Synthesis and Crystal Structure of the Bis(μ-hydroxo)diiron(II) Complex with Tridentate Ligands Having a Sterically Bulky Imidazolyl Group

The structure of the dinuclear Fe(II) complex [Fe2(OH)2(L)2](ClO4)2 (1) was determined by X-ray crystallography, where L is bis(1-methyl-2-phenyl-4-imidazolylmethyl)benzylamine. The compound crystallizes in a monoclinic space group, P1, with a = 11.007(2), b = 11.5591(12), c = 12.534(2)Å, α = 63.254...

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Bibliographic Details
Published in:X-ray Structure Analysis Online 2019/05/10, Vol.35, pp.27-29
Main Authors: YAGUCHI, Reiko, FURUTACHI, Hideki, SHIROTSUKI, Sanae, ZHANG, Xi, ISHIKAWA, Takanao, AKINE, Shigehisa, TOSHA, Takehiko, FUJINAMI, Shuhei, SUZUKI, Masatatsu, KITAGAWA, Teizo
Format: Article
Language:English
Subjects:
Coordination compounds
Crystal structure
Crystallography
Crystals
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Summary:The structure of the dinuclear Fe(II) complex [Fe2(OH)2(L)2](ClO4)2 (1) was determined by X-ray crystallography, where L is bis(1-methyl-2-phenyl-4-imidazolylmethyl)benzylamine. The compound crystallizes in a monoclinic space group, P1, with a = 11.007(2), b = 11.5591(12), c = 12.534(2)Å, α = 63.254(12), β = 86.458(19), γ = 79.581(7)°, Z = 1, V = 1400.4(4)Å3. The R1 [I > 2σ(I)] and wR2 (all data) values are 0.00328 and 0.0862, respectively, for all 6735 independent reflections. The complex has a bis(μ-hydroxo)diiron core structure.
ISSN:1883-3578
1883-3578
DOI:10.2116/xraystruct.35.27