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Coordination Polymers of γ,γ'-Dipyridyl and Mononuclear Benzoates M(OOCPh)2[O(H)Me]4 (M = Ni, Co)
The slow diffusion of a γ,γ′-dipyridyl adduct solution in methanol into a methanol solution of the adduct M[(OOCPh] 2 [O(H)Me] 4 ( 1 ) at the reagent ratio 1 : 1 and room temperature was found to result in the 1D coordination polymers {dipyM(OOCPh) 2 [O(H)Me] 2 } n (M = Ni ( 2 ), green; Co ( 3 ), or...
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| Published in: | Russian journal of inorganic chemistry 2019-10, Vol.64 (10), p.1220-1228 |
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| Main Authors: | , , , , , |
| Format: | Article |
| Language: | English |
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| cited_by | cdi_FETCH-LOGICAL-c2316-4d9ab561c753e09ac4dcfadea61e3010505ee9817c36de157e551d329445b6dd3 |
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| cites | cdi_FETCH-LOGICAL-c2316-4d9ab561c753e09ac4dcfadea61e3010505ee9817c36de157e551d329445b6dd3 |
| container_end_page | 1228 |
| container_issue | 10 |
| container_start_page | 1220 |
| container_title | Russian journal of inorganic chemistry |
| container_volume | 64 |
| creator | Datchuk, R. R. Grineva, A. A. Uvarova, M. A. Yakushev, I. A. Zubavichus, Ya. V. Nefedov, S. E. |
| description | The slow diffusion of a γ,γ′-dipyridyl adduct solution in methanol into a methanol solution of the adduct M[(OOCPh]
2
[O(H)Me]
4
(
1
) at the reagent ratio 1 : 1 and room temperature was found to result in the 1D coordination polymers {dipyM(OOCPh)
2
[O(H)Me]
2
}
n
(M = Ni (
2
), green; Co (
3
), orange) and {(dipy)
2
Co
2
(µ-OOCPh)
2
(η
2
-OOCPh)
2
⋅ MeOH}
n
(
4)
, pink). Orange polymer
3
was the only product when the initial reagents were diluted three times, and their diffusion was performed at 5°C. Synthesized polymers
2
–
4
were studied by chemical and X-ray diffraction analyses and IR spectroscopy. |
| doi_str_mv | 10.1134/S0036023619100036 |
| format | article |
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2
[O(H)Me]
4
(
1
) at the reagent ratio 1 : 1 and room temperature was found to result in the 1D coordination polymers {dipyM(OOCPh)
2
[O(H)Me]
2
}
n
(M = Ni (
2
), green; Co (
3
), orange) and {(dipy)
2
Co
2
(µ-OOCPh)
2
(η
2
-OOCPh)
2
⋅ MeOH}
n
(
4)
, pink). Orange polymer
3
was the only product when the initial reagents were diluted three times, and their diffusion was performed at 5°C. Synthesized polymers
2
–
4
were studied by chemical and X-ray diffraction analyses and IR spectroscopy.</description><identifier>ISSN: 0036-0236</identifier><identifier>EISSN: 1531-8613</identifier><identifier>DOI: 10.1134/S0036023619100036</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>Benzoates ; Chemistry ; Chemistry and Materials Science ; Coordination Compounds ; Coordination polymers ; Diffusion rate ; Infrared spectroscopy ; Inorganic Chemistry ; Methanol ; Organic chemistry ; Polymers ; Reagents ; Room temperature</subject><ispartof>Russian journal of inorganic chemistry, 2019-10, Vol.64 (10), p.1220-1228</ispartof><rights>Pleiades Publishing, Ltd. 2019</rights><rights>Copyright Springer Nature B.V. 2019</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c2316-4d9ab561c753e09ac4dcfadea61e3010505ee9817c36de157e551d329445b6dd3</citedby><cites>FETCH-LOGICAL-c2316-4d9ab561c753e09ac4dcfadea61e3010505ee9817c36de157e551d329445b6dd3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,777,781,27905,27906</link.rule.ids></links><search><creatorcontrib>Datchuk, R. R.</creatorcontrib><creatorcontrib>Grineva, A. A.</creatorcontrib><creatorcontrib>Uvarova, M. A.</creatorcontrib><creatorcontrib>Yakushev, I. A.</creatorcontrib><creatorcontrib>Zubavichus, Ya. V.</creatorcontrib><creatorcontrib>Nefedov, S. E.</creatorcontrib><title>Coordination Polymers of γ,γ'-Dipyridyl and Mononuclear Benzoates M(OOCPh)2[O(H)Me]4 (M = Ni, Co)</title><title>Russian journal of inorganic chemistry</title><addtitle>Russ. J. Inorg. Chem</addtitle><description>The slow diffusion of a γ,γ′-dipyridyl adduct solution in methanol into a methanol solution of the adduct M[(OOCPh]
2
[O(H)Me]
4
(
1
) at the reagent ratio 1 : 1 and room temperature was found to result in the 1D coordination polymers {dipyM(OOCPh)
2
[O(H)Me]
2
}
n
(M = Ni (
2
), green; Co (
3
), orange) and {(dipy)
2
Co
2
(µ-OOCPh)
2
(η
2
-OOCPh)
2
⋅ MeOH}
n
(
4)
, pink). Orange polymer
3
was the only product when the initial reagents were diluted three times, and their diffusion was performed at 5°C. Synthesized polymers
2
–
4
