Synthesis of Ni and rare earth metal (La, Pr, and Nd) oxides from spent Ni–MH batteries by selective precipitation with formic acid an investigation of photoluminescence properties

• Published in: Ionics 2020, Vol.26 (1), p.311-321
• Main Authors: Marins, A. A. L., Banhos, S. G., Cruz, P. C. M., Rodrigues, R. V., Marciniak, L., Muri, E. J. B., Strȩk, W., de Freitas, M. B. J. G.
• Format: Article
• Language: English
• Subjects: Chelating agents; Chelation; Chemistry; Chemistry and Materials Science; Condensed Matter Physics; Electrochemistry; Energy Storage; Formates; Formic acid; Lanthanum; Leaching; Neodymium; Nickel; Optical and Electronic Materials; Organic chemistry; Original Paper; Photoluminescence; Praseodymium; Praseodymium oxide; Rare earth elements; Renewable and Green Energy; Thermal decomposition
• ISSN: 0947-7047; 1862-0760
• DOI: 10.1007/s11581-019-03158-3

A new chemical method was developed for the separation of Ni and rare earths (RE = La, Pr, and Nd) from spent Ni–MH batteries using formic acid as leaching and chelating agent. Ni and RE formates were characterized by FTIR, XRD, TG/DTG, SEM, EDS, and ICP-OES. The photoluminescence properties of RE formate were also investigated. When excited at 420, 421, 422, and 435 nm, RE formate exhibited narrow emission bands at 834, 837, 842, and 867 nm, respectively, attributed to 3 H 4  →  3 P 2 transitions of Pr 3+ and dominated by the abnormally high intensity of the intraconfigurational transition 1 D 2  →  1 G 4 . Thermal decomposition of Ni formate resulted in the formation of NiO and PrNiO 3 . The oxides obtained from RE formate consisted mainly of a crystalline phase of Pr 2 O 3 .