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Synthesis, solar cell application, and biological study of vinyl substituted isophorone derivatives
In this study, isophorone derivatives, which are single step aldol products, were designed and synthesized. Our overview of the synthesis of solar cell application and biological applications of series vinyl substituted isophorone compounds is reported. All synthesized compounds were characterized b...
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Published in: | Research on chemical intermediates 2019-11, Vol.45 (11), p.5625-5639 |
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container_title | Research on chemical intermediates |
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creator | Kozak, Zehra Pıravadılı Mucur, Selin Canımkurbey, Betül İdil, Önder Eryılmaz, Serpil Gul, Melek |
description | In this study, isophorone derivatives, which are single step aldol products, were designed and synthesized. Our overview of the synthesis of solar cell application and biological applications of series vinyl substituted isophorone compounds is reported. All synthesized compounds were characterized both through experimental techniques and calculations with density functional theory. Additionally, we investigated the photophysical properties of small organic compounds for organic bulk heterojunction photovoltaic cells. The solar cell efficiency results were compared and compound 4 was found to be more efficient than the other compounds. It was found that the optical quantum yield values were very close. Isophorone derivatives showed better antioxidant activities, which were DPPH, metal chelating, reducing activity, and antimicrobial activities against
Salmonella typhimurium
,
Klebsiella pneumonia
,
Candida albicans
,
Staphylococcus aureus
,
Bacillus subtilis
, and
Escherichia coli
. Compound 7 (which is substituted quinoline) and compound 5 (which is substituted cyno) had the highest antioxidant effect. The 4-brom phenyl, 4-cyno phenyl were used against gram negative bacteria and the 4-ter-butyl phenyl group was indicated for gram positive bacteria and yeast. |
doi_str_mv | 10.1007/s11164-019-03924-y |
format | article |
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Salmonella typhimurium
,
Klebsiella pneumonia
,
Candida albicans
,
Staphylococcus aureus
,
Bacillus subtilis
, and
Escherichia coli
. Compound 7 (which is substituted quinoline) and compound 5 (which is substituted cyno) had the highest antioxidant effect. The 4-brom phenyl, 4-cyno phenyl were used against gram negative bacteria and the 4-ter-butyl phenyl group was indicated for gram positive bacteria and yeast.</description><identifier>ISSN: 0922-6168</identifier><identifier>EISSN: 1568-5675</identifier><identifier>DOI: 10.1007/s11164-019-03924-y</identifier><language>eng</language><publisher>Dordrecht: Springer Netherlands</publisher><subject>Aldehydes ; Antioxidants ; Bacteria ; Catalysis ; Chelation ; Chemistry ; Chemistry and Materials Science ; Density functional theory ; Derivatives ; E coli ; Heterojunctions ; Inorganic Chemistry ; Klebsiella ; Organic compounds ; Photovoltaic cells ; Physical Chemistry ; Quinoline ; Salmonella ; Solar cells ; Substitutes ; Synthesis ; Yeast</subject><ispartof>Research on chemical intermediates, 2019-11, Vol.45 (11), p.5625-5639</ispartof><rights>Springer Nature B.V. 2019</rights><rights>Copyright Springer Nature B.V. 2019</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c356t-4de577a43096e3c0e06dcb408d73be0c98da762511b12cf3d1150003e3f2a9153</citedby><cites>FETCH-LOGICAL-c356t-4de577a43096e3c0e06dcb408d73be0c98da762511b12cf3d1150003e3f2a9153</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Kozak, Zehra</creatorcontrib><creatorcontrib>Pıravadılı Mucur, Selin</creatorcontrib><creatorcontrib>Canımkurbey, Betül</creatorcontrib><creatorcontrib>İdil, Önder</creatorcontrib><creatorcontrib>Eryılmaz, Serpil</creatorcontrib><creatorcontrib>Gul, Melek</creatorcontrib><title>Synthesis, solar cell application, and biological study of vinyl substituted isophorone derivatives</title><title>Research on chemical intermediates</title><addtitle>Res Chem Intermed</addtitle><description>In this study, isophorone derivatives, which are single step aldol products, were designed and synthesized. Our overview of the synthesis of solar cell application and biological applications of series vinyl substituted isophorone compounds is reported. All synthesized compounds were characterized both through experimental techniques and calculations with density functional theory. Additionally, we investigated the photophysical properties of small organic compounds for organic bulk heterojunction photovoltaic cells. The solar cell efficiency results were compared and compound 4 was found to be more efficient than the other compounds. It was found that the optical quantum yield values were very close. Isophorone derivatives showed better antioxidant activities, which were DPPH, metal chelating, reducing activity, and antimicrobial activities against
Salmonella typhimurium
,
Klebsiella pneumonia
,
Candida albicans
,
Staphylococcus aureus
,
Bacillus subtilis
, and
Escherichia coli
