Thermochemical and Energy Characteristics of 1,4-Diethynylbenzene

The standard enthalpy of formation of 1,4-diethynylbenzene experimentally to be 500.6 ± 6.7 kJ/mol. Calculations show that 1,4-diethynylbenzene has a relatively high adiabatic combustion temperature (about 1970 K at a pressure of 5 atm) and very high heat of combustion in oxygen (42 MJ/kg); therefor...

Full description

Saved in:
Bibliographic Details
Published in:Combustion, explosion, and shock waves explosion, and shock waves, 2019-11, Vol.55 (6), p.644-647
Main Authors: Lempert, D. B., Zyuzin, I. N., Nabatova, A. V., Kazakov, A. I., Yanovskii, L. S.
Format: Article
Language:English
Subjects:
Adiabatic flow
Classical and Continuum Physics
Classical Mechanics
Combustion temperature
Control
Dynamical Systems
Engineering
Enthalpy
Heat of combustion
HMX
Physical Chemistry
Physics
Physics and Astronomy
Solid fuels
Vibration
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
cited_by cdi_FETCH-LOGICAL-c316t-f0080e2b7007a012a0f4bec0ab172752d3b1a1219813e55865178ccd5a3f122d3
cites cdi_FETCH-LOGICAL-c316t-f0080e2b7007a012a0f4bec0ab172752d3b1a1219813e55865178ccd5a3f122d3
container_end_page 647
container_issue 6
container_start_page 644
container_title Combustion, explosion, and shock waves
container_volume 55
creator Lempert, D. B.
Zyuzin, I. N.
Nabatova, A. V.
Kazakov, A. I.
Yanovskii, L. S.
description The standard enthalpy of formation of 1,4-diethynylbenzene experimentally to be 500.6 ± 6.7 kJ/mol. Calculations show that 1,4-diethynylbenzene has a relatively high adiabatic combustion temperature (about 1970 K at a pressure of 5 atm) and very high heat of combustion in oxygen (42 MJ/kg); therefore, 1,4-diethynylbenzene can be used as the basis to develop an effective dispersing agent of solid fuel that provides an adiabatic combustion temperature of up to 2500 K at a heat of combustion far exceeding the values provided by HMX and the other azides of N-heterocycles previously proposed for this purpose.
doi_str_mv 10.1134/S0010508219060029
format article
fullrecord <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_2330975752</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2330975752</sourcerecordid><originalsourceid>FETCH-LOGICAL-c316t-f0080e2b7007a012a0f4bec0ab172752d3b1a1219813e55865178ccd5a3f122d3</originalsourceid><addsrcrecordid>eNp1kDFPwzAQhS0EEqXwA9gisRK4s-M4HavSAlIlBsocOc6lSdU4xU6H8OtxVCQGxHTD-957p8fYLcIDokge3wEQJGQcZ5AC8NkZm6BUIs5EIs_ZZJTjUb9kV97vICA8SSdsvqnJtZ2pqW2M3kfaltHSktsO0aLWTpueXOP7xvioqyK8T-Knhvp6sMO-IPtFlq7ZRaX3nm5-7pR9rJabxUu8fnt-XczXsRGY9nEFkAHxQgEoDcg1VElBBnSBiivJS1GgxvB-hoKkzFKJKjOmlFpUyIM8ZXen3IPrPo_k-3zXHZ0NlTkXAmZKhpRA4YkyrvPeUZUfXNNqN-QI-bhU_mep4OEnjw-s3ZL7Tf7f9A33wmg1</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2330975752</pqid></control><display><type>article</type><title>Thermochemical and Energy Characteristics of 1,4-Diethynylbenzene</title><source>Springer Nature</source><creator>Lempert, D. B. ; Zyuzin, I. N. ; Nabatova, A. V. ; Kazakov, A. I. ; Yanovskii, L. S.</creator><creatorcontrib>Lempert, D. B. ; Zyuzin, I. N. ; Nabatova, A. V. ; Kazakov, A. I. ; Yanovskii, L. S.</creatorcontrib><description>The standard enthalpy of formation of 1,4-diethynylbenzene experimentally to be 500.6 ± 6.7 kJ/mol. Calculations show that 1,4-diethynylbenzene has a relatively high adiabatic combustion temperature (about 1970 K at a pressure of 5 atm) and very high heat of combustion in oxygen (42 MJ/kg); therefore, 1,4-diethynylbenzene can be used as the basis to develop an effective dispersing agent of solid fuel that provides an adiabatic combustion temperature of up to 2500 K at a heat of combustion far exceeding the values provided by HMX and the other azides of N-heterocycles previously proposed for this purpose.