Loading…
Methyl palmitate hydrodeoxygenation over silica‐supported nickel phosphide catalysts in flow reactor: experimental and kinetic study
BACKGROUND The search for alternative sources of fuels is crucial for sustainable development now and in the near future. Biomass attracts much attention as an environmentally friendly, green and CO2‐neutral source of fuels. Hydrodeoxygenation (HDO) of fatty acid‐based feedstocks such as nonedible v...
Saved in:
| Published in: | Journal of chemical technology and biotechnology (1986) 2019-09, Vol.94 (9), p.3007-3019 |
|---|---|
| Main Authors: | , , , , |
| Format: | Article |
| Language: | English |
| Subjects: | |
| Citations: | Items that this one cites Items that cite this one |
| Online Access: | Get full text |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
| cited_by | cdi_FETCH-LOGICAL-c3341-b070f6695f328ad1cf85499c4d673c9d6890082c4b00586f4e397dd5443039033 |
|---|---|
| cites | cdi_FETCH-LOGICAL-c3341-b070f6695f328ad1cf85499c4d673c9d6890082c4b00586f4e397dd5443039033 |
| container_end_page | 3019 |
| container_issue | 9 |
| container_start_page | 3007 |
| container_title | Journal of chemical technology and biotechnology (1986) |
| container_volume | 94 |
| creator | Shamanaev, Ivan V Deliy, Irina V Aleksandrov, Pavel V Reshetnikov, Sergey I Bukhtiyarova, Galina A |
| description | BACKGROUND
The search for alternative sources of fuels is crucial for sustainable development now and in the near future. Biomass attracts much attention as an environmentally friendly, green and CO2‐neutral source of fuels. Hydrodeoxygenation (HDO) of fatty acid‐based feedstocks such as nonedible vegetable oil, waste cooking oil and animal fat is a versatile technology for producing efficient fuels. HDO schemes are often contradictory and have different numbers of stages. In the work reported, a highly active nickel phosphide catalyst was obtained and methyl palmitate (MP) HDO kinetic modelling was carried out to elucidate the HDO reaction scheme.
RESULTS
The effect of reduction temperature (400–600 °C) on the catalytic properties of the catalyst in MP HDO was evaluated and the most active catalyst (after reduction at 450 °C) was used in the kinetic experiments. The experimental data were collected in a wide range of MP conversion. The reaction scheme of MP HDO was elucidated by means of mathematical modelling which was specified by successive consideration of the experimental results of HDO selectivities at low MP conversions (1–10%), additional experiments of alcohol HDO (dodecanol‐1 as an analogue for hexadecanol‐1) and analysis of gas‐phase products.
CONCLUSIONS
In accordance with the results obtained, both hydrolysis of MP and hydrogenolysis of C OCH3 bond should be considered for describing the conversion of MP to intermediate compounds. This finding could explain the synergetic effect of acid and metal centres, which has been reported in the literature on aliphatic ester HDO, and justify the higher activity of bifunctional catalysts in this reaction. © 2019 Society of Chemical Industry |
| doi_str_mv | 10.1002/jctb.6111 |
| format | article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_2269961173</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2269961173</sourcerecordid><originalsourceid>FETCH-LOGICAL-c3341-b070f6695f328ad1cf85499c4d673c9d6890082c4b00586f4e397dd5443039033</originalsourceid><addsrcrecordid>eNp1kL1OwzAUhS0EEqUw8AaWmBgC13HixGxQ8SsQS5kj176hLiEOtgtkY2LmGXkSUsrKdJbv3Hv0EbLP4IgBpMcLHWdHgjG2QUYMZJFkQsAmGUEqyiTNi3yb7ISwAABRpmJEPu8wzvuGdqp5tlFFpPPeeGfQvfeP2KpoXUvdK3oabGO1-v74Csuucz6ioa3VTzh05y50c2uQahVV04cYqG1p3bg36lHp6PwJxfcOvX3GdiCoag19si1Gq2mIS9Pvkq1aNQH3_nJMHi7Op5Or5Pb-8npyeptozjOWzKCAWgiZ1zwtlWG6LvNMSp0ZUXAtjSglQJnqbAaQl6LOkMvCmDzLOHAJnI_Jwfpu593LEkOsFm7p2-FllaZCysFcsaIO15T2LgSPddUN05XvKwbVSnO10lytNA_s8Zp9sw32_4PVzWR69tv4Adywgq0</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2269961173</pqid></control><display><type>article</type><title>Methyl palmitate hydrodeoxygenation over silica‐supported nickel phosphide catalysts in flow reactor: experimental and kinetic study</title><source>Wiley</source><creator>Shamanaev, Ivan V ; Deliy, Irina V ; Aleksandrov, Pavel V ; Reshetnikov, Sergey I ; Bukhtiyarova, Galina A</creator><creatorcontrib>Shamanaev, Ivan V ; Deliy, Irina V ; Aleksandrov, Pavel V ; Reshetnikov, Sergey I ; Bukhtiyarova, Galina A</creatorcontrib><description>BACKGROUND
