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Kinetics of scandium sorption by phosphorus-containing ion exchanger purolite D5041 from hydrolysis sulfuric acid from titanium dioxide production
The kinetics of sorption of scandium and main impurities (iron, titanium, zirconium, aluminum and thorium) from hydrolysis sulfuric acid from titanium dioxide production by phosphorus-containing cation exchanger Purolite D5041 was investigated. The results of experiments by the limited-volume method...
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creator | Rychkov, V. N. Smirnov, A. L. Nalivayko, K. A. Titova, S. M. Kirillov, E. V. |
description | The kinetics of sorption of scandium and main impurities (iron, titanium, zirconium, aluminum and thorium) from hydrolysis sulfuric acid from titanium dioxide production by phosphorus-containing cation exchanger Purolite D5041 was investigated. The results of experiments by the limited-volume method and method of interruption showed that sorption occurred in a mixed-diffusion mode for all studied elements. Experimental data can be adequately described by a pseudo-second order model equation. This indicates that sorption was accompanied by intramolecular interaction of sorbed substances. |
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N. ; Smirnov, A. L. ; Nalivayko, K. A. ; Titova, S. M. ; Kirillov, E. V.</creator><contributor>Smirnov, Andrey A. ; Volkovich, Vladimir A. ; Zvonarev, Sergey V. ; Kashin, Ilya V. ; Narkhov, Evgeniy D.</contributor><creatorcontrib>Rychkov, V. N. ; Smirnov, A. L. ; Nalivayko, K. A. ; Titova, S. M. ; Kirillov, E. V. ; Smirnov, Andrey A. ; Volkovich, Vladimir A. ; Zvonarev, Sergey V. ; Kashin, Ilya V. ; Narkhov, Evgeniy D.</creatorcontrib><description>The kinetics of sorption of scandium and main impurities (iron, titanium, zirconium, aluminum and thorium) from hydrolysis sulfuric acid from titanium dioxide production by phosphorus-containing cation exchanger Purolite D5041 was investigated. The results of experiments by the limited-volume method and method of interruption showed that sorption occurred in a mixed-diffusion mode for all studied elements. Experimental data can be adequately described by a pseudo-second order model equation. This indicates that sorption was accompanied by intramolecular interaction of sorbed substances.</description><identifier>ISSN: 0094-243X</identifier><identifier>EISSN: 1551-7616</identifier><identifier>DOI: 10.1063/1.5134205</identifier><identifier>CODEN: APCPCS</identifier><language>eng</language><publisher>Melville: American Institute of Physics</publisher><subject>Aluminum ; Cation exchanging ; Hydrolysis ; Ion exchangers ; Kinetics ; Phosphorus ; Scandium ; Sorption ; Sulfuric acid ; Thorium ; Titanium ; Titanium dioxide ; Zirconium</subject><ispartof>AIP conference proceedings, 2019, Vol.2174 (1)</ispartof><rights>Author(s)</rights><rights>2019 Author(s). 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V.</creatorcontrib><title>Kinetics of scandium sorption by phosphorus-containing ion exchanger purolite D5041 from hydrolysis sulfuric acid from titanium dioxide production</title><title>AIP conference proceedings</title><description>The kinetics of sorption of scandium and main impurities (iron, titanium, zirconium, aluminum and thorium) from hydrolysis sulfuric acid from titanium dioxide production by phosphorus-containing cation exchanger Purolite D5041 was investigated. The results of experiments by the limited-volume method and method of interruption showed that sorption occurred in a mixed-diffusion mode for all studied elements. Experimental data can be adequately described by a pseudo-second order model equation. This indicates that sorption was accompanied by intramolecular interaction of sorbed substances.