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Effect of Composition of Cobalt-Molybdenum-Containing Sulfonium Thiosalts on the Hydrogenation Activity of Nanosized Catalysts In Situ Synthesized on Their Basis
Cobalt-molybdenum-containing thiosalts with different composition of the sulfonium cation are prepared. The activities of sulfide catalysts in situ synthesized on their basis in the hydrogenation of substituted naphthalenes are compared. It is shown that the sulfonium cation composition affects the...
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Published in: | Petroleum chemistry 2019-12, Vol.59 (12), p.1285-1292 |
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Main Authors: | , , , , |
Format: | Article |
Language: | English |
Subjects: | |
Citations: | Items that this one cites Items that cite this one |
Online Access: | Get full text |
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Summary: | Cobalt-molybdenum-containing thiosalts with different composition of the sulfonium cation are prepared. The activities of sulfide catalysts in situ synthesized on their basis in the hydrogenation of substituted naphthalenes are compared. It is shown that the sulfonium cation composition affects the morphology of the sulfide particles and the phase composition of the catalyst. It is demonstrated that the conversion of model alkyl-substituted bicyclic aromatic hydrocarbons is higher in the presence of the catalyst prepared from the phenylsulfonium thiosalt. |
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ISSN: | 0965-5441 1555-6239 |
DOI: | 10.1134/S0965544119120065 |