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From Liquid–Gas Chromatography to a Chromatomembrane Mass-Exchange Process

We considered the physicochemical regularities and analytical capabilities of separation methods based on the manifestation of capillary effects in hydrophobic microporous media, namely, liquid–gas chromatography with a stationary gas phase in the pores of a solid-phase substrate and a mass-exchange...

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Bibliographic Details
Published in:Journal of analytical chemistry (New York, N.Y.) N.Y.), 2019-10, Vol.74 (10), p.955-974
Main Authors: Moskvin, L. N., Rodinkov, O. V.
Format: Article
Language:English
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Summary:We considered the physicochemical regularities and analytical capabilities of separation methods based on the manifestation of capillary effects in hydrophobic microporous media, namely, liquid–gas chromatography with a stationary gas phase in the pores of a solid-phase substrate and a mass-exchange process in liquid–gas and liquid–liquid systems, carried out in a biporous matrix. The advantages of these methods compared to conventional mass-exchange processes in the same systems in terms of higher efficiency and a possibility of the separation of substances in a continuous mode are shown.
ISSN:1061-9348
1608-3199
DOI:10.1134/S1061934819100083