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Disaggregation of Zinc Tetra(4-Carboxyphenoxy) Phthalocyaninate in Aqueous Solutions of Dodecyl-, Tetradecyl-, and Hexadecyltrimethylammonium Bromides at pH 6–9
The aggregation of zinc tetra(4-carboxyphenoxy) phthalocyaninate, ZnPc(COOH) 4 , in organic solvents and water at different pH values has been analyzed using electronic absorption and luminescence spectroscopies. It has been found that, in aqueous systems at pH 6–9, ZnPc(COOH) 4 exists in an aggrega...
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Published in: | Colloid journal of the Russian Academy of Sciences 2019-11, Vol.81 (6), p.711-719 |
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container_end_page | 719 |
container_issue | 6 |
container_start_page | 711 |
container_title | Colloid journal of the Russian Academy of Sciences |
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creator | Movchan, T. G. Chernyad’ev, A. Yu Plotnikova, E. V. Tsivadze, A. Yu Baulin, V. E. |
description | The aggregation of zinc tetra(4-carboxyphenoxy) phthalocyaninate, ZnPc(COOH)
4
, in organic solvents and water at different pH values has been analyzed using electronic absorption and luminescence spectroscopies. It has been found that, in aqueous systems at pH 6–9, ZnPc(COOH)
4
exists in an aggregated state, while it forms molecular solutions in dimethylformamide and dimethyl sulfoxide. The use of cationic surfactants (dodecyl-, tetradecyl-, and hexadecyltrimethylammonium bromides) causes the disaggregation of ZnPc(COOH)
4
into individual molecules in aqueous solutions at pH ≥ 6. This opens up possibilities of applying ZnPc(COOH)
4
as a preparation for photodynamic therapy in physiological solutions, because each molecule of this compound may participate in the generation of singlet molecular oxygen. |
doi_str_mv | 10.1134/S1061933X19060127 |
format | article |
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4
, in organic solvents and water at different pH values has been analyzed using electronic absorption and luminescence spectroscopies. It has been found that, in aqueous systems at pH 6–9, ZnPc(COOH)
4
exists in an aggregated state, while it forms molecular solutions in dimethylformamide and dimethyl sulfoxide. The use of cationic surfactants (dodecyl-, tetradecyl-, and hexadecyltrimethylammonium bromides) causes the disaggregation of ZnPc(COOH)
4
into individual molecules in aqueous solutions at pH ≥ 6. This opens up possibilities of applying ZnPc(COOH)
4
as a preparation for photodynamic therapy in physiological solutions, because each molecule of this compound may participate in the generation of singlet molecular oxygen.</description><identifier>ISSN: 1061-933X</identifier><identifier>EISSN: 1608-3067</identifier><identifier>DOI: 10.1134/S1061933X19060127</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>Aqueous solutions ; Bromides ; Chemistry ; Chemistry and Materials Science ; Dimethyl sulfoxide ; Oxygen ; Photodynamic therapy ; Polymer Sciences ; Surfaces and Interfaces ; Thin Films ; Zinc</subject><ispartof>Colloid journal of the Russian Academy of Sciences, 2019-11, Vol.81 (6), p.711-719</ispartof><rights>Pleiades Publishing, Ltd. 2019</rights><rights>2019© Pleiades Publishing, Ltd. 2019</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c353t-9d414144f009258f4b2cce48a134f0439fb5f4b451e9e46980c2d98947fed8863</citedby><cites>FETCH-LOGICAL-c353t-9d414144f009258f4b2cce48a134f0439fb5f4b451e9e46980c2d98947fed8863</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Movchan, T. G.</creatorcontrib><creatorcontrib>Chernyad’ev, A. Yu</creatorcontrib><creatorcontrib>Plotnikova, E. V.</creatorcontrib><creatorcontrib>Tsivadze, A. Yu</creatorcontrib><creatorcontrib>Baulin, V. E.</creatorcontrib><title>Disaggregation of Zinc Tetra(4-Carboxyphenoxy) Phthalocyaninate in Aqueous Solutions of Dodecyl-, Tetradecyl-, and Hexadecyltrimethylammonium Bromides at pH 6–9</title><title>Colloid journal of the Russian Academy of Sciences</title><addtitle>Colloid J</addtitle><description>The aggregation of zinc tetra(4-carboxyphenoxy) phthalocyaninate, ZnPc(COOH)
4
, in organic solvents and water at different pH values has been analyzed using electronic absorption and luminescence spectroscopies. It has been found that, in aqueous systems at pH 6–9, ZnPc(COOH)
4
exists in an aggregated state, while it forms molecular solutions in dimethylformamide and dimethyl sulfoxide. The use of cationic surfactants (dodecyl-, tetradecyl-, and hexadecyltrimethylammonium bromides) causes the disaggregation of ZnPc(COOH)
4
into individual molecules in aqueous solutions at pH ≥ 6. This opens up possibilities of applying ZnPc(COOH)
