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Versatile Solvothermal Synthetic Method and Structural Characterization of Lithium Coordination Networks

The reactions of LiOH·H 2 O with 1,3,5-benzenetricarboxylic acid (1,3,5-btc) under versatile solvothermal conditions produce a series of lithium coordination polymers, namely {[Li 2 (1,3,5-btc)(1,3,5-Hbtc)(DMF)](DMF) 2 } n ( 1 ), {[Li 3 (1,3,5-btc)(DMSO) 3 ](H 2 O)} n ( 2 ), {((CH 3 ) 2 NH)[Li 2 (1,...

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Published in:Journal of inorganic and organometallic polymers and materials 2019-09, Vol.29 (5), p.1447-1456
Main Authors: Jiang, Zhi-Qiang, Du, Yu, Zhu, Xue-Jun, Lu, Jin, Huang, Zai-Chun, Li, Yu-Feng, Kang, Yao
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cited_by cdi_FETCH-LOGICAL-c356t-2321c30f49e4b5727518b69f50f40c3021a4c973775ef3ad53406360c9c323693
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container_title Journal of inorganic and organometallic polymers and materials
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description The reactions of LiOH·H 2 O with 1,3,5-benzenetricarboxylic acid (1,3,5-btc) under versatile solvothermal conditions produce a series of lithium coordination polymers, namely {[Li 2 (1,3,5-btc)(1,3,5-Hbtc)(DMF)](DMF) 2 } n ( 1 ), {[Li 3 (1,3,5-btc)(DMSO) 3 ](H 2 O)} n ( 2 ), {((CH 3 ) 2 NH)[Li 2 (1,3,5-btc)(H 2 O)]} n ( 3 ), {((CH 3 ) 2 NH)[Li 2 (1,3,5-btc)(1,3,5-Hbtc)]} n ( 4 ), {((CH 3 ) 2 NH)[Li 2 (1,3,5-btc)]} n ( 5 ) and [Li 3 (1,3,5-btc)(H 2 O)] n ( 6 ) (DMSO = dimethyl sulphoxide, DMF =  N,N -dimethylformamide). Compound 1 and 4 exhibit two-dimensional framework, while compound 2, 3, 5 and 6 show three-dimensional network. The results demonstrate different solvents or different temperatures can generate the structural diversity. Graphical Abstract
doi_str_mv 10.1007/s10904-019-01108-0
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Compound 1 and 4 exhibit two-dimensional framework, while compound 2, 3, 5 and 6 show three-dimensional network. The results demonstrate different solvents or different temperatures can generate the structural diversity. 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Compound 1 and 4 exhibit two-dimensional framework, while compound 2, 3, 5 and 6 show three-dimensional network. The results demonstrate different solvents or different temperatures can generate the structural diversity. 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subjects Chemistry
Chemistry and Materials Science
Coordination polymers
Dimethyl sulfoxide
Inorganic Chemistry
Lithium
Organic Chemistry
Polymer Sciences
Structural analysis
title Versatile Solvothermal Synthetic Method and Structural Characterization of Lithium Coordination Networks
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