Bimetal−Organic Framework Derived High‐Valence‐State Cu‐Doped Co3O4 Porous Nanosheet Arrays for Efficient Oxygen Evolution and Water Splitting

• Published in: ChemCatChem 2019-09, Vol.11 (17), p.4420-4426
• Main Authors: Tian, Yongshang, Cao, Lijia, Qin, Panpan
• Format: Article
• Language: English
• Subjects: Arrays; Bimetals; bimetal−organic framework; Co3+-rich surface; Cobalt oxides; Electrocatalysts; Electrodes; Electrolysis; Electron transport; Electronic structure; Hydrogen-based energy; Low voltage; Mathematical morphology; Metal foams; Nanosheets; overall water splitting; oxygen evolution reaction; Oxygen evolution reactions; porous nanosheet arrays; Pyrolysis; Water splitting
• ISSN: 1867-3880; 1867-3899
• DOI: 10.1002/cctc.201900834

Developing low‐cost, high‐efficient, and robust electrocatalysts for oxygen evolution reaction (OER) holds promise for the future hydrogen economy through overall water splitting. Herein, Cu doped Co3O4 porous nanosheet arrays were synthesized on three‐dimensional (3D) nickel foam (Cu−Co3O4 NAs/NF) by a facile pyrolysis process of bimetal−organic frameworks precursors. The systematic experiments evidence that the Cu doping in Co3O4 materials not only results in affluent trivalent cobalt as active sites for OER electrocatalysis, but also modulates the nanosheet morphology to achieve high specific surface area and well‐exposed active sites. Moreover, the 3D electrode configuration simultaneously offers open‐channels for electron transport and gas products release. Benefitting from the exotic geometric and electronic structure, the engineered Cu−Co3O4 NAs/NF electrode exhibits outstanding activity (an overpotential of 230 mV at 10 mA cm−2) and long‐term durability toward OER, much better than the benchmark IrO2/NF. Together with its remarkable HER activity, our Cu−Co3O4 NAs/NF electrode enables a low voltage of 1.58 V to generate a current density of 10 mA cm−2 for overall water splitting, which is comparable to those of current Co‐based bifunctional electrocatalysts. This work may open up opportunities to explore other advanced electrocatalysts with high valence Co3+ and 3D porous architectures for scale‐up water electrolysis. Oxygen evolution: Co3+‐rich Cu‐doped Co3O4 nanosheet arrays have been successfully prepared by a facile pyrolysis process of bimetal−organic frameworks precursors. Thanks to the affluent Co3+ active sites and 3D porous architectures, the engineered catalysts delivers impressive OER performance with low overpotentials of only 230 mV at a current density of 10 mA cm−2, which vastly exceeds the benchmark IrO2 on nickel foam.