The search for alternative sources of fuels is crucial for sustainable development now and in the near future. Biomass attracts much attention as an environmentally friendly, green and CO2‐neutral source of fuels. Hydrodeoxygenation (HDO) of fatty acid‐based feedstocks such as nonedible vegetable oil, waste cooking oil and animal fat is a versatile technology for producing efficient fuels. HDO schemes are often contradictory and have different numbers of stages. In the work reported, a highly active nickel phosphide catalyst was obtained and methyl palmitate (MP) HDO kinetic modelling was carried out to elucidate the HDO reaction scheme.
RESULTS
The effect of reduction temperature (400–600 °C) on the catalytic properties of the catalyst in MP HDO was evaluated and the most active catalyst (after reduction at 450 °C) was used in the kinetic experiments. The experimental data were collected in a wide range of MP conversion. The reaction scheme of MP HDO was elucidated by means of mathematical modelling which was specified by successive consideration of the experimental results of HDO selectivities at low MP conversions (1–10%), additional experiments of alcohol HDO (dodecanol‐1 as an analogue for hexadecanol‐1) and analysis of gas‐phase products.
CONCLUSIONS
In accordance with the results obtained, both hydrolysis of MP and hydrogenolysis of C OCH3 bond should be considered for describing the conversion of MP to intermediate compounds. This finding could explain the synergetic effect of acid and metal centres, which has been reported in the literature on aliphatic ester HDO, and justify the higher activity of bifunctional catalysts in this reaction. © 2019 Society of Chemical Industry</description><identifier>ISSN: 0268-2575</identifier><identifier>EISSN: 1097-4660</identifier><identifier>DOI: 10.1002/jctb.6111</identifier><language>eng</language><publisher>Chichester, UK: John Wiley & Sons, Ltd</publisher><subject>Alcohols ; Aliphatic compounds ; Animal fat ; Carbon dioxide ; Catalysis ; Catalysts ; Conversion ; Cooking ; Cooking oils ; Dodecanol ; Fatty acids ; Fuels ; hydrodeoxygenation ; Hydrogenolysis ; kinetic modelling ; Mathematical models ; Nickel ; nickel phosphide catalyst ; Nuclear fuels ; Oil wastes ; Oils & fats ; Organic chemistry ; Palmitic acid ; Phosphides ; reaction scheme ; Reduction ; Silica ; Silicon dioxide ; Sustainable development ; Vegetable oils</subject><ispartof>Journal of chemical technology and biotechnology (1986), 2019-09, Vol.94 (9), p.3007-3019</ispartof><rights>2019 Society of Chemical Industry</rights><rights>Copyright © 2019 Society of Chemical Industry</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c3341-b070f6695f328ad1cf85499c4d673c9d6890082c4b00586f4e397dd5443039033</citedby><cites>FETCH-LOGICAL-c3341-b070f6695f328ad1cf85499c4d673c9d6890082c4b00586f4e397dd5443039033</cites><orcidid>0000-0003-2583-3183</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Shamanaev, Ivan V</creatorcontrib><creatorcontrib>Deliy, Irina V</creatorcontrib><creatorcontrib>Aleksandrov, Pavel V</creatorcontrib><creatorcontrib>Reshetnikov, Sergey I</creatorcontrib><creatorcontrib>Bukhtiyarova, Galina A</creatorcontrib><title>Methyl palmitate hydrodeoxygenation over silica‐supported nickel phosphide catalysts in flow reactor: experimental and kinetic study</title><title>Journal of chemical technology and biotechnology (1986)</title><description>BACKGROUND
The search for alternative sources of fuels is crucial for sustainable development now and in the near future. Biomass attracts much attention as an environmentally friendly, green and CO2‐neutral source of fuels. Hydrodeoxygenation (HDO) of fatty acid‐based feedstocks such as nonedible vegetable oil, waste cooking oil and animal fat is a versatile technology for producing efficient fuels. HDO schemes are often contradictory and have different numbers of stages. In the work reported, a highly active nickel phosphide catalyst was obtained and methyl palmitate (MP) HDO kinetic modelling was carried out to elucidate the HDO reaction scheme.
