A single-crystal-to-single-crystal transformation affording photochromic 3D MORF crystals

Metal-organic framework (MOF) type crystals in which rigid, viologen-based pillars are surrounded by cucurbit[7]uril (CB[7]) macrocycles are described. These metal-organic rotaxane frameworks (MORF) are obtained by desolvation of a crystal precursor featuring a network already near-optimal toward 3D...

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Published in:Chemical communications (Cambridge, England) England), 2019-11, Vol.55 (92), p.13824-13827
Main Authors: Yang, Xue, Giorgi, Michel, Karoui, Hakim, Gigmes, Didier, Hornebecq, Virginie, Ouari, Olivier, Kermagoret, Anthony, Bardelang, David
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Language:English
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Crystallography
Metal-organic frameworks
Photochromism
Single crystals
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cited_by cdi_FETCH-LOGICAL-c350t-7b773e19792d91f3b12be3906832065c1e0385c182d0ffcc59271a64df6e08f93
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container_end_page 13827
container_issue 92
container_start_page 13824
container_title Chemical communications (Cambridge, England)
container_volume 55
creator Yang, Xue
Giorgi, Michel
Karoui, Hakim
Gigmes, Didier
Hornebecq, Virginie
Ouari, Olivier
Kermagoret, Anthony
Bardelang, David
description Metal-organic framework (MOF) type crystals in which rigid, viologen-based pillars are surrounded by cucurbit[7]uril (CB[7]) macrocycles are described. These metal-organic rotaxane frameworks (MORF) are obtained by desolvation of a crystal precursor featuring a network already near-optimal toward 3D metal-ligand reticulation and show reversible photochromism. Metal-organic framework (MOF) type crystals in which rigid, viologen-based pillars are surrounded by cucurbit[7]uril (CB[7]) macrocycles are described.
doi_str_mv 10.1039/c9cc07121k
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subjects Crystallography
Metal-organic frameworks
Photochromism
Single crystals
title A single-crystal-to-single-crystal transformation affording photochromic 3D MORF crystals
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