</description><subject>Aluminum</subject><subject>Cation exchanging</subject><subject>Hydrolysis</subject><subject>Ion exchangers</subject><subject>Kinetics</subject><subject>Phosphorus</subject><subject>Scandium</subject><subject>Sorption</subject><subject>Sulfuric acid</subject><subject>Thorium</subject><subject>Titanium</subject><subject>Titanium dioxide</subject><subject>Zirconium</subject><issn>0094-243X</issn><issn>1551-7616</issn><fulltext>true</fulltext><rsrctype>conference_proceeding</rsrctype><creationdate>2019</creationdate><recordtype>conference_proceeding</recordtype><recordid>eNp9kU1LAzEQhoMoWKsH_0HAm7A1n7vbo_iNBS8K3kK-tk1pkzXZSPdv-IvdpQVvHoaBed-ZZ5gB4BKjGUYlvcEzjikjiB-BCeYcF1WJy2MwQWjOCsLo5yk4S2mNEJlXVT0BP6_O287pBEMDk5beuLyFKcS2c8FD1cN2FdIQMadCB99J551fwlG0O72SfmkjbHMMG9dZeM8Rw7CJYQtXvRmKfXIJprxpcnQaSu3MXu1cJ_2IMi7snLGwjcFkPULPwUkjN8leHPIUfDw-vN89F4u3p5e720XREk67AtMaYVMrJVFFmeaKEWMrxfkcaWQxZ6wyuqwlM0hrZDTCXNaqNA1TqrIE0ym42s8d0F_Zpk6sQ45-QApCCSGMlzUfXNd7V9LDyuN-oo1uK2MvvkMUWBzuLVrT_GfGSIwP-mugv5nlheE</recordid><startdate>20191206</startdate><enddate>20191206</enddate><creator>Rychkov, V. N.</creator><creator>Smirnov, A. L.</creator><creator>Nalivayko, K. A.</creator><creator>Titova, S. M.</creator><creator>Kirillov, E. V.</creator><general>American Institute of Physics</general><scope>8FD</scope><scope>H8D</scope><scope>L7M</scope></search><sort><creationdate>20191206</creationdate><title>Kinetics of scandium sorption by phosphorus-containing ion exchanger purolite D5041 from hydrolysis sulfuric acid from titanium dioxide production</title><author>Rychkov, V. N. ; Smirnov, A. L. ; Nalivayko, K. A. ; Titova, S. M. ; Kirillov, E. 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V.</au><au>Smirnov, Andrey A.</au><au>Volkovich, Vladimir A.</au><au>Zvonarev, Sergey V.</au><au>Kashin, Ilya V.</au><au>Narkhov, Evgeniy D.</au><format>book</format><genre>proceeding</genre><ristype>CONF</ristype><atitle>Kinetics of scandium sorption by phosphorus-containing ion exchanger purolite D5041 from hydrolysis sulfuric acid from titanium dioxide production</atitle><btitle>AIP conference proceedings</btitle><date>2019-12-06</date><risdate>2019</risdate><volume>2174</volume><issue>1</issue><issn>0094-243X</issn><eissn>1551-7616</eissn><coden>APCPCS</coden><abstract>The kinetics of sorption of scandium and main impurities (iron, titanium, zirconium, aluminum and thorium) from hydrolysis sulfuric acid from titanium dioxide production by phosphorus-containing cation exchanger Purolite D5041 was investigated. The results of experiments by the limited-volume method and method of interruption showed that sorption occurred in a mixed-diffusion mode for all studied elements. Experimental data can be adequately described by a pseudo-second order model equation. This indicates that sorption was accompanied by intramolecular interaction of sorbed substances.</abstract><cop>Melville</cop><pub>American Institute of Physics</pub><doi>10.1063/1.5134205</doi><tpages>6</tpages></addata></record> |
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source | American Institute of Physics:Jisc Collections:Transitional Journals Agreement 2021-23 (Reading list) |
subjects | Aluminum Cation exchanging Hydrolysis Ion exchangers Kinetics Phosphorus Scandium Sorption Sulfuric acid Thorium Titanium Titanium dioxide Zirconium |
title | Kinetics of scandium sorption by phosphorus-containing ion exchanger purolite D5041 from hydrolysis sulfuric acid from titanium dioxide production |
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