A Nanospherical Mesoporous Ruthenium-Containing Polymer as a Guaiacol Hydrogenation Catalyst

A hybrid catalyst is synthesized using ruthenium nanoparticles deposited on a nanospherical mesoporous polymer. Catalytic properties are studied in guaiacol hydrogenation at a temperature of 200–250°С and a hydrogen pressure of 5.0 MPa. Effect of solvent and catalytic additives on the reaction is in...

Full description

Saved in:
Bibliographic Details
Published in:Petroleum chemistry 2019-12, Vol.59 (12), p.1300-1306
Main Authors: Boronoev, M. P., Shakirov, I. I., Ignat’eva, V. I., Maximov, A. L., Karakhanov, E. A.
Format: Article
Language:English
Subjects:
Additives
Binary systems
Catalysts
Chemical synthesis
Chemistry
Chemistry and Materials Science
Dodecane
Hydrogen storage
Hydrogenation
Industrial Chemistry/Chemical Engineering
Nanoparticles
Phenols
Polymer industry
Polymers
Ruthenium
Scandium
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:A hybrid catalyst is synthesized using ruthenium nanoparticles deposited on a nanospherical mesoporous polymer. Catalytic properties are studied in guaiacol hydrogenation at a temperature of 200–250°С and a hydrogen pressure of 5.0 MPa. Effect of solvent and catalytic additives on the reaction is investigated. It is shown that the synthesized catalyst exhibits the highest activity in guaiacol hydrodeoxygenation in the two-phase system water/ n -dodecane and when the reaction is carried out in the presence of scandium triflate.
ISSN:0965-5441
1555-6239
DOI:10.1134/S096554411912003X