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Amphiphilic Star-Shaped Calix[4]resorcinarene as Stationary Phase for Capillary Gas Chromatography
This work describes the separation performance of the amphiphilic star-shaped calix[4]resorcinarene (C4A-CL) as the stationary phase for capillary gas chromatography (GC). The statically coated C4A-CL capillary column exhibited medium polarity and high column efficiency of 3877 plates m −1 determine...
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| Published in: | Chromatographia 2019-11, Vol.82 (11), p.1697-1708 |
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| Main Authors: | , , , , , , , , , |
| Format: | Article |
| Language: | English |
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| cites | cdi_FETCH-LOGICAL-c319t-dbf2def3d9c88e2a02fd0404ed29517b279983b86d742e097c1f5d4429f7fe8c3 |
| container_end_page | 1708 |
| container_issue | 11 |
| container_start_page | 1697 |
| container_title | Chromatographia |
| container_volume | 82 |
| creator | Sun, Tao Li, Bin Li, Yan Zhao, Xinyu Song, Qianqian Jiang, Xingxing Shuai, Xiaomin Li, Youyang Cai, Zhiqiang Hu, Shaoqiang |
| description | This work describes the separation performance of the amphiphilic star-shaped calix[4]resorcinarene (C4A-CL) as the stationary phase for capillary gas chromatography (GC). The statically coated C4A-CL capillary column exhibited medium polarity and high column efficiency of 3877 plates m
−1
determined by naphthalene at 120 °C. Importantly, the C4A-CL column exhibited extremely high resolving capability for aliphatic analytes with varying polarity, including
n
-alkanes, esters, ketones, alcohols, and bromoalkanes. In addition, the C4A-CL column exhibited high selectivity and resolving capability for positional, structural and
cis
-/
trans
-isomers. Among them, the C4A-CL column displayed advantageous resolving capability over the commercial DB-17 column for aromatic amine isomers. Moreover, it was applied for the determination of isomer impurities in real samples, showing good potential in GC applications. |
| doi_str_mv | 10.1007/s10337-019-03783-0 |
| format | article |
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−1
determined by naphthalene at 120 °C. Importantly, the C4A-CL column exhibited extremely high resolving capability for aliphatic analytes with varying polarity, including
n
-alkanes, esters, ketones, alcohols, and bromoalkanes. In addition, the C4A-CL column exhibited high selectivity and resolving capability for positional, structural and
cis
-/
trans
-isomers. Among them, the C4A-CL column displayed advantageous resolving capability over the commercial DB-17 column for aromatic amine isomers. Moreover, it was applied for the determination of isomer impurities in real samples, showing good potential in GC applications.</description><identifier>ISSN: 0009-5893</identifier><identifier>EISSN: 1612-1112</identifier><identifier>DOI: 10.1007/s10337-019-03783-0</identifier><language>eng</language><publisher>Berlin/Heidelberg: Springer Berlin Heidelberg</publisher><subject>Alcohols ; Aliphatic compounds ; Alkanes ; Analytical Chemistry ; Chemistry ; Chemistry and Materials Science ; Chromatography ; Esters ; Gas chromatography ; Isomers ; Ketones ; Laboratory Medicine ; Naphthalene ; Original ; Pharmacy ; Polarity ; Proteomics ; Selectivity</subject><ispartof>Chromatographia, 2019-11, Vol.82 (11), p.1697-1708</ispartof><rights>Springer-Verlag GmbH Germany, part of Springer Nature 2019</rights><rights>Copyright Springer Nature B.V. 