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Versatile Solvothermal Synthetic Method and Structural Characterization of Lithium Coordination Networks
The reactions of LiOH·H 2 O with 1,3,5-benzenetricarboxylic acid (1,3,5-btc) under versatile solvothermal conditions produce a series of lithium coordination polymers, namely {[Li 2 (1,3,5-btc)(1,3,5-Hbtc)(DMF)](DMF) 2 } n ( 1 ), {[Li 3 (1,3,5-btc)(DMSO) 3 ](H 2 O)} n ( 2 ), {((CH 3 ) 2 NH)[Li 2 (1,...
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Published in: | Journal of inorganic and organometallic polymers and materials 2019-09, Vol.29 (5), p.1447-1456 |
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container_issue | 5 |
container_start_page | 1447 |
container_title | Journal of inorganic and organometallic polymers and materials |
container_volume | 29 |
creator | Jiang, Zhi-Qiang Du, Yu Zhu, Xue-Jun Lu, Jin Huang, Zai-Chun Li, Yu-Feng Kang, Yao |
description | The reactions of LiOH·H
2
O with 1,3,5-benzenetricarboxylic acid (1,3,5-btc) under versatile solvothermal conditions produce a series of lithium coordination polymers, namely {[Li
2
(1,3,5-btc)(1,3,5-Hbtc)(DMF)](DMF)
2
}
n
(
1
), {[Li
3
(1,3,5-btc)(DMSO)
3
](H
2
O)}
n
(
2
), {((CH
3
)
2
NH)[Li
2
(1,3,5-btc)(H
2
O)]}
n
(
3
), {((CH
3
)
2
NH)[Li
2
(1,3,5-btc)(1,3,5-Hbtc)]}
n
(
4
), {((CH
3
)
2
NH)[Li
2
(1,3,5-btc)]}
n
(
5
) and [Li
3
(1,3,5-btc)(H
2
O)]
n
(
6
) (DMSO = dimethyl sulphoxide, DMF =
N,N
-dimethylformamide). Compound
1
and
4
exhibit two-dimensional framework, while compound
2, 3, 5
and
6
show three-dimensional network. The results demonstrate different solvents or different temperatures can generate the structural diversity.
Graphical Abstract |
doi_str_mv | 10.1007/s10904-019-01108-0 |
format | article |
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2
O with 1,3,5-benzenetricarboxylic acid (1,3,5-btc) under versatile solvothermal conditions produce a series of lithium coordination polymers, namely {[Li
2
(1,3,5-btc)(1,3,5-Hbtc)(DMF)](DMF)
2
}
n
(
1
), {[Li
3
(1,3,5-btc)(DMSO)
3
](H
2
O)}
n
(
2
), {((CH
3
)
2
NH)[Li
2
(1,3,5-btc)(H
2
O)]}
n
(
3
), {((CH
3
)
2
NH)[Li
2
(1,3,5-btc)(1,3,5-Hbtc)]}
n
(
4
), {((CH
3
)
2
NH)[Li
2
(1,3,5-btc)]}
n
(
5
) and [Li
3
(1,3,5-btc)(H
2
O)]
n
(
6
) (DMSO = dimethyl sulphoxide, DMF =
N,N
-dimethylformamide). Compound
1
and
4
exhibit two-dimensional framework, while compound
2, 3, 5
and
6
show three-dimensional network. The results demonstrate different solvents or different temperatures can generate the structural diversity.
