Specific Features of Thermochemically Initiated Radical Copolymerization of Mixtures of Methacrylic Monomers in the Presence of Dissolved Polyvinyl Butyral

Thermochemically initiated radical copolymerization of a mixture of di(1-methacryloxy-3-chloropropoxy-2-)methylphosphonate (FOM-II) and 2-hydroxypropyl methacrylate in the bulk in the presence of 1–10 wt % dissolved polyvinyl butyral was studied. The process is characterized by two and more self-acc...

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Published in:Russian journal of applied chemistry 2019-06, Vol.92 (6), p.787-795
Main Authors: Novakov, I. A., Vaniev, M. A., Borisov, S. V., Sidorenko, N. V., Kochnov, A. B., Bakhtina, G. D.
Format: Article
Language:English
Subjects:
Acceleration
Chemical industry
Chemistry
Chemistry and Materials Science
Chemistry/Food Science
Copolymerization
Hydroxypropyl methacrylate
Industrial Chemistry/Chemical Engineering
Macromolecular Compounds and Polymeric Materials
Macromolecules
Monomers
Polymerization
Polyvinyl acetal resins
Polyvinyl butyral
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container_title Russian journal of applied chemistry
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description Thermochemically initiated radical copolymerization of a mixture of di(1-methacryloxy-3-chloropropoxy-2-)methylphosphonate (FOM-II) and 2-hydroxypropyl methacrylate in the bulk in the presence of 1–10 wt % dissolved polyvinyl butyral was studied. The process is characterized by two and more self-acceleration periods. This is associated with specific features of FOM-II polymerization transformations and with the presence of polyvinyl butyral macromolecules capable of association with methacrylic monomer molecules in the polymerizing system.
doi_str_mv 10.1134/S1070427219060089
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source Springer Nature
subjects Acceleration
Chemical industry
Chemistry
Chemistry and Materials Science
Chemistry/Food Science
Copolymerization
Hydroxypropyl methacrylate
Industrial Chemistry/Chemical Engineering
Macromolecular Compounds and Polymeric Materials
Macromolecules
Monomers
Polymerization
Polyvinyl acetal resins
Polyvinyl butyral
title Specific Features of Thermochemically Initiated Radical Copolymerization of Mixtures of Methacrylic Monomers in the Presence of Dissolved Polyvinyl Butyral
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