject>Niobium oxides</subject><subject>Organic chemistry</subject><subject>Polymer Sciences</subject><subject>Raw materials</subject><subject>Separation</subject><subject>Solid Mechanics</subject><subject>Surface active agents</subject><issn>0022-2461</issn><issn>1573-4803</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><recordid>eNp1kcuKFDEUhoMo2I4-gLuAKxc15p6qZTN4GRgc8LIOqdRJdcbuSpmkmOkX8LlNWYLMQrII_HxfziE_Qq8puaSE6HeZklbyhtC2YVTKhj5BOyo1b0RL-FO0I4SxhglFn6MXOd8RQqRmdId-7acQp-Dw5_62KecZsIvzDAnHNNo198me4D6mH3gAF5MtMOD7UA7Y2dTHh_OxJnhMcZkz9jHhYxgPBR_OQ4p_iCnjDLOtYp2Dl2mob9tTH2AqddQ0hDXPL9Ezb48ZXv29L9D3D--_XX1qbm4_Xl_tbxonmCqNh65zmgvo2xZE65WyvvfcK2m1pNIJ1RGmrfa8A2iFJrqjSjvZcll_CXp-gd5s784p_lwgF3MXlzTVkYYx2SnKlNKVutyo0R7BhMnHkqyrZ4BTqEuDDzXfS85XQYgqvH0kVKbAQxntkrO5_vrlMUs31qWYcwJv5hRONp0NJWbt0mxdmtqlWbs0tDpsc3JlpxHSv7X_L_0GaVGi2Q</recordid><startdate>20180601</startdate><enddate>20180601</enddate><creator>Liu, Xiuping</creator><creator>Li, Xue</creator><creator>Li, Jing</creator><creator>Li, Guixia</creator><creator>Guo, Sheng</creator><creator>Zhu, Houyu</creator><creator>Zhao, Lianming</creator><creator>Hao, Chunlian</creator><creator>Guo, Wenyue</creator><general>Springer US</general><general>Springer</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>ISR</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>AFKRA</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>KB.</scope><scope>L6V</scope><scope>M7S</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PTHSS</scope><orcidid>https://orcid.org/0000-0002-9304-260X</orcidid><orcidid>https://orcid.org/0000-0002-4935-3750</orcidid><orcidid>https://orcid.org/0000-0003-4651-8131</orcidid><orcidid>https://orcid.org/0000-0002-2512-9834</orcidid><orcidid>https://orcid.org/0000-0002-7537-984X</orcidid><orcidid>https://orcid.org/0000-0001-9869-3615</orcidid><orcidid>https://orcid.org/0000-0002-5084-2711</orcidid><orcidid>https://orcid.org/0000-0002-1102-2163</orcidid><orcidid>https://orcid.org/0000-0002-7706-1843</orcidid></search><sort><creationdate>20180601</creationdate><title>Anionic NbO-type copper organic framework decorated with carboxylate groups for light hydrocarbons separation under ambient conditions</title><author>Liu, Xiuping ; Li, Xue ; Li, Jing ; Li, Guixia ; Guo, Sheng ; Zhu, Houyu ; Zhao, Lianming ; Hao, Chunlian ; Guo, Wenyue</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c426t-fe99c734eb88e48f66afbf3f65a7515c469027a7f39ee847079167c5835100eb3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2018</creationdate><topic>Adsorption</topic><topic>Characterization and Evaluation of Materials</topic><topic>Chemical Routes to Materials</topic><topic>Chemistry and Materials Science</topic><topic>Classical Mechanics</topic><topic>Computer simulation</topic><topic>Copper</topic><topic>Crystallography and Scattering Methods</topic><topic>Fine chemicals</topic><topic>First principles</topic><topic>Hydrocarbons</topic><topic>Materials Science</topic><topic>Metal-organic frameworks</topic><topic>Methane</topic><topic>Monte Carlo methods</topic><topic>Natural gas</topic><topic>Niobium oxides</topic><topic>Organic chemistry</topic><topic>Polymer Sciences</topic><topic>Raw materials</topic><topic>Separation</topic><topic>Solid Mechanics</topic><topic>Surface active agents</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Liu, Xiuping</creatorcontrib><creatorcontrib>Li, Xue</creatorcontrib><creatorcontrib>Li, Jing</creatorcontrib><creatorcontrib>Li, Guixia</creatorcontrib><creatorcontrib>Guo, Sheng</creatorcontrib><creatorcontrib>Zhu, Houyu</creatorcontrib><creatorcontrib>Zhao, Lianming</creatorcontrib><creatorcontrib>Hao, Chunlian</creatorcontrib><creatorcontrib>Guo, Wenyue</creatorcontrib><collection>CrossRef</collection><collection>Gale In Context: Science</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central</collection><collection>AUTh Library subscriptions: ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central</collection><collection>SciTech Premium Collection</collection><collection>https://resources.nclive.org/materials</collection><collection>ProQuest Engineering Collection</collection><collection>ProQuest Engineering Database</collection><collection>Materials science collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>Engineering collection</collection><jtitle>Journal of materials science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Liu, Xiuping</au><au>Li, Xue</au><au>Li, Jing</au><au>Li, Guixia</au><au>Guo, Sheng</au><au>Zhu, Houyu</au><au>Zhao, Lianming</au><au>Hao, Chunlian</au><au>Guo, Wenyue</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Anionic NbO-type copper organic framework decorated with carboxylate groups for light hydrocarbons separation under ambient conditions</atitle><jtitle>Journal of materials science</jtitle><stitle>J Mater Sci</stitle><date>2018-06-01</date><risdate>2018</risdate><volume>53</volume><issue>12</issue><spage>8866</spage><epage>8877</epage><pages>8866-8877</pages><issn>0022-2461</issn><eissn>1573-4803</eissn><abstract>Light hydrocarbons are important raw materials for industrial products and fine chemicals. The storage and separation of C
1
–C
3
hydrocarbons are vital to their practical use. Here, we report efficient C
1
–C
3
hydrocarbon adsorption and separation with a NbO-type anionic copper metal–organic framework with uncoordinated –COO
−
groups ([Cu
2
(
L
)·(H
2
O)
2
]·2H
2
O·3DMA·(CH
3
)
2
NH
2
) (
1
). Complex
1
exhibited large C
2
H
2
(190 cm
3
g
−1
), C
2
H
4
(147 cm
3
g
−1
), C
2
H
6
(156 cm
3
g
−1
), C
3
H
6
(170 cm
3
g
−1
), and C
3
H
8
(173 cm
3
g
−1
) uptakes and high selectivities for C
2
H
2
/CH
4
(32.3), C
3
H
6
/CH
4
(152), and C
3
H
8
/CH
4
(127) under ambient conditions. The excellent cycling performance of the material was reflected by only 9.2 and 10.9% losses of the C
2
H
2
and C
3
H
6
storage capacities even after ten cycles of adsorption–desorption tests. First-principles calculations and Grand canonical Monte Carlo simulations further revealed that not only the open metal sites but also the –COO
−
groups played a key role in the high C
2
–C
3
hydrocarbon uptakes. The results obtained in this study suggest that anionic
1
is a promising candidate for light hydrocarbon adsorption and natural gas purification at room temperature.</abstract><cop>New York</cop><pub>Springer US</pub><doi>10.1007/s10853-018-2155-1</doi><tpages>12</tpages><orcidid>https://orcid.org/0000-0002-9304-260X</orcidid><orcidid>https://orcid.org/0000-0002-4935-3750</orcidid><orcidid>https://orcid.org/0000-0003-4651-8131</orcidid><orcidid>https://orcid.org/0000-0002-2512-9834</orcidid><orcidid>https://orcid.org/0000-0002-7537-984X</orcidid><orcidid>https://orcid.org/0000-0001-9869-3615</orcidid><orcidid>https://orcid.org/0000-0002-5084-2711</orcidid><orcidid>https://orcid.org/0000-0002-1102-2163</orcidid><orcidid>https://orcid.org/0000-0002-7706-1843</orcidid></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0022-2461 |
| ispartof | Journal of materials science, 2018-06, Vol.53 (12), p.8866-8877 |
| issn | 0022-2461 1573-4803 |
| language | eng |
| recordid | cdi_proquest_journals_2259612667 |
| source | Springer Nature |
| subjects | Adsorption Characterization and Evaluation of Materials Chemical Routes to Materials Chemistry and Materials Science Classical Mechanics Computer simulation Copper Crystallography and Scattering Methods Fine chemicals First principles Hydrocarbons Materials Science Metal-organic frameworks Methane Monte Carlo methods Natural gas Niobium oxides Organic chemistry Polymer Sciences Raw materials Separation Solid Mechanics Surface active agents |
| title | Anionic NbO-type copper organic framework decorated with carboxylate groups for light hydrocarbons separation under ambient conditions |
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