RESULTS
The effect of reduction temperature (400–600 °C) on the catalytic properties of the catalyst in MP HDO was evaluated and the most active catalyst (after reduction at 450 °C) was used in the kinetic experiments. The experimental data were collected in a wide range of MP conversion. The reaction scheme of MP HDO was elucidated by means of mathematical modelling which was specified by successive consideration of the experimental results of HDO selectivities at low MP conversions (1–10%), additional experiments of alcohol HDO (dodecanol‐1 as an analogue for hexadecanol‐1) and analysis of gas‐phase products.
CONCLUSIONS
In accordance with the results obtained, both hydrolysis of MP and hydrogenolysis of C OCH3 bond should be considered for describing the conversion of MP to intermediate compounds. This finding could explain the synergetic effect of acid and metal centres, which has been reported in the literature on aliphatic ester HDO, and justify the higher activity of bifunctional catalysts in this reaction. © 2019 Society of Chemical Industry</description><subject>Alcohols</subject><subject>Aliphatic compounds</subject><subject>Animal fat</subject><subject>Carbon dioxide</subject><subject>Catalysis</subject><subject>Catalysts</subject><subject>Conversion</subject><subject>Cooking</subject><subject>Cooking oils</subject><subject>Dodecanol</subject><subject>Fatty acids</subject><subject>Fuels</subject><subject>hydrodeoxygenation</subject><subject>Hydrogenolysis</subject><subject>kinetic modelling</subject><subject>Mathematical models</subject><subject>Nickel</subject><subject>nickel phosphide catalyst</subject><subject>Nuclear fuels</subject><subject>Oil wastes</subject><subject>Oils & fats</subject><subject>Organic chemistry</subject><subject>Palmitic acid</subject><subject>Phosphides</subject><subject>reaction scheme</subject><subject>Reduction</subject><subject>Silica</subject><subject>Silicon dioxide</subject><subject>Sustainable development</subject><subject>Vegetable oils</subject><issn>0268-2575</issn><issn>1097-4660</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><recordid>eNp1kL1OwzAUhS0EEqUw8AaWmBgC13HixGxQ8SsQS5kj176hLiEOtgtkY2LmGXkSUsrKdJbv3Hv0EbLP4IgBpMcLHWdHgjG2QUYMZJFkQsAmGUEqyiTNi3yb7ISwAABRpmJEPu8wzvuGdqp5tlFFpPPeeGfQvfeP2KpoXUvdK3oabGO1-v74Csuucz6ioa3VTzh05y50c2uQahVV04cYqG1p3bg36lHp6PwJxfcOvX3GdiCoag19si1Gq2mIS9Pvkq1aNQH3_nJMHi7Op5Or5Pb-8npyeptozjOWzKCAWgiZ1zwtlWG6LvNMSp0ZUXAtjSglQJnqbAaQl6LOkMvCmDzLOHAJnI_Jwfpu593LEkOsFm7p2-FllaZCysFcsaIO15T2LgSPddUN05XvKwbVSnO10lytNA_s8Zp9sw32_4PVzWR69tv4Adywgq0</recordid><startdate>201909</startdate><enddate>201909</enddate><creator>Shamanaev, Ivan V</creator><creator>Deliy, Irina V</creator><creator>Aleksandrov, Pavel V</creator><creator>Reshetnikov, Sergey I</creator><creator>Bukhtiyarova, Galina A</creator><general>John Wiley & Sons, Ltd</general><general>Wiley Subscription Services, Inc</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7QF</scope><scope>7QO</scope><scope>7QQ</scope><scope>7QR</scope><scope>7SC</scope><scope>7SE</scope><scope>7SP</scope><scope>7SR</scope><scope>7T7</scope><scope>7TA</scope><scope>7TB</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>C1K</scope><scope>F28</scope><scope>FR3</scope><scope>H8D</scope><scope>H8G</scope><scope>JG9</scope><scope>JQ2</scope><scope>KR7</scope><scope>L7M</scope><scope>L~C</scope><scope>L~D</scope><scope>P64</scope><orcidid>https://orcid.org/0000-0003-2583-3183</orcidid></search><sort><creationdate>201909</creationdate><title>Methyl palmitate hydrodeoxygenation over silica‐supported nickel phosphide catalysts in flow reactor: experimental and kinetic study</title><author>Shamanaev, Ivan V ; Deliy, Irina V ; Aleksandrov, Pavel V ; Reshetnikov, Sergey I ; Bukhtiyarova, Galina A</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3341-b070f6695f328ad1cf85499c4d673c9d6890082c4b00586f4e397dd5443039033</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><topic>Alcohols</topic><topic>Aliphatic