Synthesis, Structure, and Properties of Cadmium(II) Centered Chiral Coordination Polymer based on (R)‐6‐(1‐Carboxyethoxy)‐2‐naphthoic Acid

A cadmium chiral coordination polymer, formulated as [Cd(R‐cna)]n (1‐D) was constructed under hydrothermal method. Single‐crystal X‐ray diffraction analysis indicated that 1‐D exhibited a 2D layered structure with a point symbol of (47·63). 1‐D was further characterized by infrared spectra, powder X...

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Bibliographic Details
Published in:Zeitschrift für anorganische und allgemeine Chemie (1950) 2019-06, Vol.645 (12), p.863-869
Main Authors: Wang, Xiu‐Wen, Huang, Ji‐Han, Wang, Jun‐Ku, Yu, Ying‐Hui, Ma, Dong‐Sheng
Format: Article
Language:English
Subjects:
Aromatic polycarboxylic acid ligand, Second‐harmonic generation
Cadmium
Chiral coordination polymer
Coordination polymers
Dichroism
Harmonic generations
Hydrothermal crystal growth
Infrared analysis
Infrared spectra
Luminescence
Luminescence sensing
Thermogravimetric analysis
Trinitrotoluene
X-ray diffraction
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Summary:A cadmium chiral coordination polymer, formulated as [Cd(R‐cna)]n (1‐D) was constructed under hydrothermal method. Single‐crystal X‐ray diffraction analysis indicated that 1‐D exhibited a 2D layered structure with a point symbol of (47·63). 1‐D was further characterized by infrared spectra, powder X‐ray diffraction (PXRD), elemental analysis, thermogravimetric analysis (TGA), and circular dichroism spectra (CD). The second‐harmonic generation (SHG) property was investigated. It was also found that the luminescence of 1‐D can be quenched by iron ions and trinitrotoluene, indicating its potential application as luminescence sensing material.
ISSN:0044-2313
1521-3749
DOI:10.1002/zaac.201900029