. Compound 7 (which is substituted quinoline) and compound 5 (which is substituted cyno) had the highest antioxidant effect. The 4-brom phenyl, 4-cyno phenyl were used against gram negative bacteria and the 4-ter-butyl phenyl group was indicated for gram positive bacteria and yeast.</description><subject>Aldehydes</subject><subject>Antioxidants</subject><subject>Bacteria</subject><subject>Catalysis</subject><subject>Chelation</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Density functional theory</subject><subject>Derivatives</subject><subject>E coli</subject><subject>Heterojunctions</subject><subject>Inorganic Chemistry</subject><subject>Klebsiella</subject><subject>Organic compounds</subject><subject>Photovoltaic cells</subject><subject>Physical Chemistry</subject><subject>Quinoline</subject><subject>Salmonella</subject><subject>Solar cells</subject><subject>Substitutes</subject><subject>Synthesis</subject><subject>Yeast</subject><issn>0922-6168</issn><issn>1568-5675</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><recordid>eNp9kE1LxDAQhoMouK7-AU8Br1udSZq0PcriFwge1HNIk3Q3S21q0i7031tdwZunYYbnfQceQi4RrhGguEmIKPMMsMqAVyzPpiOyQCHLTMhCHJMFVIxlEmV5Ss5S2gGgKEtYEPM6dcPWJZ9WNIVWR2pc21Ld9603evChW1HdWVr70IbNfGppGkY70dDQve-meR3rNPhhHJylPoV-G2LoHLUu-v1csHfpnJw0uk3u4ncuyfv93dv6MXt-eXha3z5nhgs5ZLl1oih0zqGSjhtwIK2pcyhtwWsHpiqtLiQTiDUy03CLKACAO94wXaHgS3J16O1j-BxdGtQujLGbXyrGEUFCVbKZYgfKxJBSdI3qo__QcVII6lumOshUs0z1I1NNc4gfQmmGu42Lf9X_pL4Atqt5ZA</recordid><startdate>20191101</startdate><enddate>20191101</enddate><creator>Kozak, Zehra</creator><creator>Pıravadılı Mucur, Selin</creator><creator>Canımkurbey, Betül</creator><creator>İdil, Önder</creator><creator>Eryılmaz, Serpil</creator><creator>Gul, Melek</creator><general>Springer Netherlands</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20191101</creationdate><title>Synthesis, solar cell application, and biological study of vinyl substituted isophorone derivatives</title><author>Kozak, Zehra ; Pıravadılı Mucur, Selin ; Canımkurbey, Betül ; İdil, Önder ; Eryılmaz, Serpil ; Gul, Melek</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c356t-4de577a43096e3c0e06dcb408d73be0c98da762511b12cf3d1150003e3f2a9153</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><topic>Aldehydes</topic><topic>Antioxidants</topic><topic>Bacteria</topic><topic>Catalysis</topic><topic>Chelation</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Density functional theory</topic><topic>Derivatives</topic><topic>E coli</topic><topic>Heterojunctions</topic><topic>Inorganic Chemistry</topic><topic>Klebsiella</topic><topic>Organic compounds</topic><topic>Photovoltaic cells</topic><topic>Physical Chemistry</topic><topic>Quinoline</topic><topic>Salmonella</topic><topic>Solar cells</topic><topic>Substitutes</topic><topic>Synthesis</topic><topic>Yeast</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Kozak, Zehra</creatorcontrib><creatorcontrib>Pıravadılı Mucur, Selin</creatorcontrib><creatorcontrib>Canımkurbey, Betül</creatorcontrib><creatorcontrib>İdil, Önder</creatorcontrib><creatorcontrib>Eryılmaz, Serpil</creatorcontrib><creatorcontrib>Gul, Melek</creatorcontrib><collection>CrossRef</collection><jtitle>Research on chemical intermediates</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Kozak, Zehra</au><au>Pıravadılı Mucur, Selin</au><au>Canımkurbey, Betül</au><au>İdil, Önder</au><au>Eryılmaz, Serpil</au><au>Gul, Melek</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis, solar cell application, and biological study of vinyl substituted isophorone derivatives</atitle><jtitle>Research on chemical intermediates</jtitle><stitle>Res Chem Intermed</stitle><date>2019-11-01</date><risdate>2019</risdate><volume>45</volume><issue>11</issue><spage>5625</spage><epage>5639</epage><pages>5625-5639</pages><issn>0922-6168</issn><eissn>1568-5675</eissn><abstract>In this study, isophorone derivatives, which are single step aldol products, were designed and synthesized. Our overview of the synthesis of solar cell application and biological applications of series vinyl substituted isophorone compounds is reported. All synthesized compounds were characterized both through experimental techniques and calculations with density functional theory. Additionally, we investigated the photophysical properties of small organic compounds for organic bulk heterojunction photovoltaic cells. The solar cell efficiency results were compared and compound 4 was found to be more efficient than the other compounds. It was found that the optical quantum yield values were very close. Isophorone derivatives showed better antioxidant activities, which were DPPH, metal chelating, reducing activity, and antimicrobial activities against
Salmonella typhimurium
,
Klebsiella pneumonia
,
Candida albicans
,
Staphylococcus aureus
,
Bacillus subtilis
, and
Escherichia coli
. Compound 7 (which is substituted quinoline) and compound 5 (which is substituted cyno) had the highest antioxidant effect. The 4-brom phenyl, 4-cyno phenyl were used against gram negative bacteria and the 4-ter-butyl phenyl group was indicated for gram positive bacteria and yeast.</abstract><cop>Dordrecht</cop><pub>Springer Netherlands</pub><doi>10.1007/s11164-019-03924-y</doi><tpages>15</tpages></addata></record> |
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subjects | Aldehydes Antioxidants Bacteria Catalysis Chelation Chemistry Chemistry and Materials Science Density functional theory Derivatives E coli Heterojunctions Inorganic Chemistry Klebsiella Organic compounds Photovoltaic cells Physical Chemistry Quinoline Salmonella Solar cells Substitutes Synthesis Yeast |
title | Synthesis, solar cell application, and biological study of vinyl substituted isophorone derivatives |
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