FTIR and Raman Spectroscopy Characterization of Coking Coals with Diverse Coalification

— The relationship between several structural parameters and vitrinite reflectance (ranged from 0.72 to 2.14) of coal samples was analyzed with infrared and Raman spectrum, consequently important information of functional groups and molecular structures of samples were obtained. It is indicated in t...

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Published in:Coke and chemistry (New York, N.Y.) N.Y.), 2019-06, Vol.62 (6), p.211-219
Main Authors: Shao-Jing Yang, Pang, Qing Hai, Xu, Tai-Xu, He, Zhi-Jun, Song, Teng-Fei, Zhang, Jun-Hong
Format: Article
Language:English
Subjects:
Chemistry
Chemistry and Materials Science
Coal
Coking
Functional groups
Graphitization
Industrial Chemistry/Chemical Engineering
Infrared analysis
Raman spectroscopy
Reflectance
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Summary:— The relationship between several structural parameters and vitrinite reflectance (ranged from 0.72 to 2.14) of coal samples was analyzed with infrared and Raman spectrum, consequently important information of functional groups and molecular structures of samples were obtained. It is indicated in the results that the value of FC increases with the increasing of R 0 , while the value of f a increases with the increasing of R 0 in three independent ranges but decreases sharply at the junctions between regions. Besides, the overall trend of DOC is increasing, while the value of A (CH 2 )/ A (CH 3 ) decreases before the point of R 0 = 2.0 and then increases after this value. The value of “ C ” decreases and the rate of decreasing is gradually decreased. All above variations are attributed to the defunctionalization of oxygen-containing functional groups during coalification. Meanwhile, the difference between peak position of D and G increases with the increasing of R 0 while the value of A D1 / A G decreases, which is due to the decline in heterocycle compounds and disorder carbon and the increasing size of microcrystallite structure namely the effect of graphitization.
ISSN:1068-364X
1934-8398
DOI:10.3103/S1068364X19060085