Synthesis and reactivity of aminofuroxans

In this review article, we provide general information on the known methods for directed synthesis of 3- and 4-aminofuroxans, as well as analyze the main aspects of their reactivity. Methods for regio- and chemoselective transformations of aminofuroxans are considered in detail, including both class...

Full description

Saved in:
Bibliographic Details
Published in:Chemistry of heterocyclic compounds (New York, N.Y. 1965) N.Y. 1965), 2019-12, Vol.55 (12), p.1143-1164
Main Authors: Bystrov, Dmitry M., Fershtat, Leonid L., Makhova, Nina N.
Format: Article
Language:English
Subjects:
Acylation
Chemistry
Chemistry and Materials Science
Materials science
Nitration
Nitrogen oxide
Organic Chemistry
Oxidation
Pharmacology
Pharmacy
Review
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:In this review article, we provide general information on the known methods for directed synthesis of 3- and 4-aminofuroxans, as well as analyze the main aspects of their reactivity. Methods for regio- and chemoselective transformations of aminofuroxans are considered in detail, including both classical reactions involving oxidation, acylation, and nitration, as well as several intramolecular rearrangements of aminofuroxans, resulting in the formation of various nitrogen-containing heterocyclic systems. Particular attention has been focused on mechanistic details of these reactions, as well as the practical significance of the synthesized compounds for pharmacology and materials science.
ISSN:0009-3122
1573-8353
DOI:10.1007/s10593-019-02593-4