Catalytic and catalytic free process for cellulose conversion: fast pyrolysis and microwave induced pyrolysis studies

• Published in: Cellulose (London) 2015-02, Vol.22 (1), p.215-228
• Main Authors: Nieva, María Luz, Volpe, María Alicia, Moyano, Elizabeth Laura
• Format: Article
• Language: English
• Subjects: Aluminum; Aromatic hydrocarbons; biofuels; Bioorganic Chemistry; Catalysts; Catalytic converters; Cellulose; Ceramics; Cerium oxides; Chemical industry; Chemistry; Chemistry and Materials Science; Composites; Crystalline cellulose; Glass; Iron; Natural Materials; Niobium oxides; Organic Chemistry; Original Paper; Phosphoric acid; Physical Chemistry; Polymer Sciences; Pyrolysis; silica; Silicon dioxide; surface area; Sustainable Development
• ISSN: 0969-0239; 1572-882X
• DOI: 10.1007/s10570-014-0484-z

The catalytic and non-catalytic pyrolysis of microcrystalline cellulose and phosphoric acid pre-treated cellulose was investigated. The thermal processes were carried out applying two different methodologies: conventional fast pyrolysis and microwave-induced pyrolysis. For the catalytic experiments different catalysts were evaluated: CeO₂, Nb₂O₅, SiO₂, high surface area SiO₂, Si-MCM-48 and Al-Fe-MCM-48. In all cases the liquid fraction was evaluated by quantifying the yields of anhydrosugars (mainly levoglucosan, levoglucosenone and 1,4:3,6-dianhydro-α-D-glucopyranose) and aromatic hydrocarbons. In the reaction of microcrystalline cellulose levoglucosan was the main product, while levoglucosenone was predominant in the pyrolysis of phosphoric acid pre-treated cellulose. Catalysts improved the fraction of bio-oil and the product distribution depended on the nature of catalytic materials as well as the starting cellulose. On the other hand, the microwave induced pyrolysis favored the formation of char at expenses of liquid fraction. In this case levoglucosenone and other anhydrosugars in conjunction with furan compounds were the main products.