</description><identifier>ISSN: 0010-5082</identifier><identifier>EISSN: 1573-8345</identifier><identifier>DOI: 10.1134/S0010508219060029</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>Adiabatic flow ; Classical and Continuum Physics ; Classical Mechanics ; Combustion temperature ; Control ; Dynamical Systems ; Engineering ; Enthalpy ; Heat of combustion ; HMX ; Physical Chemistry ; Physics ; Physics and Astronomy ; Solid fuels ; Vibration</subject><ispartof>Combustion, explosion, and shock waves, 2019-11, Vol.55 (6), p.644-647</ispartof><rights>Pleiades Publishing, Ltd. 2019</rights><rights>Copyright Springer Nature B.V. 2019</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c316t-f0080e2b7007a012a0f4bec0ab172752d3b1a1219813e55865178ccd5a3f122d3</citedby><cites>FETCH-LOGICAL-c316t-f0080e2b7007a012a0f4bec0ab172752d3b1a1219813e55865178ccd5a3f122d3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Lempert, D. B.</creatorcontrib><creatorcontrib>Zyuzin, I. N.</creatorcontrib><creatorcontrib>Nabatova, A. V.</creatorcontrib><creatorcontrib>Kazakov, A. I.</creatorcontrib><creatorcontrib>Yanovskii, L. S.</creatorcontrib><title>Thermochemical and Energy Characteristics of 1,4-Diethynylbenzene</title><title>Combustion, explosion, and shock waves</title><addtitle>Combust Explos Shock Waves</addtitle><description>The standard enthalpy of formation of 1,4-diethynylbenzene experimentally to be 500.6 ± 6.7 kJ/mol. Calculations show that 1,4-diethynylbenzene has a relatively high adiabatic combustion temperature (about 1970 K at a pressure of 5 atm) and very high heat of combustion in oxygen (42 MJ/kg); therefore, 1,4-diethynylbenzene can be used as the basis to develop an effective dispersing agent of solid fuel that provides an adiabatic combustion temperature of up to 2500 K at a heat of combustion far exceeding the values provided by HMX and the other azides of N-heterocycles previously proposed for this purpose.</description><subject>Adiabatic flow</subject><subject>Classical and Continuum Physics</subject><subject>Classical Mechanics</subject><subject>Combustion temperature</subject><subject>Control</subject><subject>Dynamical Systems</subject><subject>Engineering</subject><subject>Enthalpy</subject><subject>Heat of combustion</subject><subject>HMX</subject><subject>Physical Chemistry</subject><subject>Physics</subject><subject>Physics and Astronomy</subject><subject>Solid fuels</subject><subject>Vibration</subject><issn>0010-5082</issn><issn>1573-8345</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><recordid>eNp1kDFPwzAQhS0EEqXwA9gisRK4s-M4HavSAlIlBsocOc6lSdU4xU6H8OtxVCQGxHTD-957p8fYLcIDokge3wEQJGQcZ5AC8NkZm6BUIs5EIs_ZZJTjUb9kV97vICA8SSdsvqnJtZ2pqW2M3kfaltHSktsO0aLWTpueXOP7xvioqyK8T-Knhvp6sMO-IPtFlq7ZRaX3nm5-7pR9rJabxUu8fnt-XczXsRGY9nEFkAHxQgEoDcg1VElBBnSBiivJS1GgxvB-hoKkzFKJKjOmlFpUyIM8ZXen3IPrPo_k-3zXHZ0NlTkXAmZKhpRA4YkyrvPeUZUfXNNqN-QI-bhU_mep4OEnjw-s3ZL7Tf7f9A33wmg1</recordid><startdate>20191101</startdate><enddate>20191101</enddate><creator>Lempert, D. B.</creator><creator>Zyuzin, I. N.</creator><creator>Nabatova, A. V.</creator><creator>Kazakov, A. I.</creator><creator>Yanovskii, L. S.</creator><general>Pleiades Publishing</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20191101</creationdate><title>Thermochemical and Energy Characteristics of 1,4-Diethynylbenzene</title><author>Lempert, D. B. ; Zyuzin, I. N. ; Nabatova, A. V. ; Kazakov, A. I. ; Yanovskii, L. S.