compounds</topic><topic>Animal fat</topic><topic>Carbon dioxide</topic><topic>Catalysis</topic><topic>Catalysts</topic><topic>Conversion</topic><topic>Cooking</topic><topic>Cooking oils</topic><topic>Dodecanol</topic><topic>Fatty acids</topic><topic>Fuels</topic><topic>hydrodeoxygenation</topic><topic>Hydrogenolysis</topic><topic>kinetic modelling</topic><topic>Mathematical models</topic><topic>Nickel</topic><topic>nickel phosphide catalyst</topic><topic>Nuclear fuels</topic><topic>Oil wastes</topic><topic>Oils & fats</topic><topic>Organic chemistry</topic><topic>Palmitic acid</topic><topic>Phosphides</topic><topic>reaction scheme</topic><topic>Reduction</topic><topic>Silica</topic><topic>Silicon dioxide</topic><topic>Sustainable development</topic><topic>Vegetable oils</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Shamanaev, Ivan V</creatorcontrib><creatorcontrib>Deliy, Irina V</creatorcontrib><creatorcontrib>Aleksandrov, Pavel V</creatorcontrib><creatorcontrib>Reshetnikov, Sergey I</creatorcontrib><creatorcontrib>Bukhtiyarova, Galina A</creatorcontrib><collection>CrossRef</collection><collection>Aluminium Industry Abstracts</collection><collection>Biotechnology Research Abstracts</collection><collection>Ceramic Abstracts</collection><collection>Chemoreception Abstracts</collection><collection>Computer and Information Systems Abstracts</collection><collection>Corrosion Abstracts</collection><collection>Electronics & Communications Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>Industrial and Applied Microbiology Abstracts (Microbiology A)</collection><collection>Materials Business File</collection><collection>Mechanical & Transportation Engineering Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Environmental Sciences and Pollution Management</collection><collection>ANTE: Abstracts in New Technology & Engineering</collection><collection>Engineering Research Database</collection><collection>Aerospace Database</collection><collection>Copper Technical Reference Library</collection><collection>Materials Research Database</collection><collection>ProQuest Computer Science Collection</collection><collection>Civil Engineering Abstracts</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>Computer and Information Systems Abstracts Academic</collection><collection>Computer and Information Systems Abstracts Professional</collection><collection>Biotechnology and BioEngineering Abstracts</collection><jtitle>Journal of chemical technology and biotechnology (1986)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Shamanaev, Ivan V</au><au>Deliy, Irina V</au><au>Aleksandrov, Pavel V</au><au>Reshetnikov, Sergey I</au><au>Bukhtiyarova, Galina A</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Methyl palmitate hydrodeoxygenation over silica‐supported nickel phosphide catalysts in flow reactor: experimental and kinetic study</atitle><jtitle>Journal of chemical technology and biotechnology (1986)</jtitle><date>2019-09</date><risdate>2019</risdate><volume>94</volume><issue>9</issue><spage>3007</spage><epage>3019</epage><pages>3007-3019</pages><issn>0268-2575</issn><eissn>1097-4660</eissn><abstract>BACKGROUND
The search for alternative sources of fuels is crucial for sustainable development now and in the near future. Biomass attracts much attention as an environmentally friendly, green and CO2‐neutral source of fuels. Hydrodeoxygenation (HDO) of fatty acid‐based feedstocks such as nonedible vegetable oil, waste cooking oil and animal fat is a versatile technology for producing efficient fuels. HDO schemes are often contradictory and have different numbers of stages. In the work reported, a highly active nickel phosphide catalyst was obtained and methyl palmitate (MP) HDO kinetic modelling was carried out to elucidate the HDO reaction scheme.
