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Optimizing the physical properties of cobalt/graphene nanocomposites for technological applications
Cobalt nanoferrites with formula CoFe 2 O 4 , and CoFe 2 O 4 /GR were synthesized using a citrate auto-combustion method. The prepared samples were characterized by X-ray diffraction, scanning electron microscopy (SEM) and the Fourier-transform infrared (FTIR) spectroscopy. The dependence of structu...
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Published in: | Applied physics. A, Materials science & processing Materials science & processing, 2019-08, Vol.125 (8), p.1-8, Article 516 |
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Main Authors: | , , , , |
Format: | Article |
Language: | English |
Subjects: | |
Citations: | Items that this one cites Items that cite this one |
Online Access: | Get full text |
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Summary: | Cobalt nanoferrites with formula CoFe
2
O
4
, and CoFe
2
O
4
/GR were synthesized using a citrate auto-combustion method. The prepared samples were characterized by X-ray diffraction, scanning electron microscopy (SEM) and the Fourier-transform infrared (FTIR) spectroscopy. The dependence of structure, magnetic and optical properties of cobalt/graphene nanocomposites on the graphene content was studied. The obtained data show that the CoFe
2
O
4
nanoparticles are homogenously decorated on the graphene layers, which act as magnetically inactive layers in turn affecting the magnetization. The high coercivity
H
c
values reflect that CoFe
2
O
4
/GR nanocomposites are hard magnets at room temperature. The energy band gap of the cobalt/graphene is estimated using Kubelka–Munk equation. The energy gap of the investigated nanocomposites was found about 1.4 eV for direct transition. The samples with high saturation magnetization values can affect by the external magnetic field, which is favorable to their application in high adsorption capacity. |
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ISSN: | 0947-8396 1432-0630 |
DOI: | 10.1007/s00339-019-2815-2 |