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Supramolecular Organization and Photovoltaic Properties of Barbiturated Oligothiophenes

Semiconducting small molecules capable of self-organizing into well-defined nanostructures have a great potential in organic electronics. In this article we review hydrogen-bond-directed supramolecular organization of barbiturated oligothiophenes and the application of the resulting one-dimensional...

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Bibliographic Details
Published in:Chemistry letters 2019-09, Vol.48 (9), p.1009-1018
Main Authors: Ouchi, Hayato, Lin, Xu, Yagai, Shiki
Format: Article
Language:English
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Summary:Semiconducting small molecules capable of self-organizing into well-defined nanostructures have a great potential in organic electronics. In this article we review hydrogen-bond-directed supramolecular organization of barbiturated oligothiophenes and the application of the resulting one-dimensional nanostructures to solution processable bulk heterojunction organic photovoltaic cells. Through this article we illustrate that through a proper molecular design we can utilize directional hydrogen bonding units as a potent tool to organize π-conjugated molecules into 1D nanostructures optoelectronically active at the device level.
ISSN:0366-7022
1348-0715
DOI:10.1246/cl.190296