were studied by chemical and X-ray diffraction analyses and IR spectroscopy.</description><subject>Benzoates</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Coordination Compounds</subject><subject>Coordination polymers</subject><subject>Diffusion rate</subject><subject>Infrared spectroscopy</subject><subject>Inorganic Chemistry</subject><subject>Methanol</subject><subject>Organic chemistry</subject><subject>Polymers</subject><subject>Reagents</subject><subject>Room temperature</subject><issn>0036-0236</issn><issn>1531-8613</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><recordid>eNp1UMtKw0AUHUTBWv0AdwMubKHRuZlHkoULjY8KjSmoK5EwzUw0JWbqTLuIv9X_6DeZUMGFyF3cy7nnAQehYyBnAJSdPxJCBfGpgAhId--gHnAKXiiA7qJeB3ndfx8dODcnhDEShD2Ux8ZYVdZyWZoaT03VfGjrsCnwZj3arE-963LR2FI1FZa1wompTb3KKy0tvtL1l5FL7XAySNN4-j70X9LBeJjoV4YHCb7AD-UIx2Z4iPYKWTl99LP76Pn25ikee5P07j6-nHi5T0F4TEVyxgXkAaeaRDJnKi-k0lKApgQIJ1zrKIQgp0Jp4IHmHBT1I8b4TChF--hk67uw5nOl3TKbm5Wt28isDfDDdnjUsmDLyq1xzuoiW9jyQ9omA5J1XWZ_umw1_lbjWm79pu2v8_-ib1m5c0A</recordid><startdate>20191001</startdate><enddate>20191001</enddate><creator>Datchuk, R. R.</creator><creator>Grineva, A. A.</creator><creator>Uvarova, M. A.</creator><creator>Yakushev, I. A.</creator><creator>Zubavichus, Ya. V.</creator><creator>Nefedov, S. E.</creator><general>Pleiades Publishing</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20191001</creationdate><title>Coordination Polymers of γ,γ'-Dipyridyl and Mononuclear Benzoates M(OOCPh)2[O(H)Me]4 (M = Ni, Co)</title><author>Datchuk, R. R. ; Grineva, A. A. ; Uvarova, M. A. ; Yakushev, I. A. ; Zubavichus, Ya. V. ; Nefedov, S. E.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c2316-4d9ab561c753e09ac4dcfadea61e3010505ee9817c36de157e551d329445b6dd3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><topic>Benzoates</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Coordination Compounds</topic><topic>Coordination polymers</topic><topic>Diffusion rate</topic><topic>Infrared spectroscopy</topic><topic>Inorganic Chemistry</topic><topic>Methanol</topic><topic>Organic chemistry</topic><topic>Polymers</topic><topic>Reagents</topic><topic>Room temperature</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Datchuk, R. R.</creatorcontrib><creatorcontrib>Grineva, A. A.</creatorcontrib><creatorcontrib>Uvarova, M. A.</creatorcontrib><creatorcontrib>Yakushev, I. A.</creatorcontrib><creatorcontrib>Zubavichus, Ya. V.</creatorcontrib><creatorcontrib>Nefedov, S. E.</creatorcontrib><collection>CrossRef</collection><jtitle>Russian journal of inorganic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Datchuk, R. R.</au><au>Grineva, A. A.</au><au>Uvarova, M. A.</au><au>Yakushev, I. A.</au><au>Zubavichus, Ya. V.</au><au>Nefedov, S. E.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Coordination Polymers of γ,γ'-Dipyridyl and Mononuclear Benzoates M(OOCPh)2[O(H)Me]4 (M = Ni, Co)</atitle><jtitle>Russian journal of inorganic chemistry</jtitle><stitle>Russ. J. Inorg. Chem</stitle><date>2019-10-01</date><risdate>2019</risdate><volume>64</volume><issue>10</issue><spage>1220</spage><epage>1228</epage><pages>1220-1228</pages><issn>0036-0236</issn><eissn>1531-8613</eissn><abstract>The slow diffusion of a γ,γ′-dipyridyl adduct solution in methanol into a methanol solution of the adduct M[(OOCPh]
2
[O(H)Me]
4
(
1
) at the reagent ratio 1 : 1 and room temperature was found to result in the 1D coordination polymers {dipyM(OOCPh)
2
[O(H)Me]
2
}
n
(M = Ni (
2
), green; Co (
3
), orange) and {(dipy)
2
Co
2
(µ-OOCPh)
2
(η
2
-OOCPh)
2
⋅ MeOH}
n
(
4)
, pink). Orange polymer
3
was the only product when the initial reagents were diluted three times, and their diffusion was performed at 5°C. Synthesized polymers
2
–
4
were studied by chemical and X-ray diffraction analyses and IR spectroscopy.</abstract><cop>Moscow</cop><pub>Pleiades Publishing</pub><doi>10.1134/S0036023619100036</doi><tpages>9</tpages></addata></record> |
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| ispartof | Russian journal of inorganic chemistry, 2019-10, Vol.64 (10), p.1220-1228 |
| issn | 0036-0236 1531-8613 |
| language | eng |
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| source | Springer Link |
| subjects | Benzoates Chemistry Chemistry and Materials Science Coordination Compounds Coordination polymers Diffusion rate Infrared spectroscopy Inorganic Chemistry Methanol Organic chemistry Polymers Reagents Room temperature |
| title | Coordination Polymers of γ,γ'-Dipyridyl and Mononuclear Benzoates M(OOCPh)2[O(H)Me]4 (M = Ni, Co) |
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