Photoinitiated Charge Transfer in a Triangular Silver(I) Hydride Complex and Its Oxophilicity

Invited for the cover of this issue are the research groups of Rolf Diller, Gereon Niedner‐Schatteburg, Christoph Riehn and Werner R. Thiel from the TU Kaiserslautern (TUK) and the group of Wim Klopper of the Karlsruhe Institute of Technology (KIT) collaborating within the research center “3MET” (SF...

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Bibliographic Details
Published in:Chemistry : a European journal 2019-08, Vol.25 (48), p.11176-11176
Main Authors: Kruppa, Sebastian V., Groß, Cedric, Gui, Xin, Bäppler, Florian, Kwasigroch, Björn, Sun, Yu, Diller, Rolf, Klopper, Wim, Niedner‐Schatteburg, Gereon, Riehn, Christoph, Thiel, Werner R.
Format: Article
Language:English
Subjects:
Charge transfer
Chemistry
Hydrides
Phosphine
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Summary:Invited for the cover of this issue are the research groups of Rolf Diller, Gereon Niedner‐Schatteburg, Christoph Riehn and Werner R. Thiel from the TU Kaiserslautern (TUK) and the group of Wim Klopper of the Karlsruhe Institute of Technology (KIT) collaborating within the research center “3MET” (SFB/TRR 88). The image depicts the photoinitiated charge transfer within a phosphine‐stabilized triangular silver hydride complex. Read the full text of the article at 10.1002/chem.201901981. “Inspired by previous studies on multinuclear silver hydrides and our work on bimetallic phosphine‐stabilized compounds, we extended the nuclearity by designing a trimetallic system that allows for direct optical excitation of a metal‐centered chromophore.” Read more about the story behind the cover in the Cover Profile and about the research itself on page 11269 ff. (DOI: 10.1002/chem.201901981).
ISSN:0947-6539
1521-3765
DOI:10.1002/chem.201903111