Nature of the magnetism of iridium in the double perovskite Sr2CoIrO6

• Published in: Physical review. B 2019-07, Vol.100 (1), p.014443
• Main Authors: Agrestini, S, Chen, K, Kuo, C-Y, Zhao, L, Lin, H-J, Chen, C-T, Rogalev, A, Ohresser, P, Chan, T-S, Weng, S-C, Auffermann, G, Völzke, A, Komarek, A C, Yamaura, K, Haverkort, M W, Hu, Z, Tjeng, L H
• Format: Article
• Language: English
• Subjects: Cobalt; Dichroism; Infrared spectroscopy; Magnetic moments; Magnetic signals; Magnetism; Perovskites; Spectrum analysis; X ray absorption
• ISSN: 2469-9950; 2469-9969
• DOI: 10.1103/PhysRevB.100.014443

We report on our investigation on the magnetism of the iridate double perovskite Sr2CoIrO6, a nominally Ir5+ Van Vleck Jeff=0 system. Using x-ray absorption (XAS) and x-ray magnetic circular dichroism (XMCD) spectroscopy at the Ir-L2,3 edges, we found a nearly zero orbital contribution to the magnetic moment and thus an apparent breakdown of the Jeff=0 ground state. By carrying out also XAS and XMCD experiments at the Co-L2,3 edges and by performing detailed full atomic multiplet calculations to simulate all spectra, we discovered that the compound consists of about 90% Ir5+ (Jeff=0) and Co3+ (S=2) and 10% Ir6+ (S=3/2) and Co2+ (S=3/2). The magnetic signal of this minority Ir6+ component is almost equally as strong as that of the main Ir5+ component. We infer that there is a competition between the Ir5+−Co3+ and the Ir6+−Co2+ configurations in this stoichiometric compound.