Highly oriented (111) CoO and Co3O4 thin films grown by ion beam sputtering

• Published in: Journal of alloys and compounds 2019-11, Vol.810, p.151912, Article 151912
• Main Authors: Prieto, P., Marco, J.F., Serrano, A., Manso, M., de la Figuera, J.
• Format: Article
• Language: English
• Subjects: Cobalt oxides; Deposition; EXAFS; Fine structure; Ion beam sputtering; Ion beams; Partial pressure; Photoelectrons; Solid phases; Substrates; Temperature dependence; Thin films; Transmittance; X ray absorption
• ISSN: 0925-8388; 1873-4669
• DOI: 10.1016/j.jallcom.2019.151912

We demonstrate that ion beam sputtering is a suitable deposition technique to obtain single-phase and highly (111)-oriented CoO and Co3O4 thin films. The control of substrate temperature and composition of the reactive atmosphere during deposition allows tailoring the phase structure and preferential growth of the films. Optimum substrate temperatures of 773 K and 603 K for CoO and Co3O4, respectively, have been determined and the presence of the single CoO and Co3O4 phases on the films has been confirmed by X-ray diffraction, X-ray photoelectron spectroscopy, X-ray absorption near-edge structure (XANES) and extended X-ray absorption fine structure (EXAFS) spectroscopies. Transmittance differences in the visible region higher than 50% have been observed between low transmittance in Co3O4 films and high transmittance in CoO films. The semiconducting behavior of Co3O4 thin films was confirmed by temperature dependent resistance measurements. The Co3O4 thin films also show a dual optical band gap at energies of 1.47 and 2.14 eV associated to d-d and p-d transition, respectively. Additionally, at intermediate temperatures between the optimum ones to growth (111)-oriented single phase CoO and Co3O4 films, only one single phase, either CoO or Co3O4, is present in the films, in which the electrical and structural properties can be controlled by the oxygen partial pressure used during deposition. [Display omitted] •Ion beam sputtering is a suitable technique to grow cobalt oxides oriented to the highest dense packed crystal planes.•Single phase cobalt oxide thin films, CoO and Co3O4, (111) oriented have been obtained.•XPS, XRD and EXAFS analysis demonstrate the high quality CoO and Co3O4 thin films.•CoO/Co3O4 thin films show insulating/high-conducting electrical behavior and high/low UV-visible transmittance.•A sharp transition between both phases is observed by varying the oxygen partial pressure.