Tandem Reactions of Ynones: via Conjugate Addition of Nitrogen‐, Carbon‐, Oxygen‐, Boron‐, Silicon‐, Phosphorus‐, and Sulfur‐Containing Nucleophiles

Ynones are widely used in organic synthesis. Their great success is rooted in their multiple functional groups. This review focus on advance of ynones in published in the decade 2009–2019. Reactions triggered by the conjugate addition of nitrogen‐, carbon‐, oxygen‐, boron‐, silicon‐, phosphorus‐, an...

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Bibliographic Details
Published in:Advanced synthesis & catalysis 2019-11, Vol.361 (21), p.4839-4881
Main Authors: Li, Yang, Yu, Jian, Bi, Yicheng, Yan, Guobing, Huang, Dayun
Format: Article
Language:English
Subjects:
Boron
Carbon
Cascade chemical reactions
Chemical synthesis
conjugate addition
Conjugates
Functional groups
mechanism
multifunctionality
Nucleophiles
Organic chemistry
Phosphorus
Silicon
Stereoselectivity
Sulfur
tandem reactions
ynones
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Summary:Ynones are widely used in organic synthesis. Their great success is rooted in their multiple functional groups. This review focus on advance of ynones in published in the decade 2009–2019. Reactions triggered by the conjugate addition of nitrogen‐, carbon‐, oxygen‐, boron‐, silicon‐, phosphorus‐, and sulfur‐containing nucleophiles are thoroughly discussed and summarized herein. Multicomponent reactions, rearrangements, cycloadditions, regio‐ and stereoselective synthesis, oxidations, coupling, green chemistry et al. are depicted in detail. We hope that this review will promote future research in this area.
ISSN:1615-4150
1615-4169
DOI:10.1002/adsc.201900611