4
as a preparation for photodynamic therapy in physiological solutions, because each molecule of this compound may participate in the generation of singlet molecular oxygen.</description><subject>Aqueous solutions</subject><subject>Bromides</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Dimethyl sulfoxide</subject><subject>Oxygen</subject><subject>Photodynamic therapy</subject><subject>Polymer Sciences</subject><subject>Surfaces and Interfaces</subject><subject>Thin Films</subject><subject>Zinc</subject><issn>1061-933X</issn><issn>1608-3067</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><recordid>eNp1kc9KxDAQxosouK4-gLeAFwWrSZN2k6PuqissKOwK4qVk2_TP0iY1SWF78x18Ax_NJzGligeRHCaT-b7fMBnPO0bwAiFMLpcIRohh_IwYjCAKJjveCEWQ-hhGk113d2W_r-97B8ZsIIQRgXTkfcxKw_Nci5zbUkmgMvBSygSshNX8lPhTrtdq2zWFkC6cgcfCFrxSScdlKbkVoJTg6rUVqjVgqaq2h5ieMlOpSLrKPx9QPwmXKZiL7ZBbXdbCFl3F61rJsq3BtVZ1mQoDuAXNHESfb-_s0NvLeGXE0Xcce0-3N6vp3F883N1PrxZ-gkNsfZYS5A7JIGRBSDOyDpJEEMrd92SQYJatQ_dIQiSYIBGjMAlSRhmZZCKlNMJj72TgNlq5iYyNN6rV0rWMA0xwQEkQhk6FBlWilTFaZHHjpuC6ixGM-1XEf1bhPMHgMU4rc6F_yf-bvgCYtY2J</recordid><startdate>20191101</startdate><enddate>20191101</enddate><creator>Movchan, T. G.</creator><creator>Chernyad’ev, A. Yu</creator><creator>Plotnikova, E. V.</creator><creator>Tsivadze, A. Yu</creator><creator>Baulin, V. E.</creator><general>Pleiades Publishing</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20191101</creationdate><title>Disaggregation of Zinc Tetra(4-Carboxyphenoxy) Phthalocyaninate in Aqueous Solutions of Dodecyl-, Tetradecyl-, and Hexadecyltrimethylammonium Bromides at pH 6–9</title><author>Movchan, T. G. ; Chernyad’ev, A. Yu ; Plotnikova, E. V. ; Tsivadze, A. Yu ; Baulin, V. E.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c353t-9d414144f009258f4b2cce48a134f0439fb5f4b451e9e46980c2d98947fed8863</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><topic>Aqueous solutions</topic><topic>Bromides</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Dimethyl sulfoxide</topic><topic>Oxygen</topic><topic>Photodynamic therapy</topic><topic>Polymer Sciences</topic><topic>Surfaces and Interfaces</topic><topic>Thin Films</topic><topic>Zinc</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Movchan, T. G.</creatorcontrib><creatorcontrib>Chernyad’ev, A. Yu</creatorcontrib><creatorcontrib>Plotnikova, E. V.</creatorcontrib><creatorcontrib>Tsivadze, A. Yu</creatorcontrib><creatorcontrib>Baulin, V. E.</creatorcontrib><collection>CrossRef</collection><jtitle>Colloid journal of the Russian Academy of Sciences</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Movchan, T. G.</au><au>Chernyad’ev, A. Yu</au><au>Plotnikova, E. V.</au><au>Tsivadze, A. Yu</au><au>Baulin, V. E.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Disaggregation of Zinc Tetra(4-Carboxyphenoxy) Phthalocyaninate in Aqueous Solutions of Dodecyl-, Tetradecyl-, and Hexadecyltrimethylammonium Bromides at pH 6–9</atitle><jtitle>Colloid journal of the Russian Academy of Sciences</jtitle><stitle>Colloid J</stitle><date>2019-11-01</date><risdate>2019</risdate><volume>81</volume><issue>6</issue><spage>711</spage><epage>719</epage><pages>711-719</pages><issn>1061-933X</issn><eissn>1608-3067</eissn><abstract>The aggregation of zinc tetra(4-carboxyphenoxy) phthalocyaninate, ZnPc(COOH)
4
, in organic solvents and water at different pH values has been analyzed using electronic absorption and luminescence spectroscopies. It has been found that, in aqueous systems at pH 6–9, ZnPc(COOH)
4
exists in an aggregated state, while it forms molecular solutions in dimethylformamide and dimethyl sulfoxide. The use of cationic surfactants (dodecyl-, tetradecyl-, and hexadecyltrimethylammonium bromides) causes the disaggregation of ZnPc(COOH)
4
into individual molecules in aqueous solutions at pH ≥ 6. This opens up possibilities of applying ZnPc(COOH)
4
as a preparation for photodynamic therapy in physiological solutions, because each molecule of this compound may participate in the generation of singlet molecular oxygen.</abstract><cop>Moscow</cop><pub>Pleiades Publishing</pub><doi>10.1134/S1061933X19060127</doi><tpages>9</tpages></addata></record> |
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language | eng |
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subjects | Aqueous solutions Bromides Chemistry Chemistry and Materials Science Dimethyl sulfoxide Oxygen Photodynamic therapy Polymer Sciences Surfaces and Interfaces Thin Films Zinc |
title | Disaggregation of Zinc Tetra(4-Carboxyphenoxy) Phthalocyaninate in Aqueous Solutions of Dodecyl-, Tetradecyl-, and Hexadecyltrimethylammonium Bromides at pH 6–9 |
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