Stabilization of Cerium(III) in the Structure of Hydrotalcite-Like Layered Double Hydroxides

This research is devoted to the preparation of cerium-containing layered double hydroxides (LDHs) and exploring the possibility of stabilizing cerium in the unstable valence state (III) in their structure. It has been shown that the best result is achieved in the case of using hydrothermal treatment...

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Bibliographic Details
Published in:Petroleum chemistry 2019-07, Vol.59 (7), p.751-755
Main Authors: Lebedeva, O. E., Ryl’tsova, I. G., Yapryntsev, M. N., Golovin, S. N., Veligzhanin, A. A.
Format: Article
Language:English
Subjects:
Cerium
Chemistry
Chemistry and Materials Science
Hydrothermal treatment
Hydroxides
Industrial Chemistry/Chemical Engineering
Synthesis
Valence
X ray absorption
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Summary:This research is devoted to the preparation of cerium-containing layered double hydroxides (LDHs) and exploring the possibility of stabilizing cerium in the unstable valence state (III) in their structure. It has been shown that the best result is achieved in the case of using hydrothermal treatment in the synthesis process. A sample of an LDH obtained via this method possesses characteristics typical for this class of compounds, as has been demonstrated using a set of instrumental methods (XRD, IR, TG–DSC). It has been proved by cerium L 3 -edge X-ray absorption spectroscopy that cerium is only partially oxidized to Ce(IV) during the synthesis process.
ISSN:0965-5441
1555-6239
DOI:10.1134/S0965544119070089