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Performances of PCL/PVC/Organoclay Nanobioblends Films for Packaging Applications
A series of antimicrobial PCL/PVC/OMMTs nanobioblends films are successfully prepared via melt blending process of the poly (ϵ‐caprolactone) (PCL), poly (vinyl chloride) (PVC), and three different clay types namely Cloisite 30B (C30B), trimethylhexadecyl ammonium (OMMT1), and cetylpyridinium chlorid...
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Published in: | Macromolecular symposia. 2019-08, Vol.386 (1), p.n/a |
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creator | Hadj‐Hamou, Assia Siham Yahiaoui, Farida |
description | A series of antimicrobial PCL/PVC/OMMTs nanobioblends films are successfully prepared via melt blending process of the poly (ϵ‐caprolactone) (PCL), poly (vinyl chloride) (PVC), and three different clay types namely Cloisite 30B (C30B), trimethylhexadecyl ammonium (OMMT1), and cetylpyridinium chloride monohydrate (OMMT2) modified montmorillonite. All the PCL/PVC/OMMTs nanocomposites display mixed intercalated/partially exfoliated structures as attested by X‐Ray Diffraction and Transmission Electron Microscopy. Glass transition, fusion and cristallization of these nanomaterials are studied using differential scanning calorimetry (DSC). The organoclay effect on the mechanical, barrier and antimicrobial properties is investigated. The results confirm that the insertion of 3 wt% of OMMT (whatever its intercalant agent nature) into the PCL/PVC matrix leads to (1) a remarkable improvement in barrier properties, (2) an interesting enhancement in mechanical properties, and (3) a strong antimicrobial activity against Staphylococcus aureus (Gram‐positive) and Escherichia coli (Gram‐negative). |
doi_str_mv | 10.1002/masy.201800239 |
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All the PCL/PVC/OMMTs nanocomposites display mixed intercalated/partially exfoliated structures as attested by X‐Ray Diffraction and Transmission Electron Microscopy. Glass transition, fusion and cristallization of these nanomaterials are studied using differential scanning calorimetry (DSC). The organoclay effect on the mechanical, barrier and antimicrobial properties is investigated. The results confirm that the insertion of 3 wt% of OMMT (whatever its intercalant agent nature) into the PCL/PVC matrix leads to (1) a remarkable improvement in barrier properties, (2) an interesting enhancement in mechanical properties, and (3) a strong antimicrobial activity against Staphylococcus aureus (Gram‐positive) and Escherichia coli (Gram‐negative).</description><identifier>ISSN: 1022-1360</identifier><identifier>EISSN: 1521-3900</identifier><identifier>DOI: 10.1002/masy.201800239</identifier><language>eng</language><publisher>Weinheim: Wiley Subscription Services, Inc</publisher><subject>Ammonium ; antibacterial activity ; Antiinfectives and antibacterials ; Antimicrobial activity ; Antimicrobial agents ; barrier properties ; bioblends ; Cetylpyridinium chloride ; Differential scanning calorimetry ; E coli ; Mechanical properties ; Melt blending ; Melting ; Montmorillonite ; Nanocomposites ; Nanomaterials ; Nanotechnology ; packaging ; Polyvinyl chloride ; Transmission electron microscopy ; Vinyl chloride</subject><ispartof>Macromolecular symposia., 2019-08, Vol.386 (1), p.n/a</ispartof><rights>2019 WILEY-VCH Verlag GmbH & Co. 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All the PCL/PVC/OMMTs nanocomposites display mixed intercalated/partially exfoliated structures as attested by X‐Ray Diffraction and Transmission Electron Microscopy. Glass transition, fusion and cristallization of these nanomaterials are studied using differential scanning calorimetry (DSC). The organoclay effect on the mechanical, barrier and antimicrobial properties is investigated. The results confirm that the insertion of 3 wt% of OMMT (whatever its intercalant agent nature) into the PCL/PVC matrix leads to (1) a remarkable improvement in barrier properties, (2) an interesting enhancement in mechanical properties, and (3) a strong antimicrobial activity against Staphylococcus aureus (Gram‐positive) and Escherichia coli (Gram‐negative).