RESULTS
The effect of reduction temperature (400–600 °C) on the catalytic properties of the catalyst in MP HDO was evaluated and the most active catalyst (after reduction at 450 °C) was used in the kinetic experiments. The experimental data were collected in a wide range of MP conversion. The reaction scheme of MP HDO was elucidated by means of mathematical modelling which was specified by successive consideration of the experimental results of HDO selectivities at low MP conversions (1–10%), additional experiments of alcohol HDO (dodecanol‐1 as an analogue for hexadecanol‐1) and analysis of gas‐phase products.
CONCLUSIONS
In accordance with the results obtained, both hydrolysis of MP and hydrogenolysis of C OCH3 bond should be considered for describing the conversion of MP to intermediate compounds. This finding could explain the synergetic effect of acid and metal centres, which has been reported in the literature on aliphatic ester HDO, and justify the higher activity of bifunctional catalysts in this reaction. © 2019 Society of Chemical Industry</abstract><cop>Chichester, UK</cop><pub>John Wiley & Sons, Ltd</pub><doi>10.1002/jctb.6111</doi><tpages>13</tpages><orcidid>https://orcid.org/0000-0003-2583-3183</orcidid></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0268-2575 |
| ispartof | Journal of chemical technology and biotechnology (1986), 2019-09, Vol.94 (9), p.3007-3019 |
| issn | 0268-2575 1097-4660 |
| language | eng |
| recordid | cdi_proquest_journals_2269961173 |
| source | Wiley |
| subjects | Alcohols Aliphatic compounds Animal fat Carbon dioxide Catalysis Catalysts Conversion Cooking Cooking oils Dodecanol Fatty acids Fuels hydrodeoxygenation Hydrogenolysis kinetic modelling Mathematical models Nickel nickel phosphide catalyst Nuclear fuels Oil wastes Oils & fats Organic chemistry Palmitic acid Phosphides reaction scheme Reduction Silica Silicon dioxide Sustainable development Vegetable oils |
| title | Methyl palmitate hydrodeoxygenation over silica‐supported nickel phosphide catalysts in flow reactor: experimental and kinetic study |
| url | http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-29T00%3A15%3A03IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Methyl%20palmitate%20hydrodeoxygenation%20over%20silica%E2%80%90supported%20nickel%20phosphide%20catalysts%20in%20flow%20reactor:%20experimental%20and%20kinetic%20study&rft.jtitle=Journal%20of%20chemical%20technology%20and%20biotechnology%20(1986)&rft.au=Shamanaev,%20Ivan%20V&rft.date=2019-09&rft.volume=94&rft.issue=9&rft.spage=3007&rft.epage=3019&rft.pages=3007-3019&rft.issn=0268-2575&rft.eissn=1097-4660&rft_id=info:doi/10.1002/jctb.6111&rft_dat=%3Cproquest_cross%3E2269961173%3C/proquest_cross%3E%3Cgrp_id%3Ecdi_FETCH-LOGICAL-c3341-b070f6695f328ad1cf85499c4d673c9d6890082c4b00586f4e397dd5443039033%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_pqid=2269961173&rft_id=info:pmid/&rfr_iscdi=true |