Near sunlight continuous broadband white-light emission by single-phase Zn()-1,3,5-benzenetricarboxylate MOFs

A new white light MOF was constructed from low-cost 1,3,5-benzenetricarboxylate and nontoxic Zinc( ii ) ions. The compound possessed the most sophisticated crystallographic asymmetric unit containing sixteen metal ions and twelve ligands. Near sunlight and human eye friendly white-light emission und...

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Bibliographic Details
Published in:Dalton transactions : an international journal of inorganic chemistry 2019-10, Vol.48 (4), p.14966-1497
Main Authors: Wang, Ce, Yin, Zheng, Ma, Wei-Min, Li, Xi-Yao, Cao, Li-Hui, Cheng, Yu, Yu, Xin-Yu, Ma, Yang-Min
Format: Article
Language:English
Subjects:
Broadband
Construction costs
Crystallography
Diodes
Ligands
Light emission
Metal-organic frameworks
Photoluminescence
Sunlight
Ultraviolet radiation
White light
Zinc compounds
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Summary:A new white light MOF was constructed from low-cost 1,3,5-benzenetricarboxylate and nontoxic Zinc( ii ) ions. The compound possessed the most sophisticated crystallographic asymmetric unit containing sixteen metal ions and twelve ligands. Near sunlight and human eye friendly white-light emission under a wide ultraviolet radiation range of 300 to 390 nm was observed for this photoemitter, without the use of expensive rare earth and complicated organic ligands. A white light MOF was constructed from low-cost 1,3,5-benzenetricarboxylate and nontoxic Zinc( ii ) ions, which exhibited near sunlight continuous white-light emission under a wide radiation range of 300 to 390 nm and was used for white-light emitting diodes.
ISSN:1477-9226
1477-9234
DOI:10.1039/c9dt03388b