Instantaneous detection of explosive and toxic nitroaromatic compounds via donor–acceptor complexation

• Published in: Journal of materials chemistry. C, Materials for optical and electronic devices Materials for optical and electronic devices, 2019, Vol.7 (30), p.9257-9262
• Main Authors: Lee, Inkyu, Kwon, Ji Eon, You, Chungsuk, Kang, Yeongkwon, Kim, Bong-Gi
• Format: Article
• Language: English
• Subjects: Aromatic compounds; Carbazoles; Chemical compounds; Chemical sensors; Chemoreceptors; Complex formation; Emission analysis; Explosives detection; Fluorescence; NMR spectroscopy; Quenching; Selectivity; Sensitivity; Spectrum analysis; Steric effects
• ISSN: 2050-7526; 2050-7534
• DOI: 10.1039/C9TC02401H

Designed carbazole-based novel fluorophores ( TPCA0M and TPCA6M ) exhibit a sensitive response to toxic and explosive nitroaromatic compounds (NACs) via complex formation, and their detection sensitivity or selectivity can be demonstrated by comparing their emission-quenching rate constant or the adoption of similar-structured aromatic compounds as a negative control. The results of time-resolved fluorescence spectroscopy indicate that the static quenching mechanism is involved in NAC detection. In addition, it has been demonstrated by UV-visible and 1 H-NMR spectroscopy studies that the emission quenching of the devised fluorophores originated from complex formation with NACs. The difference in the detection sensitivity of the fluorophores for the corresponding NACs can be connected to both the different steric effects of the fluorophores and the degree of energy off-set between the fluorophores and the NACs. A porous membrane-type detection platform, fabricated with TPCA0M , was found to be effective even at a TNT concentration of 1 ppb within 5 s, which reflects both the instantaneous detection capability and the exceptional sensitivity of the designed fluorometric chemosensors.