Graphical Abstract</description><identifier>ISSN: 1574-1443</identifier><identifier>EISSN: 1574-1451</identifier><identifier>DOI: 10.1007/s10904-019-01108-0</identifier><language>eng</language><publisher>New York: Springer US</publisher><subject>Chemistry ; Chemistry and Materials Science ; Coordination polymers ; Dimethyl sulfoxide ; Inorganic Chemistry ; Lithium ; Organic Chemistry ; Polymer Sciences ; Structural analysis</subject><ispartof>Journal of inorganic and organometallic polymers and materials, 2019-09, Vol.29 (5), p.1447-1456</ispartof><rights>Springer Science+Business Media, LLC, part of Springer Nature 2019</rights><rights>Copyright Springer Nature B.V. 2019</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c356t-2321c30f49e4b5727518b69f50f40c3021a4c973775ef3ad53406360c9c323693</citedby><cites>FETCH-LOGICAL-c356t-2321c30f49e4b5727518b69f50f40c3021a4c973775ef3ad53406360c9c323693</cites><orcidid>0000-0002-0617-9182</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27901,27902</link.rule.ids></links><search><creatorcontrib>Jiang, Zhi-Qiang</creatorcontrib><creatorcontrib>Du, Yu</creatorcontrib><creatorcontrib>Zhu, Xue-Jun</creatorcontrib><creatorcontrib>Lu, Jin</creatorcontrib><creatorcontrib>Huang, Zai-Chun</creatorcontrib><creatorcontrib>Li, Yu-Feng</creatorcontrib><creatorcontrib>Kang, Yao</creatorcontrib><title>Versatile Solvothermal Synthetic Method and Structural Characterization of Lithium Coordination Networks</title><title>Journal of inorganic and organometallic polymers and materials</title><addtitle>J Inorg Organomet Polym</addtitle><description>The reactions of LiOH·H
2
O with 1,3,5-benzenetricarboxylic acid (1,3,5-btc) under versatile solvothermal conditions produce a series of lithium coordination polymers, namely {[Li
2
(1,3,5-btc)(1,3,5-Hbtc)(DMF)](DMF)
2
}
n
(
1
), {[Li
3
(1,3,5-btc)(DMSO)
3
](H
2
O)}
n
(
2
), {((CH
3
)
2
NH)[Li
2
(1,3,5-btc)(H
2
O)]}
n
(
3
), {((CH
3
)
2
NH)[Li
2
(1,3,5-btc)(1,3,5-Hbtc)]}
n
(
4
), {((CH
3
)
2
NH)[Li
2
(1,3,5-btc)]}
n
(
5
) and [Li
3
(1,3,5-btc)(H
2
O)]
n
(
6
) (DMSO = dimethyl sulphoxide, DMF =
N,N
-dimethylformamide). Compound
1
and
4
exhibit two-dimensional framework, while compound
2, 3, 5
and
6
show three-dimensional network. The results demonstrate different solvents or different temperatures can generate the structural diversity.
Graphical Abstract</description><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Coordination polymers</subject><subject>Dimethyl sulfoxide</subject><subject>Inorganic Chemistry</subject><subject>Lithium</subject><subject>Organic Chemistry</subject><subject>Polymer Sciences</subject><subject>Structural analysis</subject><issn>1574-1443</issn><issn>1574-1451</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><recordid>eNp9UMlOwzAQtRBIlMIPcLLEOTDe4uaIIjapwKHA1XIdh6SkMdgOqHw9LkFw4zCa0dtGeggdEzglAPIsECiAZ0CKNARmGeygCRGSZ4QLsvt7c7aPDkJYAbAZCDJBzZP1Qce2s3jhuncXG-vXusOLTZ_O2Bp8a2PjKqz7Ci-iH0wcfOLLRnttovXtZ3K7Hrsaz9vYtMMal875qu1H_M7GD-dfwiHaq3UX7NHPnqLHy4uH8jqb31_dlOfzzDCRx4wySgyDmheWL4WkUpDZMi9qkSBIBCWam0IyKYWtma4E45CzHExhGGV5waboZMx99e5tsCGqlRt8n14qSiXnVOYSkoqOKuNdCN7W6tW3a-03ioDaNqrGRlVqVH03qrYmNppCEvfP1v9F_-P6AlGZeVI</recordid><startdate>20190901</startdate><enddate>20190901</enddate><creator>Jiang, Zhi-Qiang</creator><creator>Du, Yu</creator><creator>Zhu, Xue-Jun</creator><creator>Lu, Jin</creator><creator>Huang, Zai-Chun</creator><creator>Li, Yu-Feng</creator><creator>Kang, Yao</creator><general>Springer