Perfluoropolyethers with Dialkylamine End Groups: Ultrastable Lubricant for Magnetic Disk Application

It has been shown earlier that addition of X1P (partially fluorinated hexaphenoxy cyclotriphosphazene) to the lubricant Z-DOL markedly increases the durability of the magnetic disk system. Its efficacy has been attributed to the strong nucleophilic property of the triphosphazene ring. It follows tha...

Full description

Saved in:
Bibliographic Details
Published in:Tribology letters 2002-02, Vol.12 (2), p.117-122
Main Authors: Kasai, Paul H, Vedantham Raman
Format: Article
Language:English
Subjects:
Aluminum oxide
Contaminants
Durability
Fluorination
Lewis acid
Magnetic disks
Perfluoro compounds
Relative humidity
Silicon oxides
Synthesis
Tribology
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:It has been shown earlier that addition of X1P (partially fluorinated hexaphenoxy cyclotriphosphazene) to the lubricant Z-DOL markedly increases the durability of the magnetic disk system. Its efficacy has been attributed to the strong nucleophilic property of the triphosphazene ring. It follows that perfluoropolyethers terminated with nucleophilic end groups should exhibit a durability comparable to that of the Z-DOL/X1P mixture. To this end perfluoropolyethers with dialkylamine end groups were conceived and synthesized as better alternatives to Z-DOL or to the Z-DOL/X1P mixed system. Examination of the newly synthesized lubricant revealed that (1) perfluoropolyethers with dialkylamine end groups are resistant to the degradation process catalyzed by Lewis acid (e.g., aluminum oxide), (2) disks lubricated with these lubes have durability significantly better than those lubricated with Z-DOL, (3) in the drive system with disks lubricated with these lubes, the issue of the silicon oxide formation from siloxane contaminant is effectively contained (owing to the absence of degraded lube), and (4) the HDI system with disks lubricated with these lubes performs well even in the most aggressive atmospheric condition, i.e., nitrogen with 0% relative humidity.
ISSN:1023-8883
1573-2711
DOI:10.1023/A:1014041824630