</description><subject>Ammonium</subject><subject>antibacterial activity</subject><subject>Antiinfectives and antibacterials</subject><subject>Antimicrobial activity</subject><subject>Antimicrobial agents</subject><subject>barrier properties</subject><subject>bioblends</subject><subject>Cetylpyridinium chloride</subject><subject>Differential scanning calorimetry</subject><subject>E coli</subject><subject>Mechanical properties</subject><subject>Melt blending</subject><subject>Melting</subject><subject>Montmorillonite</subject><subject>Nanocomposites</subject><subject>Nanomaterials</subject><subject>Nanotechnology</subject><subject>packaging</subject><subject>Polyvinyl chloride</subject><subject>Transmission electron microscopy</subject><subject>Vinyl chloride</subject><issn>1022-1360</issn><issn>1521-3900</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><recordid>eNqFkM9LwzAUx4MoOKdXzwXP3V6SNluOozgVpqs4BE_htU1GZ9vUxCH9782Y6NHT-8Hn8x58CbmmMKEAbNqiHyYM6DwMXJ6QEU0ZjbkEOA09MBZTLuCcXHi_AwApZ3REnnPtjHUtdqX2kTVRnq2m-Ws2XbstdrZscIieQlPUtmh0V_loWTetj4IT5Vi-47buttGi75u6xM_adv6SnBlsvL76qWOyWd5usvt4tb57yBaruORpImMjNKcSk1RLIctCVIAFFylUDHSBkEgTtmASISsNgDw90JiwOYo504aPyc3xbO_sx177T7Wze9eFj4qxGRMinQkeqMmRKp313mmjele36AZFQR1SU4fU1G9qQZBH4atu9PAPrR4XL29_7jcNu3Ds</recordid><startdate>201908</startdate><enddate>201908</enddate><creator>Hadj‐Hamou, Assia Siham</creator><creator>Yahiaoui, Farida</creator><general>Wiley Subscription Services, Inc</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>201908</creationdate><title>Performances of PCL/PVC/Organoclay Nanobioblends Films for Packaging Applications</title><author>Hadj‐Hamou, Assia Siham ; Yahiaoui, Farida</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3549-f6e319a45e969cb6d0ab3650d20eba049f9cb0f469de00a35319aa428a682ef3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><topic>Ammonium</topic><topic>antibacterial activity</topic><topic>Antiinfectives and antibacterials</topic><topic>Antimicrobial activity</topic><topic>Antimicrobial agents</topic><topic>barrier properties</topic><topic>bioblends</topic><topic>Cetylpyridinium chloride</topic><topic>Differential scanning calorimetry</topic><topic>E coli</topic><topic>Mechanical properties</topic><topic>Melt blending</topic><topic>Melting</topic><topic>Montmorillonite</topic><topic>Nanocomposites</topic><topic>Nanomaterials</topic><topic>Nanotechnology</topic><topic>packaging</topic><topic>Polyvinyl chloride</topic><topic>Transmission electron microscopy</topic><topic>Vinyl chloride</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Hadj‐Hamou, Assia Siham</creatorcontrib><creatorcontrib>Yahiaoui, Farida</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Macromolecular symposia.</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Hadj‐Hamou, Assia Siham</au><au>Yahiaoui, Farida</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Performances of PCL/PVC/Organoclay Nanobioblends Films for Packaging Applications</atitle><jtitle>Macromolecular symposia.</jtitle><date>2019-08</date><risdate>2019</risdate><volume>386</volume><issue>1</issue><epage>n/a</epage><issn>1022-1360</issn><eissn>1521-3900</eissn><abstract>A series of antimicrobial PCL/PVC/OMMTs nanobioblends films are successfully prepared via melt blending process of the poly (ϵ‐caprolactone) (PCL), poly (vinyl chloride) (PVC), and three different clay types namely Cloisite 30B (C30B), trimethylhexadecyl ammonium (OMMT1), and cetylpyridinium chloride monohydrate (OMMT2) modified montmorillonite. All the PCL/PVC/OMMTs nanocomposites display mixed intercalated/partially exfoliated structures as attested by X‐Ray Diffraction and Transmission Electron Microscopy. Glass transition, fusion and cristallization of these nanomaterials are studied using differential scanning calorimetry (DSC). The organoclay effect on the mechanical, barrier and antimicrobial properties is investigated. The results confirm that the insertion of 3 wt% of OMMT (whatever its intercalant agent nature) into the PCL/PVC matrix leads to (1) a remarkable improvement in barrier properties, (2) an interesting enhancement in mechanical properties, and (3) a strong antimicrobial activity against Staphylococcus aureus (Gram‐positive) and Escherichia coli (Gram‐negative).</abstract><cop>Weinheim</cop><pub>Wiley Subscription Services, Inc</pub><doi>10.1002/masy.201800239</doi><tpages>8</tpages></addata></record> |
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subjects | Ammonium antibacterial activity Antiinfectives and antibacterials Antimicrobial activity Antimicrobial agents barrier properties bioblends Cetylpyridinium chloride Differential scanning calorimetry E coli Mechanical properties Melt blending Melting Montmorillonite Nanocomposites Nanomaterials Nanotechnology packaging Polyvinyl chloride Transmission electron microscopy Vinyl chloride |
title | Performances of PCL/PVC/Organoclay Nanobioblends Films for Packaging Applications |
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