US</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><orcidid>https://orcid.org/0000-0002-0617-9182</orcidid></search><sort><creationdate>20190901</creationdate><title>Versatile Solvothermal Synthetic Method and Structural Characterization of Lithium Coordination Networks</title><author>Jiang, Zhi-Qiang ; Du, Yu ; Zhu, Xue-Jun ; Lu, Jin ; Huang, Zai-Chun ; Li, Yu-Feng ; Kang, Yao</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c356t-2321c30f49e4b5727518b69f50f40c3021a4c973775ef3ad53406360c9c323693</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Coordination polymers</topic><topic>Dimethyl sulfoxide</topic><topic>Inorganic Chemistry</topic><topic>Lithium</topic><topic>Organic Chemistry</topic><topic>Polymer Sciences</topic><topic>Structural analysis</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Jiang, Zhi-Qiang</creatorcontrib><creatorcontrib>Du, Yu</creatorcontrib><creatorcontrib>Zhu, Xue-Jun</creatorcontrib><creatorcontrib>Lu, Jin</creatorcontrib><creatorcontrib>Huang, Zai-Chun</creatorcontrib><creatorcontrib>Li, Yu-Feng</creatorcontrib><creatorcontrib>Kang, Yao</creatorcontrib><collection>CrossRef</collection><jtitle>Journal of inorganic and organometallic polymers and materials</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Jiang, Zhi-Qiang</au><au>Du, Yu</au><au>Zhu, Xue-Jun</au><au>Lu, Jin</au><au>Huang, Zai-Chun</au><au>Li, Yu-Feng</au><au>Kang, Yao</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Versatile Solvothermal Synthetic Method and Structural Characterization of Lithium Coordination Networks</atitle><jtitle>Journal of inorganic and organometallic polymers and materials</jtitle><stitle>J Inorg Organomet Polym</stitle><date>2019-09-01</date><risdate>2019</risdate><volume>29</volume><issue>5</issue><spage>1447</spage><epage>1456</epage><pages>1447-1456</pages><issn>1574-1443</issn><eissn>1574-1451</eissn><abstract>The reactions of LiOH·H
2
O with 1,3,5-benzenetricarboxylic acid (1,3,5-btc) under versatile solvothermal conditions produce a series of lithium coordination polymers, namely {[Li
2
(1,3,5-btc)(1,3,5-Hbtc)(DMF)](DMF)
2
}
n
(
1
), {[Li
3
(1,3,5-btc)(DMSO)
3
](H
2
O)}
n
(
2
), {((CH
3
)
2
NH)[Li
2
(1,3,5-btc)(H
2
O)]}
n
(
3
), {((CH
3
)
2
NH)[Li
2
(1,3,5-btc)(1,3,5-Hbtc)]}
n
(
4
), {((CH
3
)
2
NH)[Li
2
(1,3,5-btc)]}
n
(
5
) and [Li
3
(1,3,5-btc)(H
2
O)]
n
(
6
) (DMSO = dimethyl sulphoxide, DMF =
N,N
-dimethylformamide). Compound
1
and
4
exhibit two-dimensional framework, while compound
2, 3, 5
and
6
show three-dimensional network. The results demonstrate different solvents or different temperatures can generate the structural diversity.
Graphical Abstract</abstract><cop>New York</cop><pub>Springer US</pub><doi>10.1007/s10904-019-01108-0</doi><tpages>10</tpages><orcidid>https://orcid.org/0000-0002-0617-9182</orcidid></addata></record> |
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issn | 1574-1443 1574-1451 |
language | eng |
recordid | cdi_proquest_journals_2274427670 |
source | Springer Nature:Jisc Collections:Springer Nature Read and Publish 2023-2025: Springer Reading List |
subjects | Chemistry Chemistry and Materials Science Coordination polymers Dimethyl sulfoxide Inorganic Chemistry Lithium Organic Chemistry Polymer Sciences Structural analysis |
title | Versatile Solvothermal Synthetic Method and Structural Characterization of Lithium Coordination Networks |
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