Specific Features of Thermochemically Initiated Radical Copolymerization of Mixtures of Methacrylic Monomers in the Presence of Dissolved Polyvinyl Butyral

Thermochemically initiated radical copolymerization of a mixture of di(1-methacryloxy-3-chloropropoxy-2-)methylphosphonate (FOM-II) and 2-hydroxypropyl methacrylate in the bulk in the presence of 1–10 wt % dissolved polyvinyl butyral was studied. The process is characterized by two and more self-acc...

Full description

Saved in:
Bibliographic Details
Published in:Russian journal of applied chemistry 2019-06, Vol.92 (6), p.787-795
Main Authors: Novakov, I. A., Vaniev, M. A., Borisov, S. V., Sidorenko, N. V., Kochnov, A. B., Bakhtina, G. D.
Format: Article
Language:English
Subjects:
Acceleration
Chemical industry
Chemistry
Chemistry and Materials Science
Chemistry/Food Science
Copolymerization
Hydroxypropyl methacrylate
Industrial Chemistry/Chemical Engineering
Macromolecular Compounds and Polymeric Materials
Macromolecules
Monomers
Polymerization
Polyvinyl acetal resins
Polyvinyl butyral
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:Thermochemically initiated radical copolymerization of a mixture of di(1-methacryloxy-3-chloropropoxy-2-)methylphosphonate (FOM-II) and 2-hydroxypropyl methacrylate in the bulk in the presence of 1–10 wt % dissolved polyvinyl butyral was studied. The process is characterized by two and more self-acceleration periods. This is associated with specific features of FOM-II polymerization transformations and with the presence of polyvinyl butyral macromolecules capable of association with methacrylic monomer molecules in the polymerizing system.
ISSN:1070-4272
1608-3296
DOI:10.1134/S1070427219060089