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Oxygen reduction using a metal-free naphthalene diimide-based covalent organic framework electrocatalyst

A novel naphthalene diimide-based covalent organic framework (NDI-COF) has been synthesized and successfully exfoliated into COF nanosheets (CONs). Electrochemical measurements reveal that the naphthalene diimide units incorporated into NDI-CONs act as efficient electrocatalyst for oxygen reduction...

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2020-01, Vol.56 (8), p.1267-127
Main Authors: Royuela, Sergio, Martínez-Periñán, Emiliano, Arrieta, Marina P, Martínez, José I, Ramos, M. Mar, Zamora, Félix, Lorenzo, Encarnación, Segura, José L
Format: Article
Language:English
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Summary:A novel naphthalene diimide-based covalent organic framework (NDI-COF) has been synthesized and successfully exfoliated into COF nanosheets (CONs). Electrochemical measurements reveal that the naphthalene diimide units incorporated into NDI-CONs act as efficient electrocatalyst for oxygen reduction in alkaline media, showing its potential for the development of metal-free fuel cells. A novel naphthalene diimide-based covalent organic framework (NDI-COF) has been synthesized and successfully exfoliated into COF nanosheets (CONs) to provide an efficient electrocatalyst for the oxygen reduction reaction.
ISSN:1359-7345
1364-548X
DOI:10.1039/c9cc06479f