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c316t-f0080e2b7007a012a0f4bec0ab172752d3b1a1219813e55865178ccd5a3f122d3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><topic>Adiabatic flow</topic><topic>Classical and Continuum Physics</topic><topic>Classical Mechanics</topic><topic>Combustion temperature</topic><topic>Control</topic><topic>Dynamical Systems</topic><topic>Engineering</topic><topic>Enthalpy</topic><topic>Heat of combustion</topic><topic>HMX</topic><topic>Physical Chemistry</topic><topic>Physics</topic><topic>Physics and Astronomy</topic><topic>Solid fuels</topic><topic>Vibration</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Lempert, D. B.</creatorcontrib><creatorcontrib>Zyuzin, I. N.</creatorcontrib><creatorcontrib>Nabatova, A. V.</creatorcontrib><creatorcontrib>Kazakov, A. I.</creatorcontrib><creatorcontrib>Yanovskii, L. S.</creatorcontrib><collection>CrossRef</collection><jtitle>Combustion, explosion, and shock waves</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Lempert, D. B.</au><au>Zyuzin, I. N.</au><au>Nabatova, A. V.</au><au>Kazakov, A. I.</au><au>Yanovskii, L. S.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Thermochemical and Energy Characteristics of 1,4-Diethynylbenzene</atitle><jtitle>Combustion, explosion, and shock waves</jtitle><stitle>Combust Explos Shock Waves</stitle><date>2019-11-01</date><risdate>2019</risdate><volume>55</volume><issue>6</issue><spage>644</spage><epage>647</epage><pages>644-647</pages><issn>0010-5082</issn><eissn>1573-8345</eissn><abstract>The standard enthalpy of formation of 1,4-diethynylbenzene experimentally to be 500.6 ± 6.7 kJ/mol. Calculations show that 1,4-diethynylbenzene has a relatively high adiabatic combustion temperature (about 1970 K at a pressure of 5 atm) and very high heat of combustion in oxygen (42 MJ/kg); therefore, 1,4-diethynylbenzene can be used as the basis to develop an effective dispersing agent of solid fuel that provides an adiabatic combustion temperature of up to 2500 K at a heat of combustion far exceeding the values provided by HMX and the other azides of N-heterocycles previously proposed for this purpose.</abstract><cop>Moscow</cop><pub>Pleiades Publishing</pub><doi>10.1134/S0010508219060029</doi><tpages>4</tpages></addata></record>
fulltext fulltext
identifier ISSN: 0010-5082
ispartof Combustion, explosion, and shock waves, 2019-11, Vol.55 (6), p.644-647
issn 0010-5082
1573-8345
language eng
recordid cdi_proquest_journals_2330975752
source Springer Nature
subjects Adiabatic flow
Classical and Continuum Physics
Classical Mechanics
Combustion temperature
Control
Dynamical Systems
Engineering
Enthalpy
Heat of combustion
HMX
Physical Chemistry
Physics
Physics and Astronomy
Solid fuels
Vibration
title Thermochemical and Energy Characteristics of 1,4-Diethynylbenzene
url http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-07T14%3A47%3A43IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Thermochemical%20and%20Energy%20Characteristics%20of%201,4-Diethynylbenzene&rft.jtitle=Combustion,%20explosion,%20and%20shock%20waves&rft.au=Lempert,%20D.%20B.&rft.date=2019-11-01&rft.volume=55&rft.issue=6&rft.spage=644&rft.epage=647&rft.pages=644-647&rft.issn=0010-5082&rft.eissn=1573-8345&rft_id=info:doi/10.1134/S0010508219060029&rft_dat=%3Cproquest_cross%3E2330975752%3C/proquest_cross%3E%3Cgrp_id%3Ecdi_FETCH-LOGICAL-c316t-f0080e2b7007a012a0f4bec0ab172752d3b1a1219813e55865178ccd5a3f122d3%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_pqid=2330975752&rft_id=info:pmid/&rfr_iscdi=true