UV-protection of cellulosic fabric prints using hyperbranched polyester-stabilized titania coating

• Published in: Progress in organic coatings 2019-11, Vol.136, p.105295, Article 105295
• Main Authors: Hakeim, Osama A., Abdelghaffar, Fatma, Haroun, Ahmed A.
• Format: Article
• Language: English
• Subjects: Acceleration; Cellulosic fabrics and pigment fixation; Chemical industry; Diffraction patterns; Encapsulated phthalocyanine; Encapsulation; Fourier transforms; Gravimetric analysis; Hyperbranched polyesters; Infrared analysis; Light diffraction; Liquid phases; Nanocomposites; Phase separation; Photon correlation spectroscopy; Pigments; Polyester resins; Protective coatings; Shielding; Sol-gel processes; Thermal analysis; Titania; Ultraviolet radiation; UV shielding property; Zeta potential
• ISSN: 0300-9440; 1873-331X
• DOI: 10.1016/j.porgcoat.2019.105295

[Display omitted] •Organic pigment coated with titania for attaining good UV-shielding properties.•Hyperbranched polyester-Stabilized Phthalocyanine Pigments Coated with Titania.•Titania shells of pigment gave an efficient UV shielding property on cellulosic fabrics.•Level of UV protection relies on the numbers of terminated hydroxyl groups in HPBs.•Long term durability of UV protection throughout washing and light exposure. This study approached a convenient method for the organic pigment coated with titania for attaining good UV-shielding properties. Hyperbranched polyesters (HBPs) included various HBPs; generation2 (HBPs16) and generation 4 (HBPs 64) are formulated for encapsulation of phthalocyanine pigments using liquid-phase separation method. The encapsulated pigments are then coated by titania via sol-gel process from n-butoxide (TBOT).Thermal gravimetric analysis (TGA), scanning/transmission electron microscope (SEM/TEM), Fourier transform infrared spectroscopy (FTIR), dynamic light scattering (DLS), X-ray diffraction pattern (XRD), and zeta potential analysis were examined to illustrate the coating performance of titania. The stabilized coated pigment nanocomposites are used for printing of cellulosic fabrics. UV shielding property of the pigment prints was systematically investigated. It is further demonstrated that the obtained titania shells of pigment prints can serve as an efficient protection against UV light and could obviously enhance the UV shielding property. The degree of protection depends on the numbers of functional hydroxyl end groups in hyperbranched polyesters. Besides, the titania coated pigment has no noticeable effect on the driving force for acceleration of pigment printing process under the unfavourable conditions.