A Nanospherical Mesoporous Ruthenium-Containing Polymer as a Guaiacol Hydrogenation Catalyst

A hybrid catalyst is synthesized using ruthenium nanoparticles deposited on a nanospherical mesoporous polymer. Catalytic properties are studied in guaiacol hydrogenation at a temperature of 200–250°С and a hydrogen pressure of 5.0 MPa. Effect of solvent and catalytic additives on the reaction is in...

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Published in:Petroleum chemistry 2019-12, Vol.59 (12), p.1300-1306
Main Authors: Boronoev, M. P., Shakirov, I. I., Ignat’eva, V. I., Maximov, A. L., Karakhanov, E. A.
Format: Article
Language:English
Subjects:
Additives
Binary systems
Catalysts
Chemical synthesis
Chemistry
Chemistry and Materials Science
Dodecane
Hydrogen storage
Hydrogenation
Industrial Chemistry/Chemical Engineering
Nanoparticles
Phenols
Polymer industry
Polymers
Ruthenium
Scandium
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container_end_page 1306
container_issue 12
container_start_page 1300
container_title Petroleum chemistry
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creator Boronoev, M. P.
Shakirov, I. I.
Ignat’eva, V. I.
Maximov, A. L.
Karakhanov, E. A.
description A hybrid catalyst is synthesized using ruthenium nanoparticles deposited on a nanospherical mesoporous polymer. Catalytic properties are studied in guaiacol hydrogenation at a temperature of 200–250°С and a hydrogen pressure of 5.0 MPa. Effect of solvent and catalytic additives on the reaction is investigated. It is shown that the synthesized catalyst exhibits the highest activity in guaiacol hydrodeoxygenation in the two-phase system water/ n -dodecane and when the reaction is carried out in the presence of scandium triflate.
doi_str_mv 10.1134/S096554411912003X
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subjects Additives
Binary systems
Catalysts
Chemical synthesis
Chemistry
Chemistry and Materials Science
Dodecane
Hydrogen storage
Hydrogenation
Industrial Chemistry/Chemical Engineering
Nanoparticles
Phenols
Polymer industry
Polymers
Ruthenium
Scandium
title A Nanospherical Mesoporous Ruthenium-Containing Polymer as a Guaiacol Hydrogenation Catalyst
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