2019</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c319t-dbf2def3d9c88e2a02fd0404ed29517b279983b86d742e097c1f5d4429f7fe8c3</citedby><cites>FETCH-LOGICAL-c319t-dbf2def3d9c88e2a02fd0404ed29517b279983b86d742e097c1f5d4429f7fe8c3</cites><orcidid>0000-0002-2380-340X</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Sun, Tao</creatorcontrib><creatorcontrib>Li, Bin</creatorcontrib><creatorcontrib>Li, Yan</creatorcontrib><creatorcontrib>Zhao, Xinyu</creatorcontrib><creatorcontrib>Song, Qianqian</creatorcontrib><creatorcontrib>Jiang, Xingxing</creatorcontrib><creatorcontrib>Shuai, Xiaomin</creatorcontrib><creatorcontrib>Li, Youyang</creatorcontrib><creatorcontrib>Cai, Zhiqiang</creatorcontrib><creatorcontrib>Hu, Shaoqiang</creatorcontrib><title>Amphiphilic Star-Shaped Calix[4]resorcinarene as Stationary Phase for Capillary Gas Chromatography</title><title>Chromatographia</title><addtitle>Chromatographia</addtitle><description>This work describes the separation performance of the amphiphilic star-shaped calix[4]resorcinarene (C4A-CL) as the stationary phase for capillary gas chromatography (GC). The statically coated C4A-CL capillary column exhibited medium polarity and high column efficiency of 3877 plates m
−1
determined by naphthalene at 120 °C. Importantly, the C4A-CL column exhibited extremely high resolving capability for aliphatic analytes with varying polarity, including
n
-alkanes, esters, ketones, alcohols, and bromoalkanes. In addition, the C4A-CL column exhibited high selectivity and resolving capability for positional, structural and
cis
-/
trans
-isomers. Among them, the C4A-CL column displayed advantageous resolving capability over the commercial DB-17 column for aromatic amine isomers. Moreover, it was applied for the determination of isomer impurities in real samples, showing good potential in GC applications.</description><subject>Alcohols</subject><subject>Aliphatic compounds</subject><subject>Alkanes</subject><subject>Analytical Chemistry</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Chromatography</subject><subject>Esters</subject><subject>Gas chromatography</subject><subject>Isomers</subject><subject>Ketones</subject><subject>Laboratory Medicine</subject><subject>Naphthalene</subject><subject>Original</subject><subject>Pharmacy</subject><subject>Polarity</subject><subject>Proteomics</subject><subject>Selectivity</subject><issn>0009-5893</issn><issn>1612-1112</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><recordid>eNp9kFFLwzAQx4MoOKdfwKeCz9FL0jbJ4yg6hYHC9EkkpG2ydnRNTTpw397MCr4Jxx13_O5_xx-hawK3BIDfBQKMcQxEYmBcMAwnaEZyQjEhhJ6iGQBInAnJztFFCNvYUpnnM1QudkPTxujaKlmP2uN1owdTJ4Xu2q_39MOb4HzV9tqb3iQ6HKGxdbE_JC-NDiaxzkd6aLvuOFtGpGi82-nRbbwemsMlOrO6C-bqt87R28P9a_GIV8_Lp2KxwhUjcsR1aWltLKtlJYShGqitIYXU1FRmhJeUSylYKfKap9SA5BWxWZ2mVFpujajYHN1MuoN3n3sTRrV1e9_Hk4oyyEQaxWSk6ERV3oXgjVWDb3fxc0VAHb1Uk5cqeql-vIx5jti0FCLcb4z_k_5n6xsMknfy</recordid><startdate>20191101</startdate><enddate>20191101</enddate><creator>Sun, Tao</creator><creator>Li, Bin</creator><creator>Li, Yan</creator><creator>Zhao, Xinyu</creator><creator>Song, Qianqian</creator><creator>Jiang, Xingxing</creator><creator>Shuai, Xiaomin</creator><creator>Li, Youyang</creator><creator>Cai, Zhiqiang</creator><creator>Hu, Shaoqiang</creator><general>Springer Berlin Heidelberg</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><orcidid>https://orcid.org/0000-0002-2380-340X</orcidid></search><sort><creationdate>20191101</creationdate><title>Amphiphilic Star-Shaped Calix[4]resorcinarene as Stationary Phase for Capillary Gas Chromatography</title><author>Sun, Tao ; Li, Bin ; Li, Yan ; Zhao, Xinyu ; Song, Qianqian ; Jiang, Xingxing ; Shuai, Xiaomin ; Li, Youyang ; Cai, Zhiqiang ; Hu, Shaoqiang</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c319t-dbf2def3d9c88e2a02fd0404ed29517b279983b86d742e097c1f5d4429f7fe8c3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><topic>Alcohols</topic><topic>Aliphatic compounds</topic><topic>Alkanes</topic><topic>Analytical Chemistry</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Chromatography</topic><topic>Esters</topic><topic>Gas chromatography</topic><topic>Isomers</topic><topic>Ketones</topic><topic>Laboratory Medicine</topic><topic>Naphthalene</topic><topic>Original</topic><topic>Pharmacy</topic><topic>Polarity</topic><topic>Proteomics</topic><topic>Selectivity</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Sun, Tao</creatorcontrib><creatorcontrib>Li, Bin</creatorcontrib><creatorcontrib>Li, Yan</creatorcontrib><creatorcontrib>Zhao, Xinyu</creatorcontrib><creatorcontrib>Song, Qianqian</creatorcontrib><creatorcontrib>Jiang, Xingxing</creatorcontrib><creatorcontrib>Shuai, Xiaomin</creatorcontrib><creatorcontrib>Li, Youyang</creatorcontrib><creatorcontrib>Cai, Zhiqiang</creatorcontrib><creatorcontrib>Hu, Shaoqiang</creatorcontrib><collection>CrossRef</collection><jtitle>Chromatographia</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Sun, Tao</au><au>Li, Bin</au><au>Li, Yan</au><au>Zhao, Xinyu</au><au>Song, Qianqian</au><au>Jiang, Xingxing</au><au>Shuai, Xiaomin</au><au>Li, Youyang</au><au>Cai, Zhiqiang</au><au>Hu, Shaoqiang</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Amphiphilic Star-Shaped Calix[4]resorcinarene as Stationary Phase for Capillary Gas Chromatography</atitle><jtitle>Chromatographia</jtitle><stitle>Chromatographia</stitle><date>2019-11-01</date><risdate>2019</risdate><volume>82</volume><issue>11</issue><spage>1697</spage><epage>1708</epage><pages>1697-1708</pages><issn>0009-5893</issn><eissn>1612-1112</eissn><abstract>This work describes the separation performance of the amphiphilic star-shaped calix[4]resorcinarene (C4A-CL) as the stationary phase for capillary gas chromatography (GC). The statically coated C4A-CL capillary column exhibited medium polarity and high column efficiency of 3877 plates m
−1
determined by naphthalene at 120 °C. Importantly, the C4A-CL column exhibited extremely high resolving capability for aliphatic analytes with varying polarity, including
n
-alkanes, esters, ketones, alcohols, and bromoalkanes. In addition, the C4A-CL column exhibited high selectivity and resolving capability for positional, structural and
cis
-/
trans
-isomers. Among them, the C4A-CL column displayed advantageous resolving capability over the commercial DB-17 column for aromatic amine isomers. Moreover, it was applied for the determination of isomer impurities in real samples, showing good potential in GC applications.</abstract><cop>Berlin/Heidelberg</cop><pub>Springer Berlin Heidelberg</pub><doi>10.1007/s10337-019-03783-0</doi><tpages>12</tpages><orcidid>https://orcid.org/0000-0002-2380-340X</orcidid></addata></record> |
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| subjects | Alcohols Aliphatic compounds Alkanes Analytical Chemistry Chemistry Chemistry and Materials Science Chromatography Esters Gas chromatography Isomers Ketones Laboratory Medicine Naphthalene Original Pharmacy Polarity Proteomics Selectivity |
| title | Amphiphilic Star-Shaped Calix[4]resorcinarene as Stationary Phase for Capillary Gas Chromatography |
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