Kinetics of Allyl Alcohol Epoxidation with Hydrogen Peroxide Catalyzed by a TS-1/Al2O3

The kinetics of oxidation of allyl alcohol to glycidol in the presence of extruded titanium silicalite was investigated. Based on the experimental data obtained, a kinetic model of the process was developed and the activation energies of the target and side reactions, the rate constants and the adso...

Full description

Saved in:
Bibliographic Details
Published in:Catalysis letters 2019-11, Vol.149 (11), p.3076-3086
Main Authors: Sulimov, A., Ovcharova, A., Ovcharov, A., Sulimova, J.
Format: Article
Language:English
Subjects:
Adequacy
Alcohol
Aluminum oxide
Catalysis
Chemistry
Chemistry and Materials Science
Epoxidation
Extrusion
Hydrogen peroxide
Industrial Chemistry/Chemical Engineering
Organometallic Chemistry
Oxidation
Physical Chemistry
Rate constants
Reaction kinetics
Silicalite
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:The kinetics of oxidation of allyl alcohol to glycidol in the presence of extruded titanium silicalite was investigated. Based on the experimental data obtained, a kinetic model of the process was developed and the activation energies of the target and side reactions, the rate constants and the adsorption equilibrium were determined. Testing of the process of allyl alcohol epoxidation was carried out and the adequacy of the proposed kinetic model was evaluated at the bench laboratory installation of continuous action. Graphic Abstract
ISSN:1011-372X
1572-879X
DOI:10.1007/s10562-019-02877-6