Probing the surface polarity of native celluloses using genuine solvatochromic dyes

• Published in: Cellulose (London) 2002-03, Vol.9 (1), p.31-40
• Main Authors: fischer, Kristin, Spange, Stefan, Fischer, Steffen, Bellmann, Cornelia, Adams, Jörg
• Format: Article
• Language: English
• Subjects: Basicity; Cellulose; Crystal structure; Crystallinity; Degree of crystallinity; Dyes; Fluorescence; Hydrogen bonds; Iron; Parameters; Polarity; Solvation
• ISSN: 0969-0239; 1572-882X
• DOI: 10.1023/A:1015896629947

The surface polarity of native celluloses has been investigated by the following solvatochromic dyes: dicyano-bis (1,10)-phenanthroline iron (II) Fe(phen)2 (CN)2 (1), bis(4-N,N-dimethylamino)-benzophenone (2), and cou-marine 153 (3). Linear Solvation Energy (LSE) relationships and the UV/Vis data have been used to characterize the surface polarity of different native cellulose batches in terms of the empirical Kamlet–Taft polarity parameters α (hydrogen bond acidity), β (hydrogen bond basicity), and π * (dipolarity/polarizability). α, β, π *and calculated Reichardt's E T (30) values are reported for various native and regenerated cellulose samples with different degrees of crystallinity. The degree of crystallinity of the cellulose samples has been determined by X-ray. The microcrystalline environment of cellulose can be exactly parameterized in terms of the α, β and π *values. It shows a fairly strong acidity α and a low dipolarity/polarizability. For the amorphous sections smaller α and larger π * values are observed. The correspondence of the empirical polarity parameters determined has been discussed in relation to results from pyrene fluorescence and zetapotential measurements.