Characterization of phases in the V2O5–Yb2O3 system obtained by high-energy ball milling and high-temperature treatment

It has been demonstrated that apart from the known compounds YbVO 4 and Yb 8 V 2 O 17 , a substitutive solid solution is also formed in the binary oxide system V 2 O 5 –Yb 2 O 3 . This solid solution is characterized by limited solubility of vanadium(V) oxide in the crystal lattice of ytterbium oxid...

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Bibliographic Details
Published in:Journal of materials science 2018-10, Vol.53 (19), p.13491-13500
Main Authors: Piz, M., Dulian, P., Filipek, E., Wieczorek-Ciurowa, K., Kochmanski, P.
Format: Article
Language:English
Subjects:
Ball milling
Characterization and Evaluation of Materials
Chemistry and Materials Science
Classical Mechanics
Crystal lattices
Crystallography and Scattering Methods
Direct reduction
Energy gap
High temperature
Materials Science
Mechanochemical Synthesis
Polymer Sciences
Solid Mechanics
Solid solutions
Vanadium pentoxide
Ytterbium
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Summary:It has been demonstrated that apart from the known compounds YbVO 4 and Yb 8 V 2 O 17 , a substitutive solid solution is also formed in the binary oxide system V 2 O 5 –Yb 2 O 3 . This solid solution is characterized by limited solubility of vanadium(V) oxide in the crystal lattice of ytterbium oxide, and its general formula is Yb 2−5 x □ 2 x V 3 x O 3 , where 0.00 
ISSN:0022-2461
1573-4803
DOI:10